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Metal catalyzed cross-coupling reactions and more. Volume 1 /

This is the follow-up handbook to the bestselling Metal-Catalyzed Cross Coupling Reactions, the definitive reference in the field. In line with the enormous developments in this area, this is not so much a new edition, but rather a new book in three volumes with over 50% more content. This new conte...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Meijere, A. de, Bräse, Stefan, Oestreich, Martin
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Weinheim an der Bergstrasse, Germany : Wiley-VCH, 2014.
Temas:
Acceso en línea:Texto completo

MARC

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245 0 0 |a Metal catalyzed cross-coupling reactions and more.  |n Volume 1 /  |c edited by Armin de Meijere, Stefan Bräse, and Martin Oestreich. 
264 1 |a Weinheim an der Bergstrasse, Germany :  |b Wiley-VCH,  |c 2014. 
264 4 |c ©2014 
300 |a 1 online resource (1551 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
504 |a Includes bibliographical references at the end of each chapters and index. 
588 0 |a Online resource; title from PDF title page (ebrary, viewed December 11, 2013). 
505 0 |a Metal-Catalyzed Cross-Coupling Reactions and More; Contents to Volume 1; Preface; List of Contributors; Chapter 1 Mechanistic Aspects of Metal-Catalyzed C, C- and C, X-Bond Forming Reactions; 1.1 Mechanisms of Cross-Coupling Reactions; 1.1.1 The Earlier Mechanistic Proposal: The Stille Reaction; 1.1.2 The Oxidative Addition; 1.1.2.1 Cis-Complexes in the Oxidative Addition; 1.1.2.2 The Role of Alkene and Anionic Ligands; 1.1.2.3 Cross-Couplings in the Presence of Bulky Phosphines; 1.1.2.4 N-Heterocyclic Carbenes as Ligands; 1.1.2.5 Palladacycles as Catalysts. 
505 8 |a 1.1.2.6 Involvement of Pd(IV) in Catalytic Cycles1.1.2.7 Oxidative Addition of Stannanes to Pd(0); 1.1.3 The Transmetallation in the Stille Reaction; 1.1.3.1 Isolation of the Transmetallation Step; 1.1.3.2 Dissociative Mechanistic Proposals; 1.1.3.3 Cyclic and Open Associative Transmetallation; 1.1.3.4 The Copper Effect; 1.1.3.5 Transmetallation in the Suzuki-Miyaura Reaction; 1.1.3.6 Transmetallation in the Negishi Reaction; 1.1.3.7 Transmetallation in the Hiyama Reaction; 1.1.3.8 Couplings Catalyzed by Copper and Gold; 1.1.3.9 Couplings Catalyzed by Iron and Cobalt. 
505 8 |a 1.1.4 Reductive Elimination1.2 Palladium-Catalyzed [alpha]-Arylation of Carbonyl Compounds and Nitriles; 1.3 Formation of C-X (X = N, O, S) Bonds in Metal-Catalyzed Reactions; 1.3.1 Reductive Elimination to Generate C-N, C-O, and C-S Bonds from Organopalladium(II) Complexes; 1.3.2 Nickel- and Copper-Catalyzed Formation of C-X Bonds; 1.4 Summary and Outlook; List of Abbreviations; References; Chapter 2 State-of-the-Art in Metal-Catalyzed Cross-Coupling Reactions of Organoboron Compounds with Organic Electrophiles; 2.1 Introduction; 2.1.1 Catalytic Cycle. 
505 8 |a 2.1.2 Improvements toward More Efficient Cross-Coupling Conditions2.1.2.1 Development of New Phosphine and NHC Ligands; 2.1.2.2 Usage of Masked Boron Derivatives as Cross-Coupling Partners; 2.1.2.3 Lewis Acids as Additives; 2.1.2.4 Adjusting the Nucleophilicity of Organoboron Cross-Coupling Partners; 2.1.2.5 Copper Salts as Additives; 2.2 Advances in Cross-Coupling Reactions for the Formation of C(sp2)-C(sp2) Bonds; 2.2.1 Background; 2.2.2 Recent Developments in the Use of New Electrophilic Coupling Partners; 2.2.2.1 Chlorides; 2.2.2.2 Fluorides; 2.2.2.3 Pseudohalides. 
505 8 |a 2.2.3 Recent Developments in Organoboron Cross-Coupling Partners2.2.3.1 Trifluoroborate Salts; 2.2.3.2 N-Methyliminodiacetic Acid (MIDA) Boronates; 2.2.3.3 Other Organoboron Cross-Coupling Partners; 2.2.4 Synthesis of Enantiomerically Enriched Atropisomers; 2.3 Advances in the Cross-Coupling Reactions for the Formation of C(sp3)-C(sp2) or C(sp3)-C(sp3) Bonds; 2.3.1 Background; 2.3.1.1 Stereochemistry; 2.3.2 Cross-Couplings between Unsaturated sp2 Carbon Centers and sp3 Carbon Centers; 2.3.2.1 Cross-Couplings between sp3 Alkyl Halides and sp2 Alkenyl or Aryl Boron Derivatives. 
520 |a This is the follow-up handbook to the bestselling Metal-Catalyzed Cross Coupling Reactions, the definitive reference in the field. In line with the enormous developments in this area, this is not so much a new edition, but rather a new book in three volumes with over 50% more content. This new content includes C-H activation, shifting the focus away from typical cross-coupling reactions, while those topics and chapters found in Diederich/de Meijere's book have been updated and expanded. With its highly experienced editor team and the authors reading like an international Who's-Who in. 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Organic compounds  |x Synthesis. 
650 0 |a Metal catalysts. 
650 6 |a Composés organiques  |x Synthèse. 
650 6 |a Catalyseurs métalliques. 
650 7 |a TECHNOLOGY & ENGINEERING  |x Engineering (General)  |2 bisacsh 
650 7 |a TECHNOLOGY & ENGINEERING  |x Reference.  |2 bisacsh 
650 7 |a Metal catalysts  |2 fast 
650 7 |a Organic compounds  |x Synthesis  |2 fast 
700 1 |a Meijere, A. de. 
700 1 |a Bräse, Stefan. 
700 1 |a Oestreich, Martin. 
758 |i has work:  |a Metal-catalyzed cross-coupling reactions and more Volume 1 (Text)  |1 https://id.oclc.org/worldcat/entity/E39PD3PYW9vXM8ryfQ9J7mdHrV  |4 https://id.oclc.org/worldcat/ontology/hasWork 
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