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Endohedral Metallofullerenes : Fullerenes with Metal Inside.
Endohedral Metallofullerenes: Fullerenes with Metal Inside presents a comprehensive survey of the current state of knowledge on endohedral metallofullerenes, from preparation to functionalization, reactivity and applications. Following a brief historical overview, the book describes methods for synt...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2015.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Title Page; Copyright Page; Contents; Foreword; Preface; Personal Reflection
- Nori Shinohara; Chapter 1 Introduction; 1.1 The First Experimental Evidence of Metallofullerenes; 1.2 Early Years of Metallofullerene Research; 1.3 Conventional and IUPAC Nomenclature for Metallofullerenes; References; Chapter 2 Synthesis, Extraction, and Purification; 2.1 Synthesis of Endohedral Metallofullerenes; 2.1.1 Laser-Furnace Synthesis; 2.1.2 DC Arc-Discharge Synthesis; 2.1.3 Ion Implantation Technique; 2.2 Solvent Extraction of Metallofullerenes from Primary Soot; 2.3 Purification and Isolation by HPLC.
- 2.4 Fast Separation and Purification with Lewis AcidsReferences; Chapter 3 Molecular and Crystal Structures; 3.1 Endohedral or Exohedral? A Big Controversy; 3.2 Structural Analyses; 3.2.1 Confirmation on Endohedral Structures as Determined by Synchrotron X-Ray Powder Diffraction; 3.2.2 Dynamics of Metal Atoms within the Fullerene Cage; 3.2.3 C60-Based Metallofullerene: Li@C60; 3.2.4 Crystal Structures; 3.2.5 Single-Crystal Structural Characterization; References; Chapter 4 Electronic States and Structures; 4.1 Electron Transfer in Metallofullerenes.
- 4.2 ESR Evidence on the Existence of Structural Isomers4.3 Electrochemistry of Metallofullerenes; 4.4 Similarity in the UV-Vis-NIR Absorption Spectra; 4.5 Fermi Levels and the Electronic Structures; 4.6 Metal-Cage Vibration within Metallofullerenes; References; Chapter 5 Carbide and Nitride Metallofullerenes; 5.1 Discovery of Carbide Metallofullerenes; 5.2 Fullerene Quantum Gyroscope: an Ideal Molecular Rotor; 5.3 Nitride Metallofullerenes; References; Chapter 6 Non-Isolated Pentagon Rule Metallofullerenes; 6.1 Isolated Pentagon Rule; 6.2 Non-IPR Metallofullerenes; References.
- Chapter 7 Oxide and Sulfide Metallofullerenes7.1 Oxide Metallofullerenes; 7.2 Sulfide Metallofullerenes; References; Chapter 8 Non-metal Endohedral Fullerenes; 8.1 Nitrogen-Containing N@C60; 8.2 Phosphorous-Containing P@C60; 8.3 Inert Gas Endohedral Fullerenes He@C60, Ne@C60, Ar@C60, Kr@C60, and Xe@C60; 8.4 Hydrogen-Containing H2@C60; 8.5 Water-Containing H2O@C60; References; Chapter 9 Scanning Tunneling Microscopy Studies of Metallofullerenes; 9.1 STM Studies of Metallofullerenes on Clean Surfaces; 9.2 Metallofullerenes as Superatom; 9.3 STM/STS Studies on Metallofullerene Layers.
- 9.4 STM/STS Studies on a Single Metallofullerene MoleculeReferences; Chapter 10 Magnetic Properties of Metallofullerenes; 10.1 Magnetism of Mono-metallofullerenes; 10.2 SXAS and SXMCD Studies of Metallofullerenes; References; Chapter 11 Organic Chemistry of Metallofullerenes; 11.1 Cycloaddition Reactions; 11.1.1 Disilylation; 11.1.2 Azomethine Ylides; 11.1.3 Bingel Cyclopropanation; 11.1.4 [4+2] Diels-Alder Cycloaddition; 11.1.5 [2+2] Cycloaddition; 11.1.6 Carbenes; 11.2 Radical Addition Reactions; 11.3 Miscellaneous Reactions; 11.4 Donor-Acceptor Dyads; 11.5 Bis-adduct Formation.