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Modeling of liquid phases. Volume 2 /
This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of sma...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London : New York :
ISTE ; Wiley,
2015.
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| Colección: | Chemical engineering series (ISTE Ltd.)
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Title Page; Copyright ; Contents; Preface; Notations and Symbols; 1: Pure Liquids; 1.1. Macroscopic modeling of liquids; 1.2. Distribution of molecules in a liquid; 1.2.1. Molecular structure of a non-associated liquid; 1.2.2. The radial distribution function; 1.2.3 The curve representative of the radial distribution function; 1.2.4. Calculation of the macroscopic thermodynamic values; 1.3. Models extrapolated from gases or solids; 1.3.1. Guggenheim's smoothed potential model; 1.3.2. Mie's harmonic oscillator model.
- 1.3.3. Determination of the free volume on the basis of the dilation and the compressibility1.4. Lennard-Jones and Devonshire cellular model; 1.5. Cellular and vacancies model; 1.6. Eyring's semi-microscopic formulation of the vacancy model; 1.7. Comparison between the different microscopic models and experimental results; 2: Macroscopic Modeling of Liquid Molecular Solutions; 2.1. Macroscopic modeling of the Margules expansion; 2.2. General representation of a solution with several components; 2.3. Macroscopic modeling of the Wagner expansions.
- 2.3.1. Definition of the Wagner interaction coefficients2.3.2. Example of a ternary solution: experimental determination of Wagner's interaction coefficients; 2.4. Dilute ideal solutions; 2.4.1. Thermodynamic definition of a dilute ideal solution; 2.4.2. Activity coefficients of a component with a pure-substance reference; 2.4.3. Excess Gibbs energy of an ideal dilute solution; 2.4.4. Enthalpy of mixing for an ideal dilute solution; 2.4.5. Excess entropy of a dilute ideal solution; 2.4.6. Molar heat capacity of an ideal dilute solution at constant pressure; 2.5. Associated solutions.
- 2.5.1. Example of the study of an associated solution2.5.2. Relations between the chemical potentials of the associated solution; 2.5.3. Calculating the extent of the equilibrium in an associated solution; 2.5.4. Calculating the activity coefficients in an associated solution; 2.5.5. Definition of a regular solution; 2.5.6. Strictly-regular solutions; 2.5.7. Macroscopic modeling of strictly-regular binary solutions; 2.5.8. Extension of the model of a strictly-regular solution to solutions with more than two components; 2.6. Athermic solutions.
- 2.6.1. Thermodynamic definition of an athermic solution2.6.2. Variation of the activity coefficients with temperature in an athermic solution; 2.6.3. Molar entropy and Gibbs energy of mixing for an athermic solution; 2.6.4. Molar heat capacity of an athermic solution; 3: Microscopic Modeling of Liquid Molecular Solutions; 3.1. Models of binary solutions with molecules of similar dimensions; 3.1.1. The microscopic model of a perfect solution; 3.1.2. Microscopic description of strictly-regular solutions; 3.1.3. Microscopic modeling of an ideal dilute solution.