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Bioinspired Catalysis : Metal-Sulfur Complexes /

This book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Weigand, Wolfgang, Schollhammer, Philippe
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Weinheim : Wiley-VCH, 2014.
Temas:
Acceso en línea:Texto completo

MARC

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245 0 0 |a Bioinspired Catalysis :  |b Metal-Sulfur Complexes /  |c edited by Wolfgang Weigand and Philippe Schollhammer. 
260 |a Weinheim :  |b Wiley-VCH,  |c 2014. 
300 |a 1 online resource 
336 |a text  |b txt  |2 rdacontent 
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588 0 |a Print version record. 
520 |a This book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center. 
505 0 |a Related Titles; Title Page; Copyright; List of Contributors; Preface; Part I: PrimordialMetal-Sulfur-Mediated Reactions; Chapter 1: From Chemical Invariance to Genetic Variability; 1.1 Heuristic of Biochemical Retrodiction; 1.2 Retrodicting the Elements of Life; 1.3 Retrodicting Pioneer Catalysis; 1.4 Retrodicting Metabolic Reproduction and Evolution; 1.5 Retrodicting Pioneer-Metabolic Reactions; 1.6 Early Evolution in a Spatiotemporal Flow Context; Acknowledgments; References; Chapter 2: Fe-S Clusters: Biogenesis and Redox, Catalytic, and Regulatory Properties; 2.1 Introduction. 
505 8 |a 2.2 Fe-S Cluster Biogenesis and Trafficking2.3 Redox Properties of Fe-S Clusters; 2.4 Fe-S Clusters and Catalysis; 2.5 Fe-S Clusters and Oxidative Stress; 2.6 Regulation of Protein Expression by Fe-S Clusters; 2.7 Conclusion; References; Part II: Model Complexes of the Active Site of Hydrogenases -- Proton and Dihydrogen Activation; Chapter 3: [NiFe] Hydrogenases; 3.1 Introduction; 3.2 Introduction to [NiFe] Hydrogenases; 3.3 Nickel Thiolate Complexes as Analogs of [NiFe] Hydrogenase; 3.4 [NiFe] Hydrogenase Model Complexes; 3.5 Analogs of [NiFe] Hydrogenase Incorporating Proton Relays. 
505 8 |a 3.6 Perspectives and Future ChallengesAcknowledgments; References; Chapter 4: [FeFe] Hydrogenase Models: an Overview; 4.1 Introduction; 4.2 Synthetic Strategies toward [FeFe] Hydrogenase Model Complexes; 4.3 Properties of Model Complexes; 4.4 Conclusion; References; Chapter 5: The Third Hydrogenase; 5.1 Introduction; 5.2 Initial Studies of Hmd; 5.3 Discovery that Hmd Contains a Bound Cofactor; 5.4 Discovery that Hmd is a Metalloenzyme; 5.5 Crystal Structure Studies of [Fe] Hydrogenase; 5.6 Mechanistic Models of [Fe] Hydrogenase; References. 
505 8 |a Chapter 6: DFT Investigation of Models Related to the Active Site of Hydrogenases6.1 Introduction; 6.2 QM Studies of Hydrogenases; 6.3 QM Studies of Synthetic Complexes Related to the Active Site of Hydrogenases; 6.4 Conclusions; References; Chapter 7: Mechanistic Aspects of Biological Hydrogen Evolution and Uptake; 7.1 Introduction; 7.2 [FeFe] Hydrogenases; 7.3 [NiFe] Hydrogenases; 7.4 [Fe] Hydrogenase; 7.5 Nitrogenase; References; Part III: Nitrogen Fixation; Chapter 8: Structures and Functions of the Active Sites of Nitrogenases; 8.1 Introduction; 8.2 Properties of Mo Nitrogenase. 
505 8 |a 8.3 Catalysis by Mo Nitrogenase8.4 Unique Features of V Nitrogenase; 8.5 Catalytic Properties of Isolated FeMo-co and FeVco; Acknowledgments; References; Chapter 9: Model Complexes of the Active Site of Nitrogenases: Recent Advances; 9.1 Introduction; 9.2 Structural Models of Metal-Sulfur Clusters in the Nitrogenases; 9.3 Functional Modeling at a Single Molybdenum Center; 9.4 Functional Modeling at a Single Iron Center; 9.5 The Hydrogen and Homocitrate Issues in Nitrogenase Model Chemistry; 9.6 Sulfur- and Metal-Metal Interaction in Functional Models of Nitrogenase. 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Catalysis. 
650 0 |a Surface chemistry. 
650 0 |a Metal sulfides. 
650 2 |a Catalysis 
650 6 |a Catalyse. 
650 6 |a Chimie des surfaces. 
650 6 |a Sulfures métalliques. 
650 7 |a SCIENCE  |x Chemistry  |x Inorganic.  |2 bisacsh 
650 7 |a Catalysis  |2 fast 
650 7 |a Metal sulfides  |2 fast 
650 7 |a Surface chemistry  |2 fast 
700 1 |a Weigand, Wolfgang. 
700 1 |a Schollhammer, Philippe. 
758 |i has work:  |a Bioinspired Catalysis (Text)  |1 https://id.oclc.org/worldcat/entity/E39PCFHt68tFrP9vpHH3MwDK3P  |4 https://id.oclc.org/worldcat/ontology/hasWork 
776 0 8 |i Print version:  |a Weigand, Wolfgang.  |t Bioinspired Catalysis.  |d Weinheim : Wiley-VCH, 2014  |z 9783527333080 
856 4 0 |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=1767040  |z Texto completo 
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