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Essentials of pericyclic and photochemical reactions /
This book provides a concise introduction to pericyclic and photochemical reactions for organic synthesis. In the first part about pericyclic reactions, the author explains electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and group transfer reactions. The second part on...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Cham, Switzerland :
Springer,
2016.
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| Colección: | Lecture notes in chemistry ;
93. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Preface; Contents; Abbreviations; List of Figures; List of Tables; List of Schemes; Pericyclic Reactions; 1 General Aspects of Pericyclic Reactions; 1.1 Introduction; 1.2 Molecular Orbitals and Their Symmetry Properties; 1.3 Classification of Pericyclic Reactions; 1.4 Concertedness of Pericyclic Reactions; 1.5 Orbital Symmetry Property of Pericyclic Reactions; 1.6 Further Reading; References; 2 Electrocyclic Reactions; 2.1 Introduction; 2.2 Orbital Symmetry Basis for Stereospecificity; 2.3 The Orbital Correlation Diagrams of Reactants and Products.
- 2.4 Applications of Neutral Conjugated Systems in Electrocyclic Reactions2.5 Applications of Ionic Conjugated Systems in Electrocyclic Reactions; 2.6 Problems; 2.7 Further Reading; References; 3 Cycloaddition Reactions; 3.1 Introduction; 3.2 [2+2]-Cycloaddition Reactions; 3.2.1 Overview of Thermal and Photochemical [2+2]-Cycloaddition Reactions; 3.2.2 Applications of [2+2]-Cycloaddition Reactions; 3.3 [4+2]-Cycloaddition Reactions; 3.3.1 The Diels-Alder Reactions; 3.3.1.1 Overview of the Diels-Alder Reaction; 3.3.1.2 Regioselectivity; 3.3.1.3 Stereochemistry.
- 3.3.1.4 Stereochemical Features of the Products3.3.1.5 Substituent Effects on the Reaction Rates; 3.3.1.6 The Dienes and Dienophiles; 3.3.1.7 Lewis Acid-Catalyzed Diels-Alder Reactions; 3.3.1.8 Applications of Neutral Dienes and Dienophiles in Diels-Alder Reactions; 3.3.1.9 Applications of Ionic Dienes and Dienophiles in Diels-Alder Reactions; 3.3.1.10 Enantioselective Diels-Alder Reactions; Enantioselective D-A Reactions Using Chiral Auxiliary; Enantioselective D-A Reactions Using Chiral Catalysts; 3.3.1.11 Intramolecular Diels-Alder Reactions; 3.3.1.12 The Retro-Diels-Alder Reactions.
- 3.3.1.13 1,3-Dipolar Cycloaddition ReactionsOverview of 1,3-Dipolar Cycloaddition Reactions; Methods for Generation of 1,3-Dipolar Compounds; Regioselectivity and Stereoselectivity of 1,3-Dipolar Cycloaddition Reactions; Synthetic Applications of Intermolecular 1,3-Dipolar Cycloaddition Reactions; 3.3.1.14 Synthetic Applications of Intramolecular 1,3-Dipolar Cycloaddition Reactions; 3.4 Cycloaddition Reactions of More Than Six Electrons Systems: [4+4]-, [6+6]-, [6+4]-, [8+2]-, [12+2]-, and [14+2]-Cycloadditions; 3.5 Cheletropic Reactions; 3.5.1 Overview of Cheletropic Reactions.
- 3.5.2 Applications of Cheletropic Reactions3.6 Problems; 3.7 Further Reading; References; 4 Sigmatropic Rearrangements; 4.1 Introduction; 4.2 Orbital Symmetry Basis for Allowed and Forbidden Sigmatropic Rearrangements and Their Stereochemistry; 4.2.1 Orbital Symmetry Analysis of [1,3]-, [1,5]-, and [1,7]-Sigmatropic Shifts of Hydrogen and Alkyl Groups; 4.2.2 Orbital Symmetry Analysis of [3,3]- and [2,3]-Sigmatropic Rearrangements; 4.3 [1,3]-, [1,5]-, and [1,7]-Sigmatropic Hydrogen and Alkyl Shifts and Their Applications; 4.3.1 [1,3]-Sigmatropic Hydrogen and Alkyl Shifts.