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Catalytic Arylation Methods : From the Academic Lab to Industrial Processes.
A current view of the challenging field of catalytic arylation reactions. Clearly structured, the chapters in this one-stop resource are arranged according to the reaction type, and focus on novel, efficient and sustainable processes, rather than the well-known and established cross-coupling methods...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2014.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Related Titles; Title Page; Copyright; Dedication; Preface; List of Abbreviations; Chapter 1: Cross-Coupling Arylations: Precedents and Rapid HistoricalReview of the Field; 1.1 Metal-Catalyzed Cross-Couplings: From Its Origins to the Nobel Prize and Beyond; 1.2 Arylation: What Is So Special?; 1.3 Recent New Developments; 1.4 Selected Experiments from the Literature; References; Chapter 2: Amine, Phenol, Alcohol, and Thiol Arylation; 2.1 Introduction; 2.2 Pd-Catalyzed Processes; 2.3 Cu-Catalyzed and Promoted Arylations: (CAr-N Bond Formation); 2.4 Fe-Catalyzed Arylations
- 2.5 Ni-Catalyzed Reactions2.6 Co-Catalyzed Arylations; 2.7 Mn-Catalyzed Arylations; 2.8 Cd-Catalyzed Arylations; 2.9 Bi(III) and Indium Oxide-Catalyzed Thiol Arylations; 2.10 Conclusions and Final Comment; 2.11 Selected Experiments from the Literature; References; Chapter 3: Decarboxylative Coupling Techniques; 3.1 Introduction; 3.2 Pd-Catalyzed Versions; 3.3 Other Metal-Catalyzed Versions; 3.4 Conclusions; 3.5 Selected Experiments; References; Chapter 4: C-H Bond Activation for Arylations; 4.1 Introduction; 4.2 C(sp2)-H Activations; 4.3 Conclusions
- 4.4 Selected Experiments from the LiteratureReferences; Chapter 5: Conjugate Additions; 5.1 Conjugate Additions: A Powerful Tool for Appending Organic Residues to Cyclic and Acyclic Substrates; 5.2 Applications of Rh Catalysts; 5.3 Applications of Pd Catalysts; 5.4 Applications of Ru and Other Catalysts; 5.5 Conclusions; 5.6 Selected Experiments; References; Chapter 6: Imine Arylations
- Synthesis of Arylamines; 6.1 Arylation of C=N Bonds: Simple Access to Chiral Amine Units; 6.2 Application of Rh Catalysts; 6.3 Application of Pd Catalysts; 6.4 Application of Ru and Other Catalysts
- 9.2 Cycloaddition Events9.3 Radical-Based Cycloaromatization Processes; 9.4 Conclusions; 9.5 Selected Experiments from the Literature; References; Index; End User License Agreement