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Metal-Polymer Systems : Interface Design and Chemical Bonding.

Detalles Bibliográficos
Clasificación:	Libro Electrónico
Autor principal:	Friedrich, JÃœrg
Formato:	Electrónico eBook
Idioma:	Inglés
Publicado:	Newark : John Wiley & Sons, Incorporated, 2017.
Temas:	Chemical bonds. Chemical bonds
Acceso en línea:	Texto completo

Tabla de Contenidos:

Cover
Title Page
Copyright
Contents
Preface
Chapter 1 High-Performance Metal-Polymer Composites: Chemical Bonding, Adhesion, and Interface Design
1.1 Introduction
References
Chapter 2 Interpretation of Adhesion Phenomena
Review of Theories
2.1 General
2.2 Mechanical Interlocking
2.2.1 Mechanical Interlocking in a Macroscopic Scale
2.2.2 Mechanical Adhesion on a Microscale
2.2.3 Mechanical Anchoring on a Molecular Scale
2.3 Interdiffusion
2.3.1 Diblock Copolymers for Interface-Crossing Adhesion Promotion
2.3.2 Interdiffusion and Welding
2.3.3 Diffusion of Metals into Polymers
2.4 Interphase Formation
2.4.1 Polymer-Polymer Blends
2.4.2 Nanoparticle Composites
2.4.3 Transcrystalline Layers
2.4.4 Redox Reactions across the Metal-Polymer Interface
2.4.5 Reactions of Transition Metals with Aromatic Polymers
2.4.6 Loss in Anisotropic Orientation of Polymers Caused by Pretreatment or by Contact to Metals
2.4.7 Weak Boundary Layer
2.5 Weak Molecular Interactions (Cohesive Forces)
2.5.1 Thermodynamic Adsorption, Wetting Model
2.5.2 Contact Angle, Surface Properties, and Adhesion
2.5.3 Contact Angle Measurement
2.5.4 Advancing and Receding Contact Angles, Contact Angle Hysteresis
2.5.5 Real Surfaces
2.5.6 Critical Surface Tension
Zisman Plot
2.5.7 Surface Tension Theories
2.5.8 Polar and Dispersive Components of Surface Tension
2.5.9 Acid-Base Interactions
2.5.10 Rheological Model
2.5.11 Summary
2.6 Electrostatic Attraction
2.7 Contaminations, Role of Water, or Humidity
2.8 Coupling Agents
2.9 Use of Glues (Adhesives)
2.10 Hydrophobic Recovery
References
Chapter 3 Interactions at Interface
3.1 Composites and Laminates
3.2 Laminate Processing
3.3 Polymers as Substrate or as Coating.
3.4 Chemical Reactions at Surfaces
3.4.1 Chemisorption
3.5 Reactions of Metal Atoms with Polyolefins
3.6 Reaction of Metal Atoms with O-Functional Groups at Polymer Surfaces
3.7 Reactions of Metal Atoms with Amino Groups on Polymer Surfaces
3.8 Silane and Siloxane Adhesion-Promoting Agents
References
Chapter 4 Chemical Bonds
4.1 Bonds in Polymers
4.1.1 Covalent chemical bonds chemical bonds in polymers polymers chemical bonds in C-H and C-C Bonds in Polymers
4.1.2 C-C Double, Triple, Conjugated, and Aromatic Bonds
4.1.3 C-O, C=O, O-C=O, and O=CO-O Bonds in Polymers
4.1.4 N-Containing Functional Groups
4.1.5 Chemical Bonds in Other Materials
4.2 Reactions of Chemical Bonds during Pretreatment
4.2.1 Aliphatic Chains
4.2.2 Preformed Degradation Products and Preferred Rearrangement Processes
4.3 Chemical Bonds at Interface
4.3.1 Polymer-Polymer Linking
4.3.2 Carbon-Metal Bonds
4.3.3 Covalent Bonds between Oxides and Polymers
4.3.4 Interface between Polymers and Transition Metals
References
Chapter 5 Functional Groups at Polymer Surface and Their Reactions
5.1 OH Groups at Surface
5.2 Primary Amino Groups at Polymer Surfaces
5.3 Carboxylic Groups as Anchor Points for Grafted Molecules
5.4 Bromination
5.5 Silane Bonds
5.6 Click Chemistry
5.7 ATRP
5.8 Grafting
5.8.1 Grafting of Fluorescence Markers onto Functional Groups at Polyolefin Surfaces
5.8.2 Covalent Linking of Spacer Bonded Dye Sensors onto Polyolefin Surfaces
5.8.3 Covalent Linking of Spacer Bonded Dye Sensors onto Polyolefin Surfaces Supported by a Cucurbituril Jacket
5.8.4 Grafting of Polyglycerols onto Polyolefin Surfaces for Introducing Antifouling Property
5.8.5 Summary of Complex Structures Covalently Grafted onto Polyolefin Surfaces
5.9 Polymers Deposited onto Silicon or Glass.
5.10 Molecular Entanglement of Macromolecules of Coating and Substrate at Polymer Surfaces (Interpenetrating Network at Interface)
References
Chapter 6 Pretreatment of Polyolefin Surfaces for Introducing Functional Groups
6.1 Situation at Polyolefin Surfaces
6.2 Physical and Chemical Attacks of Polyolefin Surfaces
6.3 A Few General Remarks to the Pretreatment of Polyolefins
6.4 Introduction of Functional Groups to polyolefin Surfaces
6.5 Usual Pretreatment Processes and Their Advantages and Disadvantages
6.5.1 Oxygen Plasma Exposure
6.5.2 Structural Degradation of Polymer on Exposure to Oxygen Plasma
6.5.3 Degradation of Polymers by Exposure to Oxygen Plasma
6.5.4 Cross-linking of Polymers by Plasma-Emitted UV Radiation
6.6 Surface Oxidation by Atmospheric-Pressure Plasmas (Dielectric Barrier Discharge-DBD, Atmospheric Pressure Glow Discharge-APGD or Corona Discharge, Spark Jet, etc.)
6.7 Flame Treatment
6.8 Silicoater Process (Pyrosil)
6.9 Laser Ablation
6.10 UV Irradiation with Excimer Lamps
6.11 Ozone
6.12 Mechanical Pretreatment
6.13 Cryogenic Blasting
6.14 Skeletonizing
6.15 Roughening for Mechanical Interlocking and Increasing of Surface Area by Plasma and Sputter Etching
6.16 Solvent Cleaning
6.17 Solvent Welding
6.18 Chemical Treatment by Chromic Acid and Chromo-Sulfuric Acid
6.19 Chemical Etching and Functionalizing of Fluorine-Containing Polymers
6.20 Oxyfluorination
6.21 Sulfonation
6.22 Sputtering for Film Deposition
6.23 Cross-linking as Adhesion Improving Pretreatment (CASING)
6.24 Monosort Functionalization and Selective Chemical Reactions
6.24.1 Well-Defined Functionalization of Polymer Surfaces by Classic Organic Chemistry.
6.24.2 Selective Monosort Functionalization of Polymer Surfaces by Oxygen Plasma Exposure and Post-Plasma Chemical Treatment for Producing OH Groups
References
Chapter 7 Adhesion-Promoting Polymer Layers
7.1 General
7.2 Historical Development
7.3 Influence of Plasma Wattage on Chemical Structure of Plasma Polymers
7.4 Pulsed-Plasma Polymerization
7.5 Pressure-Pulsed Plasma
7.6 Copolymerization in Pulsed Plasmas
7.7 Some Additional Details to the Mechanisms of Plasma Polymerization
7.8 Often-Observed Abnormal Side Reactions Occurring in the Plasma Only
7.9 Structure of Plasma Polymers
7.10 Use of Plasma Polymers as Adhesion-Promoting Layers
7.11 Adhesion Promotion of Very Thick Layers
7.12 Summary
References
Chapter 8 Monosort Functional Groups at Polymer Surfaces
8.1 Introduction
8.2 Bromination of Polyolefin Surface by Exposure to the Br2 Plasma
8.3 Bromoform as Precursor
8.4 Deposition of Plasma Polymers Carrying C-Br Groups
8.5 Loss in Bromine Groups by Wet-Chemical Processing
8.6 Other Halogenations
8.6.1 Chlorination
8.6.2 Fluorination
8.6.3 Iodination
8.6.4 Measuring the Electron Temperature in Haloform Plasmas
8.6.5 Comparison of Halogenation Processes
8.7 C-Br as Anchoring Point for Grafting
8.7.1 Changing the C-Br Functionalization into NH2 Functionalization
8.7.2 Other Functional Groups
8.7.3 Grafting onto C-Br Groups
8.8 Underwater Capillary Discharge Plasma or Glow Discharge Electrolysis (GDE)
8.9 Conclusions
References
Chapter 9 Chemical Grafting onto Monosort Functionalized Polyolefin Surfaces
9.1 General Aspects
9.2 Grafting of Spacers onto Radicals
9.3 Grafting of Spacers and Oligomers by Reaction with C-OH Groups at the Polyolefin Surface
9.4 Grafting of Linear Spacers and Oligomers onto C-Br Groups.
9.5 Introduction of Spacers with Siloxane Cages (POSS)
9.6 Grafting via Click Reaction
9.7 Influence of Spacers on the Metal-Polymer Adhesion
9.8 Summary
References
Chapter 10 Conclusions and Outlook to the New Interface Design
10.1 Introduction
10.2 Physical Effects Produced by Covalent Bonding of Metal to Polymer
10.3 Introduction of Functional Groups onto Polyolefin Surfaces Associated with Damaging of Polymer Structure Near Surface
10.4 Thermal Expansion Coefficients of Metals and Polymers
10.5 Differences between Al-Polyolefin and Polyolefin-Al Laminates
10.6 Protection of Covalent Metal-Polymer Bonds along the Interface
10.7 Reaction Pays for Grafting Spacer Molecules onto Polyolefin Surfaces
10.8 Special Requirements for Metal Deposition Especially Aluminum
10.9 Used Ways to Introduce Spacers for Maximum Adhesion
10.9.1 Spacer Attachment onto NH2 Groups
10.9.2 Spacer Grafting onto OH-Groups at Polymer Surface
10.9.3 Spacer Anchoring onto C-Br Groups
10.9.4 Silane Attachment
10.9.5 Silane Hydrolysis and Subsequent Partial Cross-linking
10.9.6 Adhesion Strength Measurements
10.9.7 Summary and Conclusions
References
Chapter 11 Short Treatise on Analysis Chemical Features
11.1 General
11.2 Bulk Analysis
11.2.1 Infrared Spectroscopy
11.2.2 UV-vis spectroscopy
11.2.3 NMR Spectroscopy
11.2.4 MALDI- and ESI-ToF-MS
11.2.5 HPLC and GPC/SEC
11.3 Surface Analysis
11.3.1 Sampling Depth
11.3.2 XPS
11.3.3 ToF-SIMS
11.3.4 SEIRA and IRRAS
References
Index
EULA.

Metal-Polymer Systems : Interface Design and Chemical Bonding.

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