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Handbook of metathesis. Volume 2, Applications in organic synthesis /

The second edition of the ""go-to"" reference in this field is completely updated and features more than 80% new content, with emphasis on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in su...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Grubbs, Robert H. (Editor ), O'Leary, Daniel J. (Editor ), Chegondi, Rambabu (Contribuidor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Weinheim, Germany : Wiley-VCH, 2015.
Edición:Second edition.
Temas:
Acceso en línea:Texto completo

MARC

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245 0 0 |a Handbook of metathesis.  |n Volume 2,  |p Applications in organic synthesis /  |c edited by Robert H. Grubbs and Daniel J. O'Leary ; contributors, Rambabu Chegondi [and twenty nine others]. 
250 |a Second edition. 
264 1 |a Weinheim, Germany :  |b Wiley-VCH,  |c 2015. 
264 4 |c ©2015 
300 |a 1 online resource (772 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
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504 |a Includes bibliographical references at the end of each chapters and index. 
588 0 |a Online resource; title from PDF title page (ebrary, viewed March 6, 2015). 
505 0 |a Cover; Contents; Preface; List of Contributors; List of Abbreviations; Chapter 1 General Ring-Closing Metathesis; 1.1 Introduction; 1.2 Carbocycles (Introduction); 1.2.1 Small-Sized Carbocycles; 1.2.2 Medium-Sized Carbocycles; 1.2.3 Spiro Carbocycles; 1.3 Synthesis of Bridged Bicycloalkenes; 1.4 Synthesis of Heterocycles Containing Si, P, S, or B; 1.4.1 Si-Heterocycles; 1.4.2 P-Heterocycles; 1.4.3 S-Heterocycles; 1.4.4 B-Heterocycles; 1.5 Synthesis of O-Heterocycles; 1.5.1 Small and Medium-Size Cyclic Ethers; 1.5.2 Polycyclic Ethers; 1.6 Synthesis of N-Heterocycles; 1.6.1 N-Heterocycles. 
505 8 |a 1.6.2 Small and Medium-Sized Lactams1.7 Synthesis of Cyclic Conjugated Dienes; 1.8 Alkyne Metathesis; 1.9 Enyne Metathesis; 1.9.1 General Enyne Metathesis; 1.9.2 Dienyne Metathesis; 1.10 Tandem Processes; 1.10.1 Tandem ROM/RCM; 1.10.2 Other Tandem RCMs; 1.11 Synthesis of Macrocycles; 1.11.1 Macrocycles; 1.11.2 Macrolactones; 1.11.3 Macrolactams; 1.12 RCM and Isomerization via Ru-H; 1.13 Relay RCM (RRCM); 1.14 Z-Selective RCM; 1.14.1 Substrate-Controlled Z-Selective RCM; 1.14.2 Catalyst-Controlled Z-Selective RCM; 1.15 Enantioselective RCM; 1.16 Conclusion; Acknowledgments; References. 
505 8 |a Chapter 2 Cross-Metathesis2.1 Early Examples Using Well-Defined Molybdenum and Ruthenium Catalysts; 2.2 The General Model for Selectivity in CM Reactions; 2.3 Definition of Cross-Metathesis Reaction Categories and Chapter Organization; 2.4 Hydrocarbons; 2.4.1 Alkane Extensions; 2.4.2 Unsaturated Hydrocarbons, Including Styrene; 2.4.3 Ethylene Cross-Metathesis; 2.5 Boron; 2.6 Nitrogen; 2.6.1 Amines; 2.6.2 Amines as CM Partners in Heterocycle Syntheses; 2.6.3 Acrylonitrile and Other Nitrile-Based CM Applications; 2.6.4 Other Nitrogenous Substrates; 2.7 Oxygen. 
505 8 |a 2.7.1 Primary Allylic Alcohols and Derivatives2.7.2 Secondary Allylic Alcohols and Derivatives; 2.7.3 Tertiary Allylic Alcohols and Derivatives; 2.7.4 Homoallylic Alcohols and Derivatives; 2.7.5 Vinyl Ethers; 2.7.6 Acrolein, Crotonaldehyde, and Methacrolein; 2.7.7 Methyl Vinyl Ketone and Related Systems; 2.7.8 Acrylic Acid; 2.7.9 Acrylic Acid Derivatives, Including Esters, Thioesters, and Amides; 2.8 Halides; 2.9 Phosphorus; 2.10 Sulfur; 2.11 Fragment Coupling Reactions; 2.11.1 Acetogenins; 2.11.2 Cross-Metathesis Selectivity; 2.11.3 Tuning Metathesis Selectivity. 
505 8 |a 2.11.4 CM as an Alternative Coupling Strategy2.11.5 CM-Based Analog Synthesis; 2.11.6 Polyene Metathesis; 2.11.7 Cross-Metathesis Reaction Optimization: Pinnaic Acid; 2.12 Conclusions; References; Chapter 3 Vignette: Extending the Application of Metathesis in Chemical Biology -- The Development of Site-Selective Peptide and Protein Modifications; 3.1 Introduction; 3.2 Cross-Metathesis Methodology Studies in Aqueous Media; 3.2.1 Allyl Sulfides are Reactive Substrates in Olefin Metathesis; 3.2.2 Sulfur-Relayed Cross-Metathesis. 
520 |a The second edition of the ""go-to"" reference in this field is completely updated and features more than 80% new content, with emphasis on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality. Edited by the Nobel laureate R.H. Grubbs and D.J.O ́Leary, this volume 2 of the 3-volume work focusses on applications in organic synthesis. With a list of contributors that reads like a ""Who's-Who"" of metathesis, this is an indispensable one-stop reference for chemists in academia and industry. 
506 1 |a Legal Deposit;  |c Only available on premises controlled by the deposit library and to one user at any one time;  |e The Legal Deposit Libraries (Non-Print Works) Regulations (UK).  |5 WlAbNL 
540 |a Restricted: Printing from this resource is governed by The Legal Deposit Libraries (Non-Print Works) Regulations (UK) and UK copyright law currently in force.  |5 WlAbNL 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Alkenes  |v Handbooks, manuals, etc. 
650 0 |a Metathesis (Chemistry)  |v Handbooks, manuals, etc. 
650 0 |a Organic compounds  |x Synthesis  |v Handbooks, manuals, etc. 
650 0 |a Polymerization  |v Handbooks, manuals, etc. 
650 6 |a Alcènes  |v Guides, manuels, etc. 
650 6 |a Métathèse (Chimie)  |v Guides, manuels, etc. 
650 6 |a Composés organiques  |x Synthèse  |v Guides, manuels, etc. 
650 6 |a Polymérisation  |v Guides, manuels, etc. 
650 7 |a Alkenes  |2 fast 
650 7 |a Metathesis (Chemistry)  |2 fast 
650 7 |a Organic compounds  |x Synthesis  |2 fast 
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700 1 |a Grubbs, Robert H.,  |e editor. 
700 1 |a O'Leary, Daniel J.,  |e editor. 
700 1 |a Chegondi, Rambabu,  |e contributor. 
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