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Domino and intramolecular rearrangement reactions as advanced synthetic methods in glycoscience /
The book consists of a brief introduction, a foreward provided by professor Danishefsky of Columbia University, and about 14 - 16 chapters, each written by one or two eminent scholars/authors describing their recent research in the area of either domino reactions or intramolecular rearrangements in...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, New Jersey :
Wiley,
[2016]
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Machine generated contents note: 1.1. Introduction / Hélène Pellissier
- 1.2. Asymmetric Domino Reactions using Chiral Carbohydrate Derivatives / Hélène Pellissier
- 1.2.1. Stereocontrolled Domino Reactions of Chiral Carbohydrate Derivatives / Hélène Pellissier
- 1.2.2. Enantioselective Domino Reactions Catalyzed by Chiral Carbohydrate Derivatives / Hélène Pellissier
- 1.3. Conclusions / Hélène Pellissier
- References / Hélène Pellissier
- 2.1. Introduction / Benjamin Voigt / Rainer Mahrwald
- 2.2.C-Glycosides / Benjamin Voigt / Rainer Mahrwald
- 2.3. Amine-Catalyzed Knoevenagel-Additions / Benjamin Voigt / Rainer Mahrwald
- 2.4. Multicomponent Reactions / Benjamin Voigt / Rainer Mahrwald
- 2.5. Amine-Catalyzed Cascade Reactions of Ketoses with 1,3-Dicarbonyl Compounds / Benjamin Voigt / Rainer Mahrwald
- 2.6. Conclusions / Benjamin Voigt / Rainer Mahrwald
- References / Benjamin Voigt / Rainer Mahrwald
- 3.1. Introduction / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2. Bernet-Vasella Reaction / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.1. Domino Reductive Fragmentation/Reductive Amination / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.2. Domino Reductive Fragmentation/Barbier-Type Allylation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.3. Domino Reductive Fragmentation/Barbier-Type Propargylation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.4. Domino Reductive Fragmentation/Vinylation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.5. Domino Reductive Fragmentation/Alkylation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.6. Domino Reductive Fragmentation/Olefination / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.2.7. Domino Reductive Fragmentation/Nitromethylation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.3. Reductive Ring Contraction / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.3.1. Ring Opening/Ketyl-Olefin Annulation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.3.2. Ring Opening/Intramolecular Carbonyl Alkylation / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 3.4. Conclusions / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- References / Raquel G. Soengas / Sara M. Tomé / Artur M.S. Silva
- 4.1. Introduction / Vasco Cachatra / Amélia P. Rauter
- 4.2. Domino Reactions Toward Butenolides Fused to Six-Membered Ring Sugars and Thio Sugars / Vasco Cachatra / Amélia P. Rauter
- 4.3. Exploratory Chemistry for Amino Sugars' Domino Reactions / Vasco Cachatra / Amélia P. Rauter
- 4.4. Domino Reactions Toward Sugar Ring Contraction / Vasco Cachatra / Amélia P. Rauter
- 4.4.1. Pyrano-Furano Ring Contraction / Vasco Cachatra / Amélia P. Rauter
- 4.4.2. Ring Contraction of Furans to Oxetanes / Vasco Cachatra / Amélia P. Rauter
- 4.5. Macrocyclic Bislactone Synthesis via Domino Reaction / Vasco Cachatra / Amélia P. Rauter
- 4.6. Sugar Deoxygenation by Domino Reaction / Vasco Cachatra / Amélia P. Rauter
- 4.7. Conclusions / Vasco Cachatra / Amélia P. Rauter
- References / Vasco Cachatra / Amélia P. Rauter
- 5.1. Introduction / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.2.(5,6-Dihydro-1,4-dithiin-2-y1)Methanol: Not Simply a Homologating Agent / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.3. Sulfur-Assisted Multistep Processes and Their Use in the De Novo Synthesis of Glycostructures / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.3.1. Three Steps in One Process: Double Approach to 4-Deoxy L-(and D- )-Hexoses / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.3.2. Five Steps in One Process: The Domino Way to L-Hexoses (and Their Derivatives) / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.3.3. Up to Six Steps in One Process: 4'-Substituted Nucleoside Synthesis / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.3.4. Eight Steps in One Process: Beyond Achmatowicz Rearrangement / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.4. Concluding Remarks / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 5.5. Acknowledgments / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- References / Daniele D'Alonzo / Giovanni Palumbo / Annalisa Guaragna
- 6.1. Introduction / Zbigniew J. Witczak / Roman Bielski
- 6.2. Classification and Reaction Mechanism / Zbigniew J. Witczak / Roman Bielski
- 6.3. Conclusions / Zbigniew J. Witczak / Roman Bielski
- References / Zbigniew J. Witczak / Roman Bielski
- 7.1. Introduction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2. Convertible Isocyanides / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.1. CIC Employed in the Ugi Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.2. Resin-Bound CICs / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.3. CIC Employed in the Ugi-Smile Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.4. CIC Employed in the Joullié-Ugi Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.5. CIC Employed in the Passerini Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.6. CIC Employed in the Groebke-Blackburn-Bienaymé Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.7. CIC Employed in the Diels-Alder Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.8. Monosaccharide Isocyanides Employed in the Ugi and Passerini Reaction / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.2.9. Methyl isocyanide in the Preparation of the Hydroxy DKP Thaxtomin A / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 7.3. Conclusions / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- References / Soumava Santra / Tonja Andreana / Jean-Paul Bourgault / Peter R. Andreana
- 8.1. Introduction / Daniel B. Werz
- 8.2. Spiroketals via a Domino Oxidation/Rearrangement Sequence / Daniel B. Werz
- 8.3. Chromans and Isochromans via Domino Carbopalladation/Carbopalladation/Cyclization Sequence / Daniel B. Werz
- References / Daniel B. Werz
- 9.1. Introduction / Roman Bielski / Zbigniew J. Witczak
- 9.2. Classification / Roman Bielski / Zbigniew J. Witczak
- 9.3. Chapman Rearrangement / Zbigniew J. Witczak / Roman Bielski
- 9.4. Hofmann Rearrangement / Zbigniew J. Witczak / Roman Bielski
- 9.5. Cope Rearrangement / Zbigniew J. Witczak / Roman Bielski
- 9.6. Ferrier Rearrangement / Roman Bielski / Zbigniew J. Witczak
- 9.7. Claisen Rearrangement / Zbigniew J. Witczak / Roman Bielski
- 9.8. Overman Rearrangement / Roman Bielski / Zbigniew J. Witczak
- 9.9. Baeyer-Villiger Rearrangement / Zbigniew J. Witczak / Roman Bielski
- 9.10. Ring Contraction / Roman Bielski / Zbigniew J. Witczak
- 9.11. Conclusions / Zbigniew J. Witczak / Roman Bielski
- References / Zbigniew J.
- Witczak / Roman Bielski
- 10.1. Introduction / Agnieszka Gajewska / Anna Osuch-Kwiatkowska / Stawomir Jarosz / Maciej Cieplak
- 10.2. Rearrangements Without Changing the Sugar Skeleton / Agnieszka Gajewska / Anna Osuch-Kwiatkowska / Stawomir Jarosz / Maciej Cieplak
- 10.3. Rearrangements Connected with the Change of Sugar Unit(s) / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.4. Rearrangements Changing the Structure of a Sugar Skeleton / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.5. Rearrangement of the Sugar Skeleton Discovered En Route to Higher-Carbon Sugars / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.5.1. Synthesis of Higher-Carbon Sugars by the Wittig-Type Methodology / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.5.2. The AcetyleneNinyltin Methodology in the Synthesis of HCS / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.5.3. The Allyltin Methodology in the Synthesis of HCS / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.5.4. Rearrangement of the Structure of HCS / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.5.5. Synthesis of Polyhydroxylated Carbocyclic Derivatives with Large Rings / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 10.6. Conclusions / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- Acknowledgments / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- References / Stawomir Jarosz / Anna Osuch-Kwiatkowska / Agnieszka Gajewska / Maciej Cieplak
- 11.1. Introduction / Roman Bielski / Zbigniew J. Witczak
- 11.2. Additions to the Double Bond of the Enone System Leading to the Formation of New Rings / Roman Bielski / Zbigniew J. Witczak
- 11.3. Reductions of the Carbonyl Group Followed by Various Reactions of the Formed Alcohol / Roman Bielski / Zbigniew J. Witczak
- 11.4. Functionalization of the Carbonyl Group by Forming Carbon-Nitrogen Double Bonds (Oximes, Enamines, Hydrazines) / Roman Bielski / Zbigniew J. Witczak
- 11.5. Additions (But Not Cycloadditions) (Particularly Michael Additions) to the Double Bond of the Enone / Zbigniew J. Witczak / Roman Bielski
- 11.6. Enzymatic Reactions of Levoglucosenone / Roman Bielski / Zbigniew J. Witczak
- 11.7. High-Tonnage Products from Levoglucosenone / Roman Bielski / Zbigniew J. Witczak
- 11.7.1. Overman and Allylic Xanthate Rearrangement / Roman Bielski / Zbigniew J. Witczak
- 11.8. Conclusions / Roman Bielski / Zbigniew J. Witczak
- References / Roman Bielski / Zbigniew J. Witczak
- 12.1. Introduction / Vikram Basava / Emi Hanawa / Cecilia H. Ma.