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Reactions of Hydroxyl Radicals with Oxygenated Hydrocarbons in the Gas Phase : a Laser Photolysis/Laser-Induced Fluorescence Study.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Berlin :
Logos Verlag Berlin,
2017.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Intro; 1 Introduction; 2 Fundamentals; 2.1 Linear and Non-Linear Spectroscopy; 2.1.1 Excitation and Following Processes; 2.1.2 Excited State Population in a Two-Level System; 2.1.3 Linear Absorption Spectroscopy; 2.1.4 Saturated Laser-Induced Fluorescence; 2.2 Temperature and Pressure Dependence of Rate Coefficients of Gas Phase Reactions; 2.2.1 Temperature Dependence; 2.2.2 Pressure Dependence; 2.2.3 Statistical Rate Theory; 2.3 Complex-Forming Bimolecular Reactions; 2.3.1 Mechanismand Overall Kinetics; 2.3.2 Pressure Dependence; 2.3.3 Temperature Dependence.
- 2.3.4 Quantum chemical Methods for the Description of Potential Energy Surfaces3 Experimental; 3.1 Gas Injection Methods; 3.1.1 Original Setup; 3.1.2 Revised Setup; 3.1.3 Preparation of Gas Mixtures in Cylinders; 3.1.4 Bubbler Technique for High Pressures; 3.2 Pulsed Laser Photolysis/Laser-Induced Fluorescence; 3.2.1 Experimental Setup; 3.2.2 Reaction Cells; 3.2.3 Absorption Unit; 3.2.4 Radical Production and Detection; 3.2.5 Error Analysis; 3.3 UV/Vis Absorption; 3.3.1 Static Experiments; 3.3.2 Slow-Flow Experiments; 4 Studies on the Purity of HNO3 and Revision of the PLP/LIF Setup.
- 4.1 Introduction4.2 Identification and Quantification of Impurities; 4.2.1 Experimental Procedure; 4.2.2 Results and Discussion; 4.2.3 Conclusions; 4.3 Purity of Nitric Acid GasMixtures; 4.3.1 Experimental Procedure; 4.3.2 Results and Discussion; 4.3.3 Conclusions and Revision of the Gas Injection Method; 4.4 Supply of Pure Nitric Acid in the Gas Phase; 4.4.1 Experimental Procedure; 4.4.2 Results with Concentrated Nitric Acid; 4.4.3 Results with a TernaryMixture; 4.4.4 Conclusions; 4.5 Consequences for the PLP/LIF Experiment; 4.5.1 Measurements with the High-Pressure Bubbler.
- 4.5.2 Measurements with HNO3-Containing Gas Mixtures4.5.3 Measurements with Low Reactant Concentrations; 4.6 Outlook; 5 The Reaction DME + OH; 5.1 Introduction; 5.2 Experimental Procedure; 5.3 Analysis; 5.4 Results and Discussion; 5.5 Conclusion and Outlook; 6 The Reaction DEE + OH; 6.1 Introduction; 6.2 Experimental Procedure; 6.3 Analysis; 6.4 Results and Discussion; 6.5 Conclusion and Outlook; 7 The Reaction DMM + OH; 7.1 Introduction; 7.2 Experimental Procedure; 7.3 Analysis; 7.4 Results and Discussion; 7.5 Conclusion and Outlook; A Appendices.