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Modern vibrational spectroscopy and micro-spectroscopy : theory, instrumentation, and biomedical applications /
Modern Vibrational Spectroscopy and Micro-Spectroscopy: Theory, Instrumentation and Biomedical Applications unites the theory and background of conventional vibrational spectroscopy with the principles of microspectroscopy. It starts with basic theory as it applies to small molecules and then expand...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Chichester, West Sussex :
John Wiley & Sons, Inc.,
2015.
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| Colección: | Online access with DDA: Askews (Medicine)
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Table of Contents; Title Page; Copyright; Dedication; Preface; References; Preface to Introduction to Modern Vibrational Spectroscopy (1994); References; Part I: Modern Vibrational Spectroscopy and Micro-spectroscopy: Theory, Instrumentation and Biomedical Applications: Introduction; Chapter 1: Molecular Vibrational Motion; 1.1 The concept of normal modes of vibration; 1.2 The separation of vibrational, translational, and rotational coordinates; 1.3 Classical vibrations in mass-weighted Cartesian displacement coordinates; 1.4 Quantum mechanical description of molecular vibrations.
- 1.5 Time-dependent description and the transition moment1.6 Basic infrared and Raman spectroscopies; 1.7 Concluding remarks; References; Chapter 2: Symmetry Properties of Molecular Vibrations; 2.1 Symmetry operations and symmetry groups; 2.2 Group representations; 2.3 Symmetry representations of molecular vibrations; 2.4 Symmetry-based selection rules for absorption processes; 2.5 Selection rules for Raman scattering; 2.6 Discussion of selected small molecules; References; Chapter 3: Infrared Spectroscopy; 3.1 General aspects of IR spectroscopy; 3.2 Instrumentation.
- 3.3 Methods in interferometric IR spectroscopy3.4 Sampling strategies; References; Chapter 4: Raman Spectroscopy; 4.1 General aspects of Raman spectroscopy; 4.2 Polarizability; 4.3 Polarization of Raman scattering; 4.4 Dependence of depolarization ratios on scattering geometry; 4.5 A comparison between Raman and fluorescence spectroscopy; 4.6 Instrumentation for Raman spectroscopy; References; Chapter 5: A Deeper Look at Details in Vibrational Spectroscopy; 5.1 Fermi resonance; 5.2 Transition dipole coupling (TDC); 5.3 Group frequencies; 5.4 Rot-vibrational spectroscopy; References.
- Chapter 6: Special Raman Methods: Resonance, Surface-Enhanced, and Nonlinear Raman Techniques6.1 Resonance Raman spectroscopy; 6.2 Surface-enhanced Raman scattering (SERS); 6.3 Nonlinear Raman effects; 6.4 Continuous wave and pulsed lasers; 6.5 Epilogue; References; Chapter 7: Time-Resolved Methods in Vibrational Spectroscopy; 7.1 General remarks; 7.2 Time-resolved FT infrared (TR-FTIR) spectroscopy; 7.3 Time-resolved Raman and resonance Raman (TRRR) spectroscopy; References; Chapter 8: Vibrational Optical Activity; 8.1 Introduction to optical activity and chirality.
- 8.2 Infrared vibrational circular dichroism (VCD)8.3 Observation of VCD; 8.4 Applications of VCD; 8.5 Raman optical activity; 8.6 Observation of ROA; 8.7 Applications of ROA; References; Chapter 9: Computation of Vibrational Frequencies and Intensities; 9.1 Historical approaches to the computation of vibrational frequencies; 9.2 Vibrational energy calculations; 9.3 Ab initio quantum-mechanical normal coordinate computations; 9.4 Vibrational intensity calculations; References.