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Fuels, energy, and the environment /

"Developed specifically for mechanical chemical, and petroleum engineering students, this book provides an up-to-date, informed, well-integrated, and balanced overview of the field of fuels science and technology with particular reference to energy supplies, efficiency, and the environment. It...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Karim, G. A.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken : CRC Press, 2013.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • 1 Introduction 1
  • 1.1 Preamble 1
  • 1.2 Different Forms of Energy 2
  • 1.3 Primary Sources of Energy 2
  • 1.4 Non-Fossil Fuel Based Energy 4
  • 1.4.1 Hydropower 4
  • 1.4.2 Ocean/Wave Energy 4
  • 1.4.3 Wind Energy 4
  • 1.4.4 Solar Energy 5
  • 1.4.5 Geothermal Energy 9
  • 1.4.6 Nuclear Energy 9
  • 1.5 Considering the Losses of Energy from Its Production Source to Its Point of Consumption 10
  • 1.6 Energy Resources Exploitation 11
  • 1.7 Synopsis 12
  • Bibliography 13
  • 2 Fuels in General 15
  • 2.1 Introduction 15
  • 2.2 Some of the Main Desirable Properties of Fuels 16
  • 2.3 Some Relevant Units of Measurement 17
  • 2.4 Some Patterns of Fuel and Energy Resources and Usage 20
  • 2.5 Definitions of Reserves 21
  • 2.6 Some General Observations about Fuel and Energy Statistics 23
  • 2.7 Changes in the Consumption of Different Sources of Energy 24
  • 2.8 Problems 26
  • 2.9 Synopsis 30
  • Bibliography 30
  • 3 Fuels Classification 33
  • 3.1 Fossil Fuels 33
  • 3.2 Hydrocarbon Fuels 33
  • 3.2.1 Paraffinic Series, C<sub>n</sub>H<sub>2n+2</sub> (Saturated, All with Single "C" Bonds) 34
  • 3.2.2 Olefin Series, C<sub>n</sub>H<sub>2n</sub> (Unsaturated with One Double Bond between Two C Atoms 34
  • 3.2.3 Acetylene Series, C<sub>n</sub>H<sub>2n-2</sub> (Unsaturated with One Triple Bond between Two C Atoms) 36
  • 3.2.4 Naphthenes or Cycloparaffins, C<sub>n</sub>H<sub>2n</sub> (Closed Chain with Single and Saturated Bonds) 36
  • 3.2.5 Aromatics, C<sub>n</sub>H<sub>2n-6</sub> (Unsaturated Ring Compounds) 37
  • 3.3 Some Oxygenated Compounds 38
  • 3.4 Problems 40
  • 3.5 Synopsis 41
  • Bibliography 41
  • 4 Fuel-Consuming Energy Systems 43
  • 4.1 Fuel-Consuming Work-Producing Devices 43
  • 4.2 Work and Heat 44
  • 4.3 Efficiency 45
  • 4.4 Fuel Energy Systems 47
  • 4.4.1 Internal Combustion Engines 47
  • 4.4.1.1 Various Types of Reciprocating Engines 48
  • 4.5 Cogeneration 52
  • 4.6 Fuel Consumption 54
  • 4.7 Hybrid Engines 56
  • 4.8 Choice of Energy Systems 57
  • 4.9 Problems 58
  • 4.10 Synopsis 58
  • Bibliography 59
  • 5 Stoichiometry and Thermodynamics 61
  • 5.1 Heating Value of Fuels 61
  • 5.2 Adiabatic Flame Temperature 63
  • 5.3 Procedure for Calculating the Temperature and Composition of the Products of Combustion, When Equilibrium Conditions Are Assumed 74
  • 5.4 Calorimeters 78
  • 5.5 Some Solved Examples 78
  • 5.6 Problems 86
  • 5.7 Synopsis 90
  • Bibliography 90
  • 6 Chemical Kinetics of Fuel Combustion 93
  • 6.1 Chemical Reactions 93
  • 6.2 Combustion Chemical Kinetics 96
  • 6.3 Solved Examples 103
  • 6.4 Modeling Fuel Combustion Reactions 103
  • 6.5 Types of Chemical Reactions Relevant to Fuels and Energy 106
  • 6.6 Problems 107
  • 6.7 Synopsis 108
  • Bibliography 108
  • 7 Exhaust Emissions from the Combustion of Fuels 111
  • 7.1 Products of Combustion of Fuels 111
  • 7.2 Air Pollution Control 113
  • 7.3 Catalytic Converters 119
  • 7.4 Greenhouse Effect 121
  • 7.5 Sulfur in Fuels 125
  • 7.6 Fuel-Induced Corrosion of Metals 126
  • 7.7 Solved Example 126
  • 7.8 Problems 127
  • 7.9 Synopsis 128
  • Bibliography 129
  • 8 Combustion and Flames 131
  • 8.1 Combustion, Flames, and Ignition Processes 131
  • 8.2 Diffusion Flames versus Premixed Flames 135
  • 8.3 Combustion Stability Characteristics 142
  • 8.4 Fuel Combustion via Burners and Orifices 145
  • 8.5 Combustion of Solid Fuels 146
  • 8.6 Solid Fuels Combustion Using Fluidized Beds 148
  • 8.7 Problems 150
  • 8.8 Synopsis 151
  • Bibliography 152
  • 9 Fire and Safety in Relation to Fuel Installations and Handling 155
  • 9.1 Fuel Fires 155
  • 9.2 Flammability Limits of Fuels 156
  • 9.3 Some Protective Measures 162
  • 9.4 Flash Point 164
  • 9.5 Some Terms Related to Fuel Fires and Safety 167
  • 9.6 Solved Example 168
  • 9.7 Problems 170
  • 9.8 Synopsis 172
  • Bibliography 173
  • 10 Petroleum 175
  • 10.1 Petroleum Reservoirs 175
  • 10.2 Oil Recovery 177
  • 10.3 Enhanced Oil Recovery Methods 178
  • 10.4 Oil Sands 182
  • 10.5 Oil Shale 186
  • 10.6 Problems 188
  • 10.7 Synopsis 188
  • Bibliography 189
  • 11 Refining of Petroleum 191
  • 11.1 Need for Refining 191
  • 11.2 Refining Chemical Processes 196
  • 11.3 Catalysts and Their Action 197
  • 11.4 Controls through Codes and Standards 198
  • 11.5 Problems 199
  • 11.6 Synopsis 199
  • Bibliography 199
  • 12 Gasoline 201
  • 12.1 Spark Ignition Gasoline-Fueled Engines 201
  • 12.2 Volatility 203
  • 12.3 Additives to Gasoline 206
  • 12.4 Catalysts 207
  • 12.5 Spark Ignition Engine Knock 207
  • 12.6 Some Features of Engine Knock 209
  • 12.7 Some Negative Effects of Knock in Spark Ignition Engines 210
  • 12.8 Operational Knock Limits 211
  • 12.9 Octane Number 213
  • 12.10 Effects of Engine Variables for Increased Incidence of Knock 213
  • 12.11 Knock Control 215
  • 12.12 Three-Way Catalyst 215
  • 12.13 Problems 216
  • 12.14 Synopsis 217
  • Bibliography 218
  • 13 Diesel Fuels and Some Other Liquid Fuels 221
  • 13.1 Diesel Engine Combustion Processes 221
  • 13.2 Ignition Delay in Diesel Engines 222
  • 13.3 Diesel Engine Fuels 223
  • 13.4 Diesel Engine Emissions 228
  • 13.5 Biodiesel Fuels 229
  • 13.6 Fischer-Tropsch Diesel 230
  • 13.7 Dual-Fuel Engine 230
  • 13.8 Liquid Fuels for Aviation Applications 231
  • 13.9 Heavy Fuels for Boiler and Furnace Applications 234
  • 13.10 Liquid and Solid Propellants 234
  • 13.11 Solved Example 235
  • 13.12 Problems 236
  • 13.13 Some Definitions Associated with Liquid Fuels 237
  • 13.14 Synopsis 239
  • Bibliography 239
  • 14 Solid Fuels 241
  • 14.1 Combustion of Solid Fuels 241
  • 14.2 Coal 241
  • 14.3 Case for Coal 244
  • 14.4 Some Properties of Coal 246
  • 14.5 Classification of Coals 248
  • 14.6 Solved Examples 249
  • 14.7 Coal Combustion in Fluidized Beds 251
  • 14.8 Gasification of Coal 252
  • 14.9 Underground Gasification of Coal 254
  • 14.10 Other Solid Fuels 254
  • 14.11 Coal Bed Methane 257
  • 14.12 Solid Fuels as Propellants 257
  • 14.13 Solved Example 258
  • 14.14 Problems 259
  • 14.15 Synopsis 260
  • Bibliography 260
  • 15 Natural Gas and Other Gaseous Fuels 263
  • 15.1 Merits of Operation on Gaseous Fuels 263
  • 15.2 Natural Gas 265
  • 15.3 Natural Gas Transmission 271
  • 15.4 Flaring of Fuel Gases 275
  • 15.5 Liquefied Natural Gas 276
  • 15.6 LNG Safety 277
  • 15.7 Hydrates of Methane 278
  • 15.8 Comparison of Features of Natural-Gas-Fueled Gas Turbines with Those of Spark Ignition Engines 279
  • 15.9 Propane and Liquefied Petroleum Gas 280
  • 15.10 Solved Example 281
  • 15.11 LPG Safety 284
  • 15.12 Some Common Non-Natural Gas Mixtures 285
  • 15.13 Landfill Gases 288
  • 15.14 Biogas Fuels 289
  • 15.15 Hydrogen Sulfide 290
  • 15.16 Solved Examples 291
  • 15.17 Problems 295
  • 15.18 Some Gaseous Fuel Mixture Terms 296
  • 15.19 Synopsis 296
  • Bibliography 297
  • 16 Alternative Fuels 301
  • 16.1 Introduction 301
  • 16.2 Applications 303
  • 16.3 Alcohols as Fuels 304
  • 16.4 Hydrogen as a Fuel 306
  • 16.5 Liquid Hydrogen 310
  • 16.6 Compressed Natural Gas 311
  • 16.7 Problems 313
  • 16.8 Synopsis 313
  • Bibliography 314.