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Developments in electrochemistry : science inspired by Martin Fleischmann /
Martin Fleischmann was truly one of the 'fathers' of modern electrochemistry having made major contributions to diverse topics within electrochemical science and technology. These include the theory and practice of voltammetry and in situ spectroscopic techniques, instrumentation, electroc...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Chichester, West Sussex :
John Wiley & Sons,
2014.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Developments in Electrochemistry; Contents; List of Contributors; 1 Martin Fleischmann
- The Scientist and the Person; The Publications of Martin Fleischmann; 2 A Critical Review of the Methods Available for Quantitative Evaluation of Electrode Kinetics at Stationary Macrodisk Electrodes; 2.1 DC Cyclic Voltammetry; 2.1.1 Principles; 2.1.2 Processing DC Cyclic Voltammetric Data; 2.1.3 Semiintegration; 2.2 AC Voltammetry; 2.2.1 Advanced Methods of Theory-Experiment Comparison; 2.3 Experimental Studies; 2.3.1 Reduction of [Ru(NH3)6]3+ in an Aqueous Medium.
- 2.3.2 Oxidation of FeII(C5H5)2 in an Aprotic Solvent2.3.3 Reduction of [Fe(CN)6]3- in an Aqueous Electrolyte; 2.4 Conclusions and Outlook; References; 3 Electrocrystallization: Modeling and Its Application; 3.1 Modeling Electrocrystallization Processes; 3.2 Applications of Models; 3.2.1 The Deposition of Lead Dioxide; 3.2.2 The Electrocrystallization of Cobalt; 3.3 Summary and Conclusions; References; 4 Nucleation and Growth of New Phases on Electrode Surfaces; 4.1 An Overview of Martin Fleischmanns Contributions to Electrochemical Nucleation Studies.
- 4.2 Electrochemical Nucleation with Diffusion-Controlled Growth4.3 Mathematical Modeling of Nucleation and Growth Processes; 4.4 The Nature of Active Sites; 4.5 Induction Times and the Onset of Electrochemical Phase Formation Processes; 4.6 Conclusion; References; 5 Organic Electrosynthesis; 5.1 Indirect Electrolysis; 5.2 Intermediates for Families of Reactions; 5.3 Selective Fluorination; 5.4 Two-Phase Electrolysis; 5.5 Electrode Materials; 5.6 Towards Pharmaceutical Products; 5.7 Future Prospects; References; 6 Electrochemical Engineering and Cell Design.
- 6.1 Principles of Electrochemical Reactor Design6.1.1 Cell Potential; 6.1.2 The Rate of Chemical Change; 6.2 Decisions During the Process of Cell Design; 6.2.1 Strategic Decisions; 6.2.2 Divided and Undivided Cells; 6.2.3 Monopolar and Bipolar Electrical Connections to Electrodes; 6.2.4 Scaling the Cell Current; 6.2.5 Porous 3D Electrode Structures; 6.2.6 Interelectrode Gap; 6.3 The Influence of Electrochemical Engineering on the Chlor-Alkali Industry; 6.4 Parallel Plate Cells; 6.5 Redox Flow Batteries; 6.6 Rotating Cylinder Electrode Cells; 6.7 Conclusions; References.
- 7 Electrochemical Surface-Enhanced Raman Spectroscopy (EC-SERS): Early History, Principles, Methods, and Experiments7.1 Early History of Electrochemical Surface-Enhanced Raman Spectroscopy; 7.2 Principles and Methods of SERS; 7.2.1 Electromagnetic Enhancement of SERS; 7.2.2 Key Factors Influencing SERS; 7.2.3 "Borrowing SERS Activity" Methods; 7.2.4 Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy; 7.3 Features of EC-SERS; 7.3.1 Electrochemical Double Layer of EC-SERS Systems; 7.3.2 Electrolyte Solutions and Solvent Dependency; 7.4 EC-SERS Experiments.