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Chemical Synthesis Using Highly Reactive Metals.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Somerset :
John Wiley & Sons, Incorporated,
2016.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Title Page ; Copyright Page; Contents; Preface; Chapter 1 Genesis of Highly Reactive Metals ; Chapter 2 General Methods of Preparation and Properties ; 2.1 General Methods for€Preparation of€Highly Reactive Metals; 2.2 Physical Characteristics of€Highly Reactive Metal€Powders; 2.3 Origin of€the€Metals' High Reactivity; References; Chapter 3 Zinc ; 3.1 General Methods for€Preparation of€Rieke Zinc; 3.2 Direct Oxidative Addition of€Reactive Zinc to€Functionalized Alkyl, Aryl, and€Vinyl Halides; Typical Preparation of 3-Fluorobenzylzinc Bromide ; Typical Preparation of 4-Cyanobutylzinc Bromide.
- 3.7 Intramolecular Cyclizations and€Conjugate Additions Mediated by Rieke Zinc3.8 The Formation and€Chemistry of€Secondary and€Tertiary Alkylzinc Halides; 3.9 Electrophilic Amination of€Organozinc Halides; 3.10 Reformatsky and Reformatsky-Like Reagents and Their Chemistry ; Synthesis of€Reformatsky Reagent in€THF; Synthesis of€Reformatsky Reagent in€Diethyl Ether; 3.11 Configurationally Stable Organozinc Reagents and€Intramolecular Insertion Reactions; 3.12 Preparation of€Tertiary Amides via Aryl, Heteroaryl, and€Benzyl Organozinc Reagents; 3.13 Preparation of 5-Substituted-2-Furaldehydes.
- Results and€DiscussionGeneral Procedure for Pd-Catalyzed Cross-Coupling Reactions ; 3.14 Preparation and Chemistry of 4-Coumarylzinc Bromide ; 3.15 Preparation and Cross-Coupling of 2-Pyridyl and 3-Pyridylzinc Bromides ; Results and€Discussion; Conclusions; Experimental; General; Preparation of 2-Pyridylzinc Bromide (P1) ; Preparation of 3-Pyridylzinc Bromide (P7) ; General Procedure for Copper-Free Coupling Reactions ; Pd-Catalyzed Coupling Reaction with 4-Iodoanisole (10b) ; Preparation of€Bipyridines; Pd-Catalyzed Coupling Reaction with Haloanilines.