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Essentials of pericyclic and photochemical reactions /

This book provides a concise introduction to pericyclic and photochemical reactions for organic synthesis. In the first part about pericyclic reactions, the author explains electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and group transfer reactions. The second part on...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Dinda, Biswanath, 1947- (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cham, Switzerland : Springer, 2016.
Colección:Lecture notes in chemistry ; 93.
Temas:
Acceso en línea:Texto completo

MARC

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245 1 0 |a Essentials of pericyclic and photochemical reactions /  |c Biswanath Dinda. 
264 1 |a Cham, Switzerland :  |b Springer,  |c 2016. 
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490 1 |a Lecture notes in chemistry,  |x 0342-4901 ;  |v volume 93 
505 0 |a Preface; Contents; Abbreviations; List of Figures; List of Tables; List of Schemes; Pericyclic Reactions; 1 General Aspects of Pericyclic Reactions; 1.1 Introduction; 1.2 Molecular Orbitals and Their Symmetry Properties; 1.3 Classification of Pericyclic Reactions; 1.4 Concertedness of Pericyclic Reactions; 1.5 Orbital Symmetry Property of Pericyclic Reactions; 1.6 Further Reading; References; 2 Electrocyclic Reactions; 2.1 Introduction; 2.2 Orbital Symmetry Basis for Stereospecificity; 2.3 The Orbital Correlation Diagrams of Reactants and Products. 
505 8 |a 2.4 Applications of Neutral Conjugated Systems in Electrocyclic Reactions2.5 Applications of Ionic Conjugated Systems in Electrocyclic Reactions; 2.6 Problems; 2.7 Further Reading; References; 3 Cycloaddition Reactions; 3.1 Introduction; 3.2 [2+2]-Cycloaddition Reactions; 3.2.1 Overview of Thermal and Photochemical [2+2]-Cycloaddition Reactions; 3.2.2 Applications of [2+2]-Cycloaddition Reactions; 3.3 [4+2]-Cycloaddition Reactions; 3.3.1 The Diels-Alder Reactions; 3.3.1.1 Overview of the Diels-Alder Reaction; 3.3.1.2 Regioselectivity; 3.3.1.3 Stereochemistry. 
505 8 |a 3.3.1.4 Stereochemical Features of the Products3.3.1.5 Substituent Effects on the Reaction Rates; 3.3.1.6 The Dienes and Dienophiles; 3.3.1.7 Lewis Acid-Catalyzed Diels-Alder Reactions; 3.3.1.8 Applications of Neutral Dienes and Dienophiles in Diels-Alder Reactions; 3.3.1.9 Applications of Ionic Dienes and Dienophiles in Diels-Alder Reactions; 3.3.1.10 Enantioselective Diels-Alder Reactions; Enantioselective D-A Reactions Using Chiral Auxiliary; Enantioselective D-A Reactions Using Chiral Catalysts; 3.3.1.11 Intramolecular Diels-Alder Reactions; 3.3.1.12 The Retro-Diels-Alder Reactions. 
505 8 |a 3.3.1.13 1,3-Dipolar Cycloaddition ReactionsOverview of 1,3-Dipolar Cycloaddition Reactions; Methods for Generation of 1,3-Dipolar Compounds; Regioselectivity and Stereoselectivity of 1,3-Dipolar Cycloaddition Reactions; Synthetic Applications of Intermolecular 1,3-Dipolar Cycloaddition Reactions; 3.3.1.14 Synthetic Applications of Intramolecular 1,3-Dipolar Cycloaddition Reactions; 3.4 Cycloaddition Reactions of More Than Six Electrons Systems: [4+4]-, [6+6]-, [6+4]-, [8+2]-, [12+2]-, and [14+2]-Cycloadditions; 3.5 Cheletropic Reactions; 3.5.1 Overview of Cheletropic Reactions. 
505 8 |a 3.5.2 Applications of Cheletropic Reactions3.6 Problems; 3.7 Further Reading; References; 4 Sigmatropic Rearrangements; 4.1 Introduction; 4.2 Orbital Symmetry Basis for Allowed and Forbidden Sigmatropic Rearrangements and Their Stereochemistry; 4.2.1 Orbital Symmetry Analysis of [1,3]-, [1,5]-, and [1,7]-Sigmatropic Shifts of Hydrogen and Alkyl Groups; 4.2.2 Orbital Symmetry Analysis of [3,3]- and [2,3]-Sigmatropic Rearrangements; 4.3 [1,3]-, [1,5]-, and [1,7]-Sigmatropic Hydrogen and Alkyl Shifts and Their Applications; 4.3.1 [1,3]-Sigmatropic Hydrogen and Alkyl Shifts. 
504 |a Includes bibliographical references and index. 
588 0 |a Online resource; title from PDF title page (SpringerLink, viewed December 2, 2016). 
520 |a This book provides a concise introduction to pericyclic and photochemical reactions for organic synthesis. In the first part about pericyclic reactions, the author explains electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and group transfer reactions. The second part on photochemistry is dedicated to photochemical reactions of a variety of compound classes, including alkenes, dienes, and polyenes, carbonyl compounds, and aromatic compounds. Additionally, photofragmentation reactions are described in a dedicated chapter. The last chapter gives an outlook on applications of photochemistry and natural photochemical phenomena. Both parts start with a comprehensive presentation of the general principles of the pericyclic and photochemical reactions. All chapters are rich in examples, which help illustrate the explained principles and establish ties to results and trends in recent research. Additionally, each chapter offers exercises for students, and solutions to the problems are provided in a separate appendix. This book nicely illustrates the utility of pericyclic and photochemical reactions and provides students and researchers with the tools to apply them routinely for an efficient synthesis of complex organic molecules. It will therefore appeal to advanced undergraduate students, graduate and postgraduate students, and even to practitioners and scientists in the field of organic synthesis. The rich examples and exercises will also make it a versatile tool for teachers and lecturers. 
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650 0 |a Pericyclic reactions. 
650 0 |a Photochemistry. 
650 6 |a Réactions péricycliques. 
650 6 |a Photochimie. 
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650 7 |a Organic chemistry.  |2 bicssc 
650 7 |a SCIENCE  |x Chemistry  |x Physical & Theoretical.  |2 bisacsh 
650 7 |a Pericyclic reactions  |2 fast 
650 7 |a Photochemistry  |2 fast 
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