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Alkane Functionalization
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Newark :
John Wiley & Sons, Incorporated,
2018.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Title Page; Copyright; Contents; List of Contributors; About the Editors; Preface; List of Abbreviations; Chapter 1 Alkane Functionalization: Introduction and Overview; 1.1 Why Alkane Functionalization?; 1.2 Alkane Functionalization as a Challenge and Overcoming Approaches; 1.3 Types of Alkane Functionalization; 1.4 Structure of the Book; 1.5 Final Remarks; Acknowledgments; Part I C-O Bond Formation. Hydroxylation and Other Oxygenatio; Chapter 2 Activation and Oxidative Functionalization of Alkanes with Noble-Metal Catalysts: Molecular Mechanisms; 2.1 Introduction
- 2.2 Activation of C-H Bond in Alkanes2.3 Activation of Dioxygen; 2.3.1 Peroxo Complexes; 2.3.2 Hydroperoxo Complexes; 2.3.3 Oxo Complexes; 2.4 Design of Catalytic Systems for Oxidation of Alkanes; 2.5 Oxidation of Alkanes with Metal Complexes in Solution; 2.5.1 Shilov's System and Other Pt Catalysts; 2.5.2 Oxidation of Alkanes with Pd Compounds; 2.5.3 Rh-Containing Catalysts and Catalytic Systems; 2.6 Final Comments; References; Chapter 3 Alkane-Oxidizing Systems Based on Metal Complexes. Radical Versus Nonradical Mechanisms1; 3.1 Introduction; 3.2 Main Features of Oxidation Processes
- 3.2.1 Radical Reactions, But Not Radical-Chain Reactions3.2.2 Hydrogen Peroxide Decomposition to Generate Hydroxyl Radicals; 3.2.3 Possible Mechanisms of H2O2 Decomposition; 3.2.4 Activated Adducts (Transition States) Containing Simultaneously Two H2O2 Molecules; 3.3 Methods of Mechanism Investigation; 3.3.1 Formation of Alkyl Hydroperoxides; 3.3.2 Regioselectivity; 3.3.3 Competitive Oxidation of an Alkane and Solvent; 3.3.4 Shul'pin Test for Alkyl Hydroperoxides; 3.4 Conclusions; References; Chapter 4 Reactions of Alkyl Radicals in Aqueous Solutions*; 4.1 Introduction
- 4.2 Production of Alkyl Radicals in Aqueous Solutions4.2.1 The Fenton and Fenton-like Reactions; 4.2.2 Other Oxidation Reactions; 4.2.3 Reduction Reactions; 4.2.4 Reactions with Other Radicals; 4.2.4.1 Inorganic Radicals; 4.2.4.2 Organic Radicals; 4.3 Electrochemistry; 4.3.1 Radicals as the Products of the Direct Oxidations of Substrates on the Electrode; 4.3.2 Radicals as the Products of the Direct Reductions of Substrates on the Electrode; 4.3.3 Radicals as the Products of Electro-Catalytic Oxidations; 4.3.4 Radicals as the Products of Electro-Catalytic Reductions; 4.4 Photochemistry
- 4.4.1 Light Absorption that Leads Directly to the Dissociation of an R X Bond4.4.2 Photolytic Formation of Active Species that React to Form Alkyl Radicals; 4.4.3 Photosensitized Processes; 4.4.4 Photocatalytic Processes Initiated by Light Absorption in Semiconductors; 4.5 Ionizing Radiation; 4.6 Sono-Chemistry; 4.7 Mechano-Chemistry; 4.8 Microwave Chemistry; 4.9 Production of Alkyl Radicals in Biological Systems; 4.9.1 Enzymatic Processes; 4.9.2 Processes Initiated by ROS/RNS; 4.10 General Comments on Radical Reactions; 4.10.1 Nearly All Radicals Are Both Oxidizing and Reducing Agents