Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Ackermann, Lutz
Otros Autores: Gunnoe, T. Brent, Habgood, Laurel Goj
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Newark : John Wiley & Sons, Incorporated, 2017.
Temas:
Catalysis.
Catalyse.
Catalysis
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Title Page
  • Copyright
  • Contents
  • Introduction and Preface
  • References
  • Chapter 1 Functionalization of Heteroaromatic Substrates using Groups 9 and 10 Catalysts
  • 1.1 Introduction
  • 1.2 Thiophenes, furans, and Related Heterocycles
  • 1.3 Pyrroles, Indoles, Pyridines, and Imidazopyridines
  • 1.4 Azoles and Other Miscellaneous Heterocycles
  • 1.5 Summary
  • References
  • Chapter 2 Ruthenium Catalysts for the Alkylation of Functionalized Arenes and Heteroaromatic Substrates via Hydroarylation
  • 2.1 Introduction
  • 2.2 Alkylation by Ruthenium(0) Catalysts via Oxidative-Addition C-H Activation2.2.1 Alkylation by Ruthenium(II) Catalysts via Carboxylate-Assisted C-H Activation
  • 2.3 Summary and Conclusions
  • Abbreviations
  • References
  • Chapter 3 Alkylation of Arenes Without Chelation Assistance: Transition Metal Catalysts with d6 Electron Configurations
  • 3.1 Transition Metal-Mediated Arene Alkylation: Overview
  • 3.2 Octahedral d6 Transition Metal Catalysts for Olefin Hydroarylation: Scorpionate Supported Ru(II) Catalysts
  • 3.2.1 Structureâ#x80;#x93;Activity Relationships with TpRu(L)(NCMe)Ph: Examination of Elementary Steps and Catalytic Hydrophenylation of Ethylene as a Function of Ligand L3.2.2 Ethylene Hydrophenylation Catalyzed by Cationic Ru(II) Complexes Ligated by Poly(pyrazolyl)alkanes
  • 3.3 Olefin Hydroarylation Catalyzed by Octahedral d6 Ir(III) Supported by the Acetylacetonate Ligand
  • 3.3.1 Mechanism of Catalytic Olefin Hydrophenylation using Ir(III) Supported by the Acetylacetonate Ligand
  • 3.3.2 Other d6 Ir(III) Catalysts
  • 3.4 Summary: Comparison of Ru(II) and Ir(III) Catalysts for Olefin Hydroarylation3.5 Future Outlook: Extension of Olefin Hydroarylation using Hydrocarbons to Earth Abundant Metals
  • References
  • Chapter 4 Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers
  • 4.1 Introduction
  • 4.2 PtII Catalyzed Hydroarylation
  • 4.2.1 PtII Hydroarylation Catalysts Bearing Anionic Bidentate (NN) Ligands
  • 4.2.2 PtII Hydroarylation Catalysts Bearing Neutral Bidentate (NN) Ligands
  • 4.2.3 PtII Hydroarylation Catalysts Supported by Nonnitrogen-based Ligands
  • 4.2.4 Summary of PtII Catalyzed Hydroarylations4.3 RhI-Catalyzed Hydroarylation
  • 4.3.1 Reactions of Unfunctionalized Arenes with RhI Complexes Proceeding via Hydroarylation-Like Mechanisms
  • 4.3.2 Directed ortho-Hydroarylation Catalyzed by RhI Complexes
  • 4.3.3 RhI-Catalyzed Hydroarylation with Fluorinated Arenes
  • 4.3.4 Summary of RhI-Catalyzed Hydroarylation
  • 4.4 Directed ortho-Hydroarylation Catalyzed by IrI Complexes
  • 4.5 Hydroarylation with Ni0 Complexes via NiII Intermediates

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