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Synthetic Methods for Conjugated Polymer and Carbon Materials.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Somerset :
John Wiley & Sons, Incorporated,
2016.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Title Page; Copyright; Table of Contents; List of Contributors; Chapter 1: Stille Polycondensation: A Versatile Synthetic Approach to Functional Polymers; 1.1 Introduction; 1.2 Reaction Mechanism; 1.3 Reaction Conditions; 1.4 Examples of Functional Materials Synthesized by Stille Polycondensation; 1.5 Challenge and Outlook; 1.6 Summary; References; Chapter 2: Suzuki Polycondensation; 2.1 Introduction; 2.2 Mechanism of Suzuki Coupling and Suzuki Polycondensation; 2.3 Catalysts; 2.4 Reaction Conditions for Suzuki Coupling; 2.5 Side Reactions; 2.6 AB versus AA/BB Suzuki Polycondensation.
- 2.7 Monomer Purity, Stoichiometry, and Solvents2.8 Monomers for SPC; 2.9 Chain Growth SPC; 2.10 Scope and Applications of SPC; 2.11 Conclusion; References; Chapter 3: Controlled Synthesis of Conjugated Polymers and Block Copolymers; 3.1 Introduction; 3.2 Approaches to Controlled Polymerizations; 3.3 End-Functionalized Polymers; 3.4 Block Copolymers; 3.5 Other Copolymers; References; Chapter 4: Direct (Hetero)arylation Polymerization; 4.1 Introduction; 4.2 First Examples of Direct (Hetero)arylation Polymerization; 4.3 Selectivity and Reactivity Problems.
- 4.4 En Route to Defect-Free Conjugated Polymers4.5 Outlook; References; Chapter 5: Continuous Flow Synthesis of Conjugated Polymers and Carbon Materials; 5.1 Introduction to Flow Chemistry; 5.2 Conjugated Polymers; 5.3 Carbon Materials; 5.4 Material Processing; 5.5 Summary; References; Chapter 6: Synthesis of Structurally Defined Nanographene Materials through Oxidative Cyclodehydrogenation; 6.1 Introduction; 6.2 Synthesis of Nanographene Molecules through Oxidative Cyclodehydrogenation; 6.3 Bottom-Up Synthesis of Graphene Nanoribbons; 6.4 Conclusions; References.
- Chapter 7: Photochemical and Direct C H Arylation Routes toward Carbon Nanomaterials7.1 Introduction; 7.2 Photochemical Routes toward PAHs and Carbon Nanomaterials; 7.3 Intramolecular Direct Arylation C H; References; Chapter 8: Carbon-Rich Materials from sp-Carbon Precursors; 8.1 Introduction; 8.2 Carbyne; 8.3 Solid-State Reactions of Polyynes: Topochemical Polymerizations; 8.4 Diyne Polymerization; 8.5 Tubular Structures; 8.6 Beyond Diynes
- Topochemical Polymerization of Polyynes; 8.7 Toward "Nanographene"; 8.8 Pentalenes; 8.9 Modification of sp-Precursors with Tetracyanoethylene (TCNE).
- 8.10 Thermal Dimerization of Cumulenes8.11 Outlook: From Solution to Surface?; 8.12 Summarizing Comments; Acknowledgments; References; Index; End User License Agreement.