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Homogeneous catalysis for unreactive bond activation /
"This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters cover key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon"--
| Clasificación: | Libro Electrónico |
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| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, New Jersey :
Wiley,
2014.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Title Page; Copyright; Preface; Contributors; Chapter 1: Catalysis In C-Cl Activation; 1.1 Introduction; 1.2 Reductive Dechlorination; 1.3 Formation of C-C Bonds; 1.4 Formation of C-N Bonds; 1.5 Formation of C-O Bonds; 1.6 Formation of C-S Bonds; 1.7 Formation of C-B Bonds; 1.8 Conclusion and Outlook; References; Chapter 2: Homogeneous Transition-Metal-Catalyzed C-F Activation; 2.1 Background; 2.2 Transition-Metal-Mediated Cross-Coupling Reactions byC-F Bond Activation; 2.4 Transition-Metal-Promoted Dehydrofluorination by C-F Bond Activation.
- 2.5 The Applications of C-F Activation in Organic Synthesis2.6 Summary and Outlook; References; Chapter 3: Homogeneous Transition-Metal Catalyzed C-N Activation; 3.1 Background; 3.2 Palladium-Catalyzed C-N Activation; 3.3 Ruthenium-Catalyzed C-N Activation; 3.4 Nickel-Catalyzed C-N Activation; 3.5 Copper-Catalyzed C-N Activation; 3.6 Iron-Catalyzed C-N Activation; 3.7 Other-Transition-Metal-Catalyzed C-N Activation; 3.8 Computationally and Experimentally Mechanistic Studies; 3.9 Summary and Outlook; References; Chapter 4: Catalytic Carbon-Sulfur Bond Activation and Transformations.
- 4.1 Background4.2 C-S Bond Activation by Transition Metal Compounds; 4.3 Catalytic C-S Cleavage in Thioesters; 4.4 Catalytic C-S Cleavage in Dithioacetals; 4.5 Diverse Catalytic C-S Cleavage; 4.6 Summary and Outlook; References; Chapter 5: Homogeneous Transition-Metal-Catalyzed C-O Bond Activation; 5.1 Introduction; 5.2 Palladium-Catalyzed C-O Bond Activation; 5.3 Nickel-Catalyzed C-O Bond Activation; 5.4 Other-Transition-Metal-Catalyzed C-O Bond Activation; 5.5 Summary and Outlook; References; Chapter 6: Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization; 6.1 Overview.
- 6.2 Mechanism of C-H Cleavage6.3 Directed C-H Oxidation; 6.4 Hydroarylation; 6.5 Direct Arylation; 6.6 Carbonylation; 6.7 Hydroacylation; 6.8 Alkane Dehydrogenation; 6.9 Borylation and Silylation; 6.10 Summary and Outlook; References; Chapter 7: Catalysis in C-C Activation; 7.1 Introduction: Importance and Challenges in C-C Activation; 7.2 C-C Activation of Strained Molecules; 7.3 C-C Activation of Unstrained Molecules; 7.4 Summary and Perspective; References; Index; End User License Agreement.