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Engineering of submicron particles : fundamental concepts and models /
Brings together in one place the fundamental theory and models, and the practical aspects of submicron particle engineering This book attempts to resolve the tricky aspects of engineering submicron particles by discussing the fundamental theories of frequently used research tools-both theoretical an...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, NJ, USA :
John Wiley & Sons, Inc.,
2019.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Intro; Title Page; Copyright Page; Contents; Preface; About the Companion Website; Chapter 1 Nucleation; 1.1 Thermodynamics of Interfaces; 1.1.1 The Interface is a Surface of High Energy; 1.1.2 The Interface is a Surface Under Tension; 1.1.3 Pressure Drop Across Curved Interfaces; 1.1.3.1 Capillary Rise; 1.1.4 Vapour-Liquid Equilibrium Across Curved Interfaces; 1.1.4.1 Thomson Equation; 1.1.5 Stability of the Equilibrium; 1.2 Homogeneous Nucleation; 1.2.1 Energetics of Homogeneous Nucleation; 1.2.1.1 Energetics in Terms of Number of Units; 1.2.2 Kinetics of Homogeneous Nucleation
- 1.2.2.1 Concentration of Embryos/Nuclei1.2.2.2 Chain of Reactions Towards Formation of Nuclei; 1.2.2.3 Algebraic Manipulation of the Rate Expression; 1.2.2.4 Various Forms of Homogeneous Nucleation Rate; 1.2.3 Experimental Aspects of Homogeneous Nucleation; 1.2.3.1 Investigation Using a Cloud Chamber; 1.2.3.2 Other Methods; 1.3 Non-Homogeneous Nucleation; 1.3.1 Heterogeneous Nucleation; 1.3.2 Nucleating Agents and Organizers; 1.3.3 Secondary Nucleation; 1.4 Exercises; Bibliography; Chapter 2 Growth; 2.1 Traditional Crystal Growth Models; 2.1.1 Diffusion Controlled Growth
- 2.1.2 Surface Nucleation Controlled Growth2.1.2.1 Rate of Mononuclear Growth; 2.1.3 Surface Dislocation Controlled Growth: BCF Theory; 2.1.3.1 Rate of Surface Dislocation Controlled Growth; 2.2 Face Growth Theories; 2.2.1 Shape of a Crystal; 2.2.2 Laws of Face Growth; 2.2.2.1 Law of Bravais and Friedel; 2.2.3 Flat, Stepped, and Kinked Faces; 2.3 Measurement of Particle Size and Shape; 2.3.1 Optical Microscopy; 2.3.2 Electron Microscopy; 2.3.3 Light Scattering; 2.3.3.1 Rayleigh Scattering; 2.3.3.2 Static and Dynamic Light-Scattering Techniques; 2.4 Exercises; Bibliography
- Chapter 3 Inter-Particle Forces3.1 Inter-Molecular Forces; 3.1.1 Charge-Charge Interactions; 3.1.2 Charge-Dipole Interactions; 3.1.3 Dipole-Dipole Interactions; 3.1.4 Dipole-Induced Dipole Interactions; 3.1.5 Induced Dipole-Induced Dipole Interactions; 3.1.6 van der Waals Interaction; 3.1.7 Repulsive Potential and the Net Interaction Energy; 3.2 Inter-Particle Forces; 3.2.1 Hamaker's Pairwise Additivity Approach; 3.2.2 Lifshitz's Theory; 3.3 Measurement of Inter-Molecular Forces; 3.4 Measurement of Forces between Surfaces; 3.5 Exercises; Bibliography; Chapter 4 Stability; Charged Interface
- 4.1 Electrostatic Potential Near a Charged Surface4.2 Solution of the Poisson-Boltzmann Equation; 4.3 Repulsive Force between Two Surfaces; 4.4 Steric Stabilization; 4.5 Kinetics of Stability; 4.5.1 Diffusion of Colloidal Particles; 4.5.2 Particle Aggregation in the Absence of Potential; 4.5.3 Particle Aggregation in the Presence of a Net Potential; 4.6 Measurement of Surface Potential; 4.6.1 Surface Potential When Rs > −1; 4.7 Exercises; Bibliography; Chapter 5 Elementary Concepts of Number Balance; 5.1 State of a Particle