Polyethylene-based blends, composites and nanocomposites /

"The book focusses on the recent technical research accomplishments in the area of polyethylene-based blends, composites and nanocomposites by looking at the various aspects of processing, morphology, properties and applications. In particular, the book details the important developments in are...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: P. M., Visakh (Editor ), Martínez Morlanes, María Jose (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken, New Jersey : Wiley, [2015]
Temas:
Polyethylene > Analysis.
Nanocomposites (Materials)
Polyéthylène > Analyse.
Matériaux nanocomposites.
TECHNOLOGY & ENGINEERING > Chemical & Biochemical.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Title Page
  • Copyright
  • Contents
  • Preface
  • 1 Polyethylene-Based Blends, Composites and Nanocomposites: State-of-the-Art, New Challenges and Opportunities
  • 1.1 Ultra High Molecular Weight Polyethylene (UHMWPE) for Orthopaedic Devices: Structure/Property Relationships
  • 1.1.1 Introduction
  • HDPE and UHMWPE
  • 1.1.2 Chemical Structure
  • 1.1.3 Crystallinity and Melting Behavior
  • 1.1.4 Molecular Weight
  • 1.2 Stabilization of Irradiated Polyethylene by Introduction of Antioxidants (Vitamin E)
  • 1.2.1 Introduction
  • 1.2.2 Vitamin E Stabilized Polyethylenes
  • 1.3 Polyethylene-Based Conducting Polymer Blends and Composites
  • 1.3.1 Introduction
  • 1.3.2 Preparation
  • 1.4 Polyethylene Composites with Lignocellulosic Material: A Brief Overview
  • 1.4.1 Introduction
  • 1.4.2 Coupling Agents and Fibre Chemical Treatments
  • 1.5 LDH as Nanofillers of Nanocomposite Materials Based on Polyethylene
  • 1.6 Ultra High Molecular Weight Polyethylene and its Reinforcement/Oxidative Stability with Carbon Nanotubes in Medical Devices
  • 1.7 Montmorillonite Polyethylene Nanocomposites
  • 1.8 Characterization Methods for Polyethylene-Based Composites and Nanocomposites
  • References
  • 2 Ultra High Molecular Weight Polyethylene (UHMWPE) for Orthopaedic Devices: Structure/Property Relationships
  • 2.1 Introduction
  • HDPE and UHMWPE
  • 2.2 Chemical Structure
  • 2.3 Crystallinity and Melting Behaviour
  • 2.3.1 Avrami Theory
  • 2.3.2 Lauritzen
  • Hoffman Theory
  • 2.3.3 Crystal Growth Regimes
  • 2.4 Molecular weight
  • 2.5 Mechanical Properties
  • 2.5.1 Creep
  • 2.6 Sterilisation by Gamma Rays
  • 2.7 Conclusion and Future Trends
  • References
  • 3 Stabilization of Irradiated Polyethylene by Introduction of Antioxidants (Vitamin E)
  • 3.1 Introduction
  • 3.2 Types of Antioxidants
  • 3.2.1 Mechanism of Oxidation.
  • 3.2.2 General Principles of Stabilization
  • 3.2.2.1 Stabilization by Decreasing Initiation Rate
  • 3.2.2.1 Stabilization by Increase Termination Rate
  • 3.3 Stabilization by Vitamin E
  • 3.3.1 Structure and Biological Function of Vitamin E
  • 3.3.2 Mechanism of Stabilization of Vitamin E
  • 3.3.3 Methods of Incorporation of Vitamin E
  • 3.3.3.1 Strategy for Adding Vitamin E
  • 3.3.3.2 On the Solubility of Vitamin E in UHMWPE
  • 3.3.3.3 On the Diffusivity of Vitamin E in UHMWPE
  • 3.3.4 Vitamin E Stabilized Polyethylenes
  • 3.4 Analysis of the Content of Vitamin E
  • 3.4.1 FTIR
  • 3.4.2 UV
  • 3.4.3 HPLC
  • 3.4.4 Thermal Methods
  • 3.5 Conclusions
  • APPENDIX: Structure of Stabilizers
  • References
  • 4 Polyethylene-Based Conducting Polymer Blends and Composites
  • 4.1 Introduction
  • 4.2 Preparation
  • 4.2.1 In situ Polymerization
  • 4.2.2 Solution Blending
  • 4.2.3 Melt Blending
  • 4.3 Characterization
  • 4.3.1 Spectroscopy
  • 4.3.1.1 Fourier Transform Infrared (FTIR) Spectroscopy
  • 4.3.1.2 Raman Spectroscopy
  • 4.3.1.3 UV-vis Spectroscopy
  • 4.3.1.4 X-ray Photoelectron Spectroscopy (XPS)
  • 4.3.1.5 Electron Spin Resonance Spectroscopy (ESR)
  • 4.3.2 Microscopy
  • 4.3.3 Thermal Analysis
  • 4.3.4 X-ray Diffraction
  • 4.4 Properties
  • 4.4.1 Mechanical
  • 4.4.2 Electrical Conductivity
  • 4.4.3 Antioxidant
  • 4.4.4 Antimicrobial
  • 4.5 Applications
  • 4.5.1 Antistatic Materials
  • 4.5.2 Food Packaging
  • 4.5.3 Membranes
  • 4.6 Concluding Remarks
  • Acknowledgement
  • References
  • 5 Polyethylene Composites with Lignocellulosic Material
  • 5.1 Introduction
  • 5.2 Materials
  • 5.2.1 Polyolefins
  • 5.2.2 Recycled Polyolefins
  • 5.2.3 Natural Fibres
  • 5.3 Coupling Agents and Fibre Chemical Treatments
  • 5.3.1 Coupling Agents used in Compounding
  • 5.3.2 Chemical Pretreatments of Lignocellulosic Fibres
  • 5.4 Composites Processing and Properties.
  • 5.4.1 Extrusion
  • 5.4.2 Compression Moulding
  • 5.4.3 Injection Moulding
  • 5.4.4 Pultrusion
  • 5.4.5 Rotational Moulding
  • 5.5 Industrial Applications of Polyethylene with Lignocellulosic Fibres
  • 5.6 Conclusions and Future Trends
  • References
  • 6 Layered Double Hydroxides as Nanofillers of Composites and Nanocomposite Materials Based on Polyethylene
  • 6.1 Introduction
  • 6.2 Composites and Nanocomposites with Lamellar Fillers
  • 6.3 Layered Double Hydroxides: Structure, Properties and Uses
  • 6.3.1 Structure
  • 6.3.2 Chemical Composition
  • 6.3.3 Applications
  • 6.3.4 Preparation Procedures
  • 6.3.4.1 Precipitation Procedures
  • 6.3.4.2 Induced Hydrolysis
  • 6.3.4.3 The Salt-Oxide Method
  • 6.3.4.4 Anion Exchange
  • 6.3.4.5 The Reconstruction Method
  • 6.3.4.6 The Sol-Gel Method
  • 6.3.4.7 Urea Hydrolysis
  • 6.3.5 Post-Synthesis Treatments
  • 6.3.5.1 Hydrothermal Treatment
  • 6.3.5.2 Microwave Treatment
  • 6.4 Polyethylene as a Base of Blend Materials
  • 6.5 Strategies of Preparation: Synthesis of Composites and Nanocomposites using Modified LDHs
  • 6.6 Preparation of LDH-PE Materials
  • 6.6.1 Modification of the LDH
  • 6.6.2 Addition of Compatibilizers to PE
  • 6.6.3 Alternate Preparation Procedures
  • 6.7 Characterisation of LDH-PE Materials
  • 6.8 Properties of LDH-PE Materials
  • 6.8.1 Mechanical Properties
  • 6.8.2 Thermal Properties
  • 6.8.3 Electrical Properties
  • 6.8.4 Chemical Properties
  • 6.8.5 Other Properties
  • 6.9 Uses of LDH-PE Materials
  • 6.10 Conclusions and Current Trends of Development of LDH-PE Materials
  • Acknowledgments
  • References
  • 7 Ultra High Molecular Weight Polyethylene and its Reinforcement with Carbon Nanotubes in Medical Devices
  • 7.1 Introduction
  • 7.2 UHMWPE for Total Joint Arthroplasty
  • 7.3 Biocompatibility of CNTs and UHMWPE-CNT Nanocomposites.
  • 7.4 Manufacturing Processes of UHMWPE-CNT Nanocomposites
  • 7.4.1 CNTs Functionalization
  • 7.4.1.1 Covalent Functionalization
  • 7.4.1.2 Non-covalent Functionalization
  • 7.4.2 Processing UHMWPE-CNTs
  • 7.4.2.1 Solution Mixing
  • 7.4.2.2 In situ Polymerization
  • 7.4.2.3 Melt Mechanical Mixing
  • 7.5 Tribological Behaviour of UHMWPE and UHMWPE-CNT Nanocomposites
  • 7.5.1 Tribological Behaviour of UHMWPE
  • 7.5.2 Tribological Behaviour of UHMWPE/MWCNTs Composites
  • 7.6 Aging of UHMWPE and UHMWPE-CNT Nanocomposites
  • 7.7 Characterization of Irradiated UHMWPE and UHMWPEMWCNTs Nanocomposites
  • 7.7.1 Irradiation of UHMWPE
  • 7.7.2 Irradiated UHMWPE/MWCNTs Composites
  • 7.8 Viscoelastic Behavior and Dynamic Characterization using DMA
  • 7.8.1 Creep Testing and Modeling
  • 7.8.2 Dynamic Mechanical and Thermal Analysis
  • 7.9 Conclusion
  • Acknowledgements
  • References
  • 8 Montmorillonite Polyethylene Nanocomposites
  • 8.1 Introduction
  • 8.2 Montmorillonite
  • 8.2.1 General Description
  • 8.2.2 Surface Modification Techniques
  • 8.2.3 Characterization and Properties
  • 8.2.3.1 Elemental Analysis
  • 8.2.3.2 X-Ray Diffraction (XRD)
  • 8.2.3.3 Microscopy Techniques: Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM)
  • 8.2.3.4 Thermogravimetric Analysis (TGA)
  • 8.2.3.5 Other Tests
  • 8.3 Formulations and Processing Methods of OMt PE CPN
  • 8.3.1 Effect of Components in the OMt PE CPN Formulations
  • 8.3.2 Effect of Processing Conditions
  • 8.4 Properties of OMt PE CPN
  • 8.4.1 Thermal Stability
  • 8.4.2 Mechanical Properties
  • 8.4.3 Barrier Properties
  • 8.5 Applications of Clay Polymer Nanocomposites
  • 8.6 Future Trends and Challenges
  • References
  • 9 Characterization Methods for Polyethylene-based Composites and Nanocomposites
  • 9.1 Introduction
  • 9.2 Processing PE Composites
  • 9.2.1 Extrusion of PE Composites.
  • 9.2.2 Injection Molding
  • 9.2.3 Compression Molding
  • 9.3 Characterization
  • 9.3.1 Mechanical Properties
  • 9.3.1.1 Tensile Testing
  • 9.3.1.2 Flexural Tests
  • 9.3.1.3 Impact Tests
  • 9.3.1.4 Hardness Properties
  • 9.3.1.5 Dynamic Mechanical Analysis
  • 9.3.2 Thermal Properties
  • 9.3.2.1 Differential Scanning Calorimetry (DSC)
  • 9.3.2.2 Thermogravimetric Analysis (TGA)
  • 9.3.3 Morphological Analysis
  • 9.3.3.1 Transmission Electron Microscopy (TEM)
  • 9.3.3.2 Scanning Electron Microscope (SEM)
  • 9.3.4 Rheological Measurements
  • 9.3.5 X-ray Diffraction
  • 9.4 Conclusions
  • References
  • Index
  • EULA.

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