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The polysiloxanes /

Polysiloxanes are the most studied inorganic and semi-inorganic polymers because of their many medical and commercial uses. The Si-O backbone endows polysiloxanes with intriguing properties: the strength of the Si-O bond imparts considerable thermal stability, and the nature of the bonding imparts l...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Mark, James E., 1934-
Otros Autores: Schaefer, Dale W., Lin, Gui (Scientist)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York, NY : Oxford University Press, 2015.
Temas:
Acceso en línea:Texto completo

MARC

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100 1 |a Mark, James E.,  |d 1934-  |1 https://id.oclc.org/worldcat/entity/E39PBJvMDWjwRTMf3px9Vk3WjC 
245 1 4 |a The polysiloxanes /  |c James E. Mark, Dale W. Schaefer, and Gui Lin. 
264 1 |a New York, NY :  |b Oxford University Press,  |c 2015. 
300 |a 1 online resource 
336 |a text  |b txt  |2 rdacontent 
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504 |a Includes bibliographical references and index. 
588 0 |a Print version record. 
505 0 |a Cover; Contents; Preface; 1. Introduction; 1.1. Background; 1.2. History; 1.3. Nomenclature; 2. Preparation, Analysis, and Degradation; 2.1. Preparation of Monomers; 2.2. Ring-Opening Polymerizations; 2.3. Other Approaches and Copolymerizations; 2.4. Structural Features; 2.5. Elastomer Technology; 2.6. Analysis and Testing; 2.7. Degradation; 3. Types of Polysiloxanes; 3.1. Homopolymers; 3.2. Reactive Chains; 3.3. Dendrimers and Hyperbranched Polymers; 3.4. Liquid-Crystalline Polymers; 3.4.1. Main-Chain Liquid-Crystalline Elastomers; 3.4.2. Side-Chain Liquid-Crystalline Elastomers. 
505 8 |a 3.5. Cyclics3.5.1. Introduction; 3.5.2. Miscellaneous Properties of Polysiloxane Cyclics; 3.5.3. Comparisons Between Polysiloxane Cyclics and Polysiloxane Linear Chains; 3.6. Other Novel Materials; 3.6.1. Blends; 3.6.2. Ceramic Phases and Coatings; 3.6.3. Micropatterned Materials; 3.6.4. Nanofilaments and Molecular Wires; 3.6.5. Thermosets; 4. Some Characterization Techniques Useful for Polysiloxanes; 4.1. General Comments; 4.2. Optical and Spectroscopic Techniques; 4.3. Microscopies; 4.4. Nuclear Magnetic Resonance; 4.5. Thermoporometry; 4.6. Scattering of Light, X-Rays, and Neutrons. 
505 8 |a 4.7. Brillouin Scattering4.8. Pulse Propagation; 4.9. Theory and Simulations; 5. General Properties; 5.1. Some General Information; 5.2. Conformations and Spatial Configurations; 5.2.1. Symmetrically Substituted Polysiloxanes; 5.2.2. Stereochemically Variable Polysiloxanes; 5.2.3. Some Unusual Side Groups; 5.2.4. Poly(dimethylsilmethylene); 5.3. Flexibility of the Polymer Chains; 5.3.1. Equilibrium Flexibility; 5.3.2. Dynamic Flexibility; 5.3.3. Viscoelasticity; 5.4. Permeability; 5.5. Dielectric Constants and Dipole Moments; 5.6. Stability, Safety Aspects, and Environmental Impacts. 
505 8 |a 5.7. Thermodynamics5.8. Crystallinity; 5.9. Some Additional Unusual Properties of PDMS; 6. Surfaces; 6.1. Introduction; 6.2. Interactions with Water; 6.2.1. Hydrophilicity and Hydrophobicity; 6.2.2. Superhydrophilicity and Superhydrophobicity; 6.3. Characterization; 6.3.1. Contact Angles; 6.3.2. Wettability; 6.3.3. Spreading; 6.3.4. Surface Pressure; 6.3.5. Atomic Force Microscopy; 6.3.6. Nuclear Magnetic Resonance; 6.3.7. Swelling; 6.3.8. Exposure to Seawater; 6.4. Chains Bonded to or Embedded in Surfaces; 6.4.1. Tethering; 6.4.2. Grafting; 6.5. Radiation Treatments. 
505 8 |a 6.5.1. Plasmas and Photons6.5.2. UV and UV/Ozone Treatments; 6.5.3. Ion Beams; 6.6. Some Additional Chemical Aspects; 6.6.1. Emulsions; 6.6.2. Radical Polymerization; 6.6.3. Copolymers with Polyurethanes; 6.7. Migration; 6.7.1. Surface Segregation; 6.7.2. Recovery and Restructuring; 6.7.3. Self-Healing; 6.8. Interactions with Biomolecules; 6.8.1. Trapped Biomolecules; 6.8.2. Controlled Release; 6.8.3. Protein Adsorption; 6.8.4. Cells and Antigen Molecules; 6.8.5. Biofouling; 6.9. Mechanical Aspects; 6.9.1. Friction and Lubricity; 6.9.2. Adhesion; 6.9.3. Tribology; 6.10. Some Novel Materials. 
520 |a Polysiloxanes are the most studied inorganic and semi-inorganic polymers because of their many medical and commercial uses. The Si-O backbone endows polysiloxanes with intriguing properties: the strength of the Si-O bond imparts considerable thermal stability, and the nature of the bonding imparts low surface free energy. Prostheses, artificial organs, objects for facial reconstruction, vitreous substitutes in the eyes, and tubing take advantage of the stability and pliability of polysiloxanes. Artificial skin, contact lenses, and drug delivery systems utilize their high permeability. Such bio. 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Silicones. 
650 2 |a Silicones 
650 6 |a Silicones. 
650 7 |a silicone.  |2 aat 
650 7 |a TECHNOLOGY & ENGINEERING  |x Chemical & Biochemical.  |2 bisacsh 
650 7 |a Silicones  |2 fast 
700 1 |a Schaefer, Dale W. 
700 1 |a Lin, Gui  |c (Scientist)  |1 https://id.oclc.org/worldcat/entity/E39PCjM9m987XjJvT3XqKgyKMK 
758 |i has work:  |a The polysiloxanes (Text)  |1 https://id.oclc.org/worldcat/entity/E39PCGJRfR6RpYvB7bqwVmhfYK  |4 https://id.oclc.org/worldcat/ontology/hasWork 
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