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N-Heterocyclic Carbenes : Effective Tools for Organometallic Synthesis.
"This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scien...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2014.
|
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
| LEADER | 00000cam a2200000 i 4500 | ||
|---|---|---|---|
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| 003 | OCoLC | ||
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| 006 | m o d | ||
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| 049 | |a UAMI | ||
| 100 | 1 | |a Nolan, Steven P. | |
| 245 | 1 | 0 | |a N-Heterocyclic Carbenes : |b Effective Tools for Organometallic Synthesis. |
| 260 | |a Hoboken : |b Wiley, |c 2014. | ||
| 300 | |a 1 online resource (569 pages) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 588 | 0 | |a Print version record. | |
| 504 | |a Includes bibliographical references and index at the end of each chapters. | ||
| 520 | |a "This comprehensive reference and handbook covers in depth all major aspects of the use of N-heterocyclic carbene-complexes in organic synthesis: from the theoretical background to characterization, and from cross-coupling reactions to olefin metathesis. Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist."-- |c Unedited summary from book | ||
| 505 | 0 | |a Related Titles; Title Page; Copyright; Dedication; List of Contributors; Preface; Chapter 1: N-Heterocyclic Carbenes; 1.1 Introduction; 1.2 Structure and Properties of NHCs; 1.3 Abnormal Carbenes; 1.4 Why Are NHCs Stable?; 1.5 Bonding of NHCs to Metal Centers; 1.6 Quantifying the Properties of NHCs; 1.7 N-Heterocyclic Carbenes in the Context of Other Stable Carbenes; 1.8 Synthesis of NHCs; 1.9 Salts and Adducts of NHCs; 1.10 Summary; References; Chapter 2: Tuning and Quantifying Steric and Electronic Effects of N-Heterocyclic Carbenes; 2.1 Introduction; 2.2 Steric Effects in NHC ligands. | |
| 505 | 8 | |a 2.3 Electronic Effects in NHC Ligands2.4 Conclusions; References; Chapter 3: Chiral Monodendate N-Heterocyclic Carbene Ligands in Asymmetric Catalysis; 3.1 Introduction; 3.2 NHC-Ru; 3.3 NHC-Rh; 3.4 NHC-Ir; 3.5 NHC-Ni; 3.6 NHC-Pd; 3.7 NHC-Cu; 3.8 NHC-Ag; 3.9 NHC-Au; 3.10 Conclusion; References; Chapter 4: (N-Heterocyclic Carbene)-Palladium Complexes in Catalysis; 4.1 Introduction; 4.2 Cross-Coupling Reactions; 4.3 Chelates and Pincer Ligands; 4.4 Asymmetric Catalysis; 4.5 Oxidation Reactions; 4.6 Telomerization, Oligomerization and Polymerization; 4.7 Anticancer NHC-Pd Complexes; References. | |
| 505 | 8 | |a Chapter 5: NHC Platinum(0) Complexes: Unique Catalysts for the Hydrosilylation of Alkenes and Alkynes5.1 Introduction; 5.2 Hydrosilylation of Alkenes: The Beginning; 5.3 Initial Results with Phosphine Ligands; 5.4 NHC Platinum(0) Complexes: The Breakthrough; 5.5 Hydrosilylation of Alkynes; 5.6 Conclusions; References; Chapter 6: Synthesis and Medicinal Properties of Silver-NHC Complexes and Imidazolium Salts; 6.1 Introduction; 6.2 Silver-NHC Complexes as Antimicrobial Agents; 6.3 Silver-NHC Complexes as Anticancer Agents; 6.4 Conclusions; References. | |
| 505 | 8 | |a Chapter 7: Medical Applications of NHC-Gold and -Copper Complexes7.1 Introduction; 7.2 Gold Antimicrobial Agents; 7.3 Metals as Antitumor Reagents; 7.4 Copper Complexes as Antitumoral Reagents; 7.5 Conclusion; References; Chapter 8: NHC-Copper Complexes and their Applications; 8.1 Introduction; 8.2 History of NHC-Copper Systems; 8.3 Hydrosilylation; 8.4 Allene Formation; 8.5 1,4-Reduction; 8.6 Conjugate Addition; 8.7 Hydrothiolation, Hydroalkoxylation, Hydroamination; 8.8 Carboxylation and Carbonylation (via Boronic Acids, CH Activation): CO2 Insertion. | |
| 505 | 8 | |a 8.9 [3 + 2] Cycloaddition Reaction: Formation of Triazole8.10 Allylic Substitution; 8.11 Carbene and Nitrene Transfer; 8.12 Boration Reaction; 8.13 Olefination of Carbonyl Derivatives; 8.14 Copper-Mediated Cross-Coupling Reaction; 8.15 Fluoride Chemistry; 8.16 Other Reactions; 8.17 Transmetalation; 8.18 Conclusion; References; Chapter 9: NHC-Au(I) Complexes: Synthesis, Activation, and Application; 9.1 Introduction; 9.2 Synthesis of NHC-Gold(I) Chlorides; 9.3 Activation of NHC-Au(I) Chlorides; 9.4 Applications of NHC-Au(I) Catalysts; 9.5 Conclusion; References. | |
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Carbenes (Methylene compounds) | |
| 650 | 0 | |a Organometallic compounds |x Synthesis. | |
| 650 | 6 | |a Carbènes. | |
| 650 | 6 | |a Composés organométalliques |x Synthèse. | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Carbenes (Methylene compounds) |2 fast | |
| 650 | 7 | |a Organometallic compounds |x Synthesis |2 fast | |
| 650 | 7 | |a Carbene |2 gnd | |
| 650 | 7 | |a Stickstoffheterocyclen |2 gnd | |
| 650 | 7 | |a Metallorganische Chemie |2 gnd | |
| 758 | |i has work: |a N-heterocyclic carbenes (Text) |1 https://id.oclc.org/worldcat/entity/E39PCGyVtJDFyTcXF9dhYybgXd |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
| 776 | 0 | 8 | |i Print version: |a Nolan, Steven P. |t N-Heterocyclic Carbenes : Effective Tools for Organometallic Synthesis. |d Hoboken : Wiley, ©2014 |z 9783527334902 |
| 856 | 4 | 0 | |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=1732126 |z Texto completo |
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