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Semiconductor Photocatalysis : Principles and Applications.

Focusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Kisch, Horst
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken : Wiley, 2014.
Temas:
Acceso en línea:Texto completo

MARC

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520 |a Focusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical aspects. A valuable, one-stop source for all chemists, material scientists, and physicists working in this area, as well as novice researchers entering (semiconductor) photocatalysis. 
505 0 |a Related Titles; Title Page; Copyright; Dedication; Preface; Acknowledgments; Chapter 1: Introduction; 1.1 A Brief History of Photochemistry; 1.2 Catalysis, Photochemistry, and Photocatalysis; Chapter 2: Molecular Photochemistry; 2.1 Absorption and Emission; 2.2 Intensity of Electronic Transitions; 2.3 Excited States Radiative Lifetimes; 2.4 Energy and Electron Transfer; 2.5 Proton Transfer and Hydrogen Abstraction; 2.6 Photosensitization; 2.7 Rates and Quantum Yields; 2.8 Quenching of Excited States; 2.9 Absorption, Emission, and Excitation Spectra. 
505 8 |a 2.10 Classification and Reactivity of Excited StatesChapter 3: Molecular Photocatalysis; 3.1 Hydrogenation of 1,3-Dienes; 3.2 Co-Cyclization of Alkynes with Nitriles; 3.3 Enantioselective Trifluoromethylation of Aldehydes; 3.4 Photoinduced Electron Transfer Catalysis; 3.5 Reduction and Oxidation of Water; Chapter 4: Photoelectrochemistry; 4.1 Electronic Structure and Nature of Excited States; 4.2 Photocorrosion; 4.3 Interfacial Electron Transfer; Chapter 5: Semiconductor Photocatalysis; 5.1 Mechanisms, Kinetics, and Adsorption; 5.2 Characterization of Photocatalysts. 
505 8 |a 5.3 Preparation and Properties of Photocatalysts5.4 Type A Reactions; 5.5 Type B Reactions; 5.6 Environmental Aspects; 5.7 Titania in Food and Personal Care Products; 5.8 Photoreactors; References; Index; EULA. 
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650 0 |a Catalysts. 
650 0 |a Nanoparticles. 
650 0 |a Photocatalysis. 
650 4 |a Catalysts. 
650 4 |a Nanoparticles. 
650 4 |a Photocatalysis. 
650 4 |a Semiconductors. 
650 6 |a Catalyseurs. 
650 6 |a Nanoparticules. 
650 6 |a Photocatalyse. 
650 7 |a catalyst.  |2 aat 
650 7 |a Catalysts  |2 fast 
650 7 |a Nanoparticles  |2 fast 
650 7 |a Photocatalysis  |2 fast 
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880 0 |6 505-00/(S  |a Semiconductor Photocatalysis -- Contents -- Preface -- Acknowledgments -- Chapter 1 Introduction -- 1.1 A Brief History of Photochemistry -- 1.2 Catalysis, Photochemistry, and Photocatalysis -- Chapter 2 Molecular Photochemistry -- 2.1 Absorption and Emission -- 2.2 Intensity of Electronic Transitions -- 2.2.1 Contribution of Nuclei -- 2.2.2 Contribution of Spin -- 2.2.3 Contribution of Orbitals -- 2.3 Excited States Radiative Lifetimes -- 2.4 Energy and Electron Transfer -- 2.4.1 Energy Transfer -- 2.4.2 Electron Transfer -- 2.5 Proton Transfer and Hydrogen Abstraction -- 2.6 Photosensitization -- 2.7 Rates and Quantum Yields -- 2.8 Quenching of Excited States -- 2.8.1 Identification of the Reactive Excited State -- 2.9 Absorption, Emission, and Excitation Spectra -- 2.10 Classification and Reactivity of Excited States -- 2.10.1 Organic Molecules -- 2.10.1.1 π, π* States -- 2.10.1.2 n, π* States -- 2.10.1.3 Charge-Transfer (CT) States -- 2.10.1.4 Triplet and Singlet Oxygen Reactions -- 2.10.2 Inorganic and Organometallic Complexes -- 2.10.2.1 Metal-Centered (MC) states -- 2.10.2.2 Ligand-Centered (LC) States -- 2.10.2.3 Charge Transfer Metal to Ligand (CTML) States -- 2.10.2.4 Charge Transfer Ligand to Metal (CTLM) States -- 2.10.2.5 Charge Transfer to Solvent (CTTS) States -- 2.10.2.6 Intervalence Transfer (IT) States -- Chapter 3 Molecular Photocatalysis -- 3.1 Hydrogenation of 1,3-Dienes -- 3.2 Co-Cyclization of Alkynes with Nitriles -- 3.3 Enantioselective Trifluoromethylation of Aldehydes -- 3.4 Photoinduced Electron Transfer Catalysis -- 3.5 Reduction and Oxidation of Water -- Chapter 4 Photoelectrochemistry -- 4.1 Electronic Structure and Nature of Excited States -- 4.1.1 The (Optical) Bandgap -- 4.1.1.1 Measurement of the Bandgap Energy -- 4.1.1.2 Influence of Crystal Size -- 4.1.2 The Photonic Bandgap. 
880 8 |6 505-00/(S  |a 4.1.3 Emission Spectra -- 4.2 Photocorrosion -- 4.3 Interfacial Electron Transfer -- 4.3.1 Introduction -- 4.3.2 Thermal Interfacial Electron Transfer (IFET) -- 4.3.2.1 IFET at the Metal/Liquid Interface -- 4.3.2.2 IFET at the Semiconductor/Liquid Interface -- 4.3.3 Photochemical Interfacial Electron Transfer -- 4.3.3.1 IFET in Large Semiconductor Crystals -- 4.3.3.2 IFET in Small Semiconductor Crystals -- Chapter 5 Semiconductor Photocatalysis -- 5.1 Mechanisms, Kinetics, and Adsorption -- 5.1.1 General Classification of Reactions -- 5.1.2 Rates, Quantum Yields, and Their Comparability -- 5.1.2.1 Direct Semiconductor Photocatalysis -- 5.1.2.1.1 Factors Determining the Quantum Yield -- 5.1.2.1.2 Kinetic Aspects -- 5.1.2.1.3 Quantum Yield -- 5.1.2.1.3 Role of Adsorption -- 5.1.2.1.3 Indirect Semiconductor Photocatalysis -- 5.1.3 Influence of Semiconductor Nature and Particle Size on Chemical Selectivity -- 5.1.3.1 Control of Chemoselectivity by Surface States and Redox Amplification -- 5.2 Characterization of Photocatalysts -- 5.2.1 General Methods -- 5.2.2 Flatband and Quasi-Fermi Potentials -- 5.2.2.1 Measurements in Absence of Light -- 5.3 Preparation and Properties of Photocatalysts -- 5.3.1 Pristine Compounds and Solid Solutions -- 5.3.1.1 TiO2 -- 5.3.1.2 WO3 -- 5.3.1.3 α-Fe2O3 -- 5.3.1.4 BiVO4 -- 5.3.1.5 Ta2O3, TaON, Ta3N5, and MTaO2N -- 5.3.1.6 CuO, Cu2O -- 5.3.1.7 GaN-ZnO -- 5.3.1.8 CdS and ZnS -- 5.3.2 Grafting of CdS and TiO2 onto Inorganic Supports -- 5.3.2.1 Grafting onto a Nonconducting Support -- 5.3.2.2 Grafting onto a Semiconducting Support -- 5.3.3 Grafting of Metal Halides and Metal Oxides onto Titania -- 5.3.3.1 Metal Chloride-Grafted Titania -- 5.3.4 Metal-Loaded Powders -- 5.3.5 Nonmetal-Modified Titania -- 5.3.5.1 Nitrogen-Modified Titania -- 5.3.5.2 ``Carbon''-Modified Titania -- 5.3.5.3 Miscellaneous. 
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