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Asymmetric Synthesis of Three-Membered Rings.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Newark :
John Wiley & Sons, Incorporated,
2017.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Title Page; Copyright; Contents; Preface; List of Abbreviations; Chapter 1 Asymmetric Cyclopropanation; 1.1 Introduction; 1.2 Simmons-Smith Cyclopropanation; 1.2.1 Chiral Substrates; 1.2.1.1 Chiral Allylic Alcohols; 1.2.1.2 Chiral Allylic Amines; 1.2.1.3 Chiral Acetal-Directed Cyclopropanations; 1.2.1.4 Simple Chiral Alkenes; 1.2.2 Chiral Auxiliaries; 1.2.3 Chiral Catalysts; 1.2.3.1 Charette's Ligand; 1.2.3.2 Other Stoichiometric Ligands; 1.2.3.3 Walsh' Procedure; 1.2.3.4 True Catalytic Procedures; 1.3 Transition-Metal-Catalyzed Decomposition of Diazoalkanes.
- 1.3.1 Intermolecular Cyclopropanation1.3.1.1 Chiral Auxiliaries; 1.3.1.2 Chiral Catalysts: Cobalt; 1.3.1.3 Chiral Catalysts: Copper; 1.3.1.4 Chiral Catalysts: Rhodium; 1.3.1.5 Chiral Catalysts: Ruthenium; 1.3.1.6 Chiral Catalyst: Other Metals; 1.3.2 Intramolecular Cyclopropanation; 1.3.2.1 Chiral Auxiliaries and Chiral Compounds; 1.3.2.2 Chiral Catalysts; 1.3.3 Chiral Stoichiometric Carbenes; 1.4 Michael-Initiated and Other Ring Closures; 1.4.1 Chiral Substrates; 1.4.2 Chiral Auxiliaries; 1.4.2.1 Chiral Michael Acceptors; 1.4.2.2 Chiral Nucleophiles; 1.4.3 Organocatalysis; 1.4.3.1 Ylides.
- 1.4.3.2 Nitrocyclopropanation1.4.3.3 Halocarbonyl Compounds; 1.4.4 Metal Catalysis; 1.4.5 Other Ring Closures; 1.5 Miscellaneous Reactions; 1.5.1 Rearrangement of Chiral Oxiranes; 1.5.2 Cycloisomerization of 1,n-Enynes; 1.5.3 Denitrogenation of Chiral Pyrazolines; 1.5.4 C-H Insertion; 1.5.5 Addition to Cyclopropenes; 1.5.6 Other Methods; 1.6 Conclusions; References; Chapter 2 Asymmetric Aziridination; 2.1 Introduction; 2.2 Aziridination Based on the Use of Chiral Substrates; 2.2.1 Addition to Alkenes; 2.2.1.1 Aziridination via Nitrene Transfer to Alkenes.
- 2.2.1.2 Aziridination via Addition-Elimination Processes2.2.1.3 Miscellaneous Reactions; 2.2.2 Addition to Imines; 2.2.2.1 Methylidation of Imines; 2.2.2.2 Aza-Darzens and Analogous Reactions; 2.2.2.3 Addition/Elimination Processes; 2.2.2.4 Miscellaneous Reactions; 2.2.3 Addition to Azirines; 2.2.4 Aziridination via Intramolecular Substitution; 2.2.4.1 From 1,2-Amino Alcohols; 2.2.4.2 From 1,2-Amino Halides; 2.2.4.3 From 1,2-Azido Alcohols; 2.2.4.4 From 1,2-Amino Sulfides and 1,2-Amino Selenides; 2.2.4.5 From Epoxides; 2.2.5 Miscellaneous Reactions.
- 2.3 Aziridination Based on the Use of Chiral Catalysts2.3.1 Aziridination via Nitrene Transfer to Alkenes; 2.3.1.1 Cu-Catalyzed Aziridination; 2.3.1.2 Rh-Catalyzed Aziridination; 2.3.1.3 Ru-Catalyzed Aziridination; 2.3.1.4 Catalysis by Other Metals; 2.3.1.5 Organocatalyzed Aziridination; 2.3.2 Aziridination via Carbene Transfer to Imines; 2.3.2.1 Carbene Methodology; 2.3.2.2 Sulfur-Ylide-Mediated Aziridination; 2.3.3 Miscellaneous Reactions; 2.3.4 Kinetic Resolutions of Aziridines; 2.4 Conclusions; References; Chapter 3 Asymmetric Epoxidation; 3.1 Introduction.