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Polymer nanocomposites : advances in filler surface modification techniques /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Nova Science Publishers, Inc.,
[2009]
|
| Colección: | Nanotechnology science and technology series.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- POLYMER NANOCOMPOSITES:ADVANCES IN FILLER SURFACEMODIFICATION TECHNIQUES; Contents; Preface; Need of New Surface Modifications; Abstract; 1.1. Introduction; 1.2. Conventional Polymer NanocompositeSystems; 1.3. Unconventional Surface Modifications; 1.4. Modified Fillers with LongChains Attached on the Surface; References; Exfoliation through Esterificationfor Clay Polymer Nanocomposites; Abstract; 2.1. Introduction; 2.1.1. Clay Structure and General Properties; 2.1.2. Processing of Polymer-Clay Nanocomposites; 2.1.3. Morphology of Polymer-Clay Nanocomposites; 2.1.4. Organo-Clays.
- 2.2. Exfoliation through Esterification2.2.1. Criterion to Bring about the Exfoliation; 2.2.2. Esterification on Clay Surfaces; 2.3. Conclusions; References; Grafting of Polymer Chains'From' the Clay Surface; Abstract; 3.1. Introduction; 3.2. Polymer Brushes Prepared by In-SituFree Radical Polymerization; 3.3. Polymer Brushes Prepared by In-SituControlled/Living Radical Polymerization (C/LRP); 3.4 Polymer Brushes Prepared by In-Situ Anionic Polymerization; 3.5 Polymer Brushes Prepared by In-Situ Ring Opening Polymerization; 3.6. Polymer Brushes Initiated by Intercalated Catalysts.
- 3.7 Polymer Chains on the Edges of Clay Sheets Prepared by In-SituPolymerization3.8. Summary; References; Role of Monocationic and BicationicInitiators on the Grafting of PolymerChains 'from' the Clay Surface; Abstract; 4.1. Introduction; 4.2. Significance of Initiator BoundClay Layers for Polymer Grafting; 4.3. Types of Polymer Grafting; 4.3.1. Polymer Grafting "to" the Clay Surface; 4.3.2. Polymer Grating "from" the Clay Surface; 4.4. Types of Cationic Initiatorsfor Polymer Grafting; 4.4.1. Synthesis of Monocationic Initiator (Asymmetric type).
- 4.4.2 Synthesis of Bicationic Initiator (Symmetric type)4.5. Cationic Initiator-Bound Clay Layers; 4.5.1. Preparation of AHPA Derivative Initiator Bound Clay Layers; 4.5.2. Preparation of ACVA Derivative Initiator Bound Clay Layers; 4.5.3. Partial Initiator Bound Clay Surface with Other AlkylammoniumSurfactant; 4.6. Possible Orientations of InitiatorMolecules on the Clay Surface; 4.7. Role of Bicationic Initiators forthe Polymer Grafting; 4.8. Role of MonocationicInitiators for Polymer Grafting; 4.9. Monocationic vs Bicationic Initiators.
- 4.10. Thermal and Mechanical Properties of Polymer Clay Nanocomposites4.11. Summary; References; Grafting from Clay Surfaces Using AtomTransfer Radical Polymerization; Abstract; 5.1. Introduction; 5.2. Basics Structures of Layered Silicates; 5.2.1 Layered Silicate Structure; 5.2.2 Structures within PLSNs; 5.3 Synthetic Methods for the Preparation of PLSNs; 5.4 Living Radical Polymerizations & AtomTransfer Radical Polymerization; 5.5 Use of ATRP to Graft Polymer Chains from Clay Surfaces; 5.6. Block Copolymer-ClayNanocomposites using ATRP; Conclusions; Acknowledgements; References.