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Fundamentals of ionic liquids : from chemistry to applications /
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Newark :
John Wiley & Sons, Incorporated,
2017.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Title Page; Copyright; Contents; Chapter 1 An Introduction to Ionic Liquids; 1.1 Prologue; 1.2 The Definition of an Ionic Liquid; 1.3 A Brief Perspective; 1.4 Aprotic Versus Protic ILs; 1.5 An Overview of IL Applications; 1.6 Key Properties and Techniques for Understanding ILs; 1.6.1 Viscosity; 1.6.2 Vapor Pressure; 1.6.3 Melting Point; 1.6.4 Nanostructure; 1.6.5 Thermal Properties; 1.6.6 Electrochemical Properties; 1.6.7 Conductivity and Ion Transport; 1.6.8 Computational Techniques; 1.7 New Materials Based on ILs; 1.8 Nomenclature and Abbreviations; References.
- Chapter 2 The Structure of Ions that Form Ionic Liquids2.1 Introduction; 2.2 Ionic Interactions and the Melting Point; 2.2.1 Thermodynamics of the Melting Point; 2.3 Effect of Ion Size and Crystal Packing; 2.3.1 Quantifying the Madelung Constant; 2.3.2 Computational Prediction of the Melting Point; 2.4 Charge Delocalization and Shielding; 2.5 Ion Asymmetry; 2.6 Influence of Cation Substituents; 2.7 Degrees of Freedom and Structural Disorder; 2.7.1 Polymorphism; 2.8 Short-Range Interactions
- Hydrogen Bonding; 2.9 Dications and Dianions; 2.10 Tm Trends in Other IL Families.
- 2.11 Concluding RemarksReferences; Chapter 3 Structuring of Ionic Liquids; 3.1 Introduction; 3.2 Ionicity, Ion Pairing and Ion Association; 3.3 Short-Range Structuring; 3.4 Structural Heterogeneity and Domain Formation; 3.5 Hydrogen Bonding and Structure; 3.6 Experimental Probes of Structure; 3.7 Simulation Approaches to Understanding Structure; 3.8 Structuring at Solid Interfaces; 3.9 Ionic Liquid Structure in Confined Spaces; 3.10 Impact of Structure on Reactivity and Application; 3.11 Concluding Remarks; References; Chapter 4 Synthesis of Ionic Liquids; 4.1 Introduction.
- 4.2 Synthesis of ILs4.2.1 Formation of the Cation: Quaternization/Alkylation; 4.2.2 Anion Exchange; 4.2.2.1 Metathesis; 4.2.2.2 Purification and Challenges of the Metathesis Reaction; 4.2.2.3 Ion Exchange; 4.2.3 Synthesis of ILs via the Carbonate Route; 4.2.4 Flow Reactors; 4.2.5 Solvate ILs; 4.2.6 Chloroaluminate ILs; 4.2.7 Task-Specific Ionic liquids (TSILs); 4.2.7.1 Alkoxy-Ammonium ILs; 4.2.7.2 Zwitterionic Liquids; 4.2.8 One-Pot Synthesis of Multi-Ion ILs; 4.2.9 Polymer Ionic Liquids (Poly-ILs); 4.2.10 Protic Ionic Liquids (PILs); 4.2.11 Chiral ILs.
- 4.3 Characterization and Analysis of ILs4.4 Concluding Remarks; References; Chapter 5 Physical and Thermal Properties; 5.1 Introduction; 5.2 Phase Transitions and Thermal Properties; 5.2.1 Thermal Analysis and the Key Transitions Defining the Liquid State; 5.2.2 Glass Transition, Glassy ILs, and the Kauzman Paradox; 5.2.3 The Ideal Glass Transition; 5.2.4 Influence of Ion Structure on Tg; 5.2.5 Solid-Solid Transitions; 5.2.5.1 Plastic Crystalline Phases; 5.2.5.2 Liquid Crystals; 5.2.6 Vaporization; 5.2.7 Thermal Decomposition; 5.2.8 Thermal Conductivity and Heat Capacity.