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Chemistry of organo-hybrids : synthesis and characterization of functional nano-objects /
This book provides readers with a one-stop entry into the chemistry of varied hybrids and applications, from a molecular synthetic standpoint Describes introduction and effect of organic structures on specific support components (carbon-based materials, proteins, metals, and polymers). Chapters cove...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, New Jersey :
John Wiley & Sons,
[2015]
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Chemistry of Organo-Hybrids; Contents; Preface; Contributors; 1 Covalent Organic Functionalization and Characterization of Carbon Nanotubes; 1.1 Introduction; 1.2 Covalent Functionalization of Carbon Nanotubes with Organic Molecules; 1.2.1 Defect-Site Chemistry; 1.2.2 Halogenation; 1.2.3 Arylation; 1.2.4 Cycloaddition Reactions; 1.2.5 Radical Addition; 1.2.6 Nucleophilic and Electrophilic Additions; 1.2.7 Plasma Functionalization and Mechanochemical Treatment; 1.3 Characterization of Functionalized Carbon Nanotubes; 1.3.1 Spectroscopic Techniques; 1.3.2 Microscopic Techniques.
- 1.3.3 Thermal Techniques1.4 Conclusion; References; 2 Functionalized Graphenes; 2.1 Starting Materials; 2.2 Characterization; 2.3 Functionalization; 2.3.1 Functionalization on the Carbon Framework; 2.3.2 Functionalization Involving an Oxygenated Function; 2.4 Conclusion; References; 3 Nanodiamonds: Emergence of Functionalized Diamondoids and Their Unique Applications; 3.1 Introduction; 3.2 Historical Background: From the Synthesis of Detonation Nanodiamond to the Isolation and Characterization of Higher Diamondoids; 3.2.1 Nanodiamond versus Diamondoids: The Case of Polymantanes.
- 3.2.2 Synthesis of Polymantanes versus Extraction from the Geosphere3.2.3 Diamondoid Nomenclature and Characterization; 3.3 Functionalization of Adamantane, Diamantane, and Higher Diamondoids; 3.3.1 Diamondoid Halides; 3.3.2 Hydroxylated Diamondoids; 3.3.3 Metallated Nucleophilic Diamondoids; 3.3.4 Amino and Nitro Diamondoids and Their Derivatives; 3.3.5 Polyfunctionalized Diamondoids with Different Reactive Functionalities; 3.3.6 Alkyl-, Aryl-, Olefin-, Phosphine-, Cyano-, and Thiol-Substituted Diamondoids; 3.4 Organohybrids Built on Nanodiamond and Diamondoids and Their Applications.
- 3.4.1 Biological Applications of Nanodiamond and Diamondoid-Based Hybrids3.4.2 Polymeric Diamondoid Materials; 3.4.3 Molecular Mechanics and Electronics Innovations from Diamond Nanoassembly; 3.4.4 Synthetic and Catalytic Applications Associated to Modified Diamondoids; Abbreviations; References; 4 Titania-Based Hybrid Materials: From Molecular Precursors To The Controlled Design of Hierarchical Hybrid Materials; 4.1 Introduction; 4.2 Overview of the Reactivity of Precursors and Consequences on Structures at Large scale of Titanium-Based OXO-Polymers.
- 4.2.1 The Real Nature of the Precursor Ti(OR)44.2.2 Chemical Additives as Inhibitors of Condensation; 4.3 Main Chemical Routes for the Synthesis of Titania-Based Hybrid Materials; 4.3.1 Route A; 4.3.2 Route B; 4.3.3 Route C; 4.3.4 Route D; 4.4 Titania-Based Hybrid Mesostructured Materials; 4.4.1 Overview; 4.4.2 Evaporation-Induced Self-Assembly (EISA); 4.4.3 Hybrid O-I Titania-Based POMTFs; 4.5 Conclusion; References; 5 Functionalization of Zirconium Oxide Surfaces; 5.1 Introduction; 5.2 Why Zirconia-organic Hybrids?; 5.2.1 Mechanical Properties; 5.2.2 Chemical Properties.