Iodine chemistry and applications /

Tatsuo Kaiho is the Director of Nihon Tennen Gas Co., Ltd. (Chiba, Japan), one of the most well-known iodine manufacturing companies in the world. The Director of the Society of Iodine Science, Dr. Kaiho developed novel iodine-containing materials and processes and presented independent research at...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Kaiho, Tatsuo
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken, New Jersey : John Wiley & Sons, Inc., [2014]
Temas:
Iodine.
Iodine > Industrial applications.
Iodine > Therapeutic use.
Iodine
Iode.
Iode > Applications industrielles.
Iodothérapie.
TECHNOLOGY & ENGINEERING > Chemical & Biochemical.
Iodine > Therapeutic use
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Iodine Chemistry and Applications Iodine Chemistry and Applications
  • Copyright
  • Contents
  • List of Contributors
  • Preface
  • Chapter 1 Overview
  • 1.1 Introduction
  • 1.2 Discovery and Naming
  • 1.3 Physicochemical Properties
  • 1.4 Production
  • 1.5 Synthesis
  • 1.6 Industrial Application
  • 1.7 Recycle
  • 1.8 Biological Activity
  • 1.9 Pharmaceuticals
  • 1.10 Agrochemicals
  • 1.11 Isotopes
  • References
  • Part I Characteristics, elemental of iodine
  • Chapter 2 Physical Properties of Iodine
  • References
  • Chapter 3 Analytical Methods for Iodine and Iodides
  • 3.1 Determination of Concentration of Iodine or Iodides in Solution
  • 3.2 Raman Spectroscopic Analysis of Polyiodides
  • 3.3 X-Ray Absorption Spectroscopic Analysis of Iodine and Iodides
  • References
  • Chapter 4 Ion Chromatography
  • 4.1 General Principles and Instrumentation
  • 4.2 Stationary Phases Used for IC of Iodine Species
  • 4.3 Mobile Phases
  • 4.4 Detection of Iodine Species in IC
  • 4.5 Strong and Weak Points of IC Determinations of Iodine Species
  • 4.6 Speciation Analysis Involving IC
  • 4.7 Selected Problems Associated with Preanalytical Factors Influencing IC of Iodine Species
  • 4.8 Storage and Preservation
  • 4.9 Trends and Future Directions of Iodine Determinations by IC
  • References
  • Chapter 5 Inorganic Iodides
  • 5.1 Introduction
  • 5.2 Hydrogen Iodide
  • 5.3 Hydriodic Acid
  • 5.4 Sodium Iodide
  • 5.5 Potassium Iodide
  • 5.6 Copper (I) Iodide
  • 5.7 Silver Iodide
  • 5.8 Nitrogen Triiodide
  • 5.9 Iodine Pentoxide
  • 5.10 Interhalogen Compound of Iodine
  • References
  • Chapter 6 Organic Iodides
  • 6.1 Introduction
  • 6.2 Iodination of Aliphatic Hydrocarbons
  • 6.3 Iodination of Aromatic Hydrocarbons
  • 6.4 Iodination of Alkenes
  • 6.5 Iodination of Alkynes
  • 6.6 Halogen-Iodine Exchange of Halo Compounds
  • 6.7 Iodination of Organonitrogen Compounds.
  • 6.8 Iodination of Alcohols
  • 6.9 Iodination of Other Compounds
  • References
  • Chapter 7 Hypervalent Iodine
  • 7.1 Introduction
  • 7.2 Structures and Properties
  • 7.3 Reactivity
  • 7.4 Application
  • 7.5 Recent Progress and Feature Outlook
  • References
  • Chapter 8 Iodine and Halogen Bonding
  • 8.1 Introduction
  • 8.2 I2 as Halogen Bonding Donor
  • References
  • Part II Production of iodine
  • Chapter 9 History of Iodine
  • Summary
  • 9.1 History of Saltpeter
  • 9.2 Courtois in Dijon
  • 9.3 Courtois in Paris
  • 9.4 Discovery of Iodine
  • References
  • Chapter 10 Production Process in the Past
  • References
  • Chapter 11 Iodine Production from Caliche
  • 11.1 Introduction
  • 11.2 Production Technology
  • 11.3 Obtaining Iodate Solutions
  • 11.4 Description of the Iodine Extraction Process
  • Reference
  • Chapter 12 Iodine Production from Oilfield Brine
  • 12.1 Iodine Production in the United States
  • References
  • Chapter 13 Iodine Production from Natural Gas Brine
  • 13.1 Natural Gas Brine
  • 13.2 Characteristics of Brine
  • 13.3 Iodine Accumulation in Brine
  • 13.4 Preservation and Destruction of Brine Deposits
  • 13.5 Production of Iodine from Natural Gas Brine
  • References
  • Chapter 14 Recycling of Iodine
  • 14.1 Introduction
  • 14.2 Iodine Waste from X-ray Contrast Agents
  • 14.3 Iodine Waste from Polarizing Films
  • 14.4 Iodine Waste from the Industry
  • 14.5 Summary
  • References
  • Part III Synthesis of iodine compounds
  • Chapter 15 Iodinating Reagents
  • 15.1 Molecular Iodine
  • 15.2 Iodine Chloride
  • 15.3 N-Iodosuccinimide
  • 15.4 1,3-Diiodo-5,5-Dimethylhydantoin
  • 15.5 N-Iodosaccharin
  • 15.6 Bis(pyridine)iodonium Tetrafluoroborate
  • 15.7 Others
  • References
  • Chapter 16 Oxidizing Agents
  • 16.1 Molecular Iodine
  • 16.2 Inorganic Iodine Compounds
  • 16.3 Organic Hypervalent Iodine Compounds
  • References.
  • Chapter 17 Reaction of Iodo Compounds
  • 17.1 Coupling Reactions with Organic Iodides
  • References
  • Chapter 18 Metal Iodides-Mediated Reaction
  • 18.1 Metal Iodides-Mediated Reaction
  • 18.2 Metal Iodide-Mediated Reaction (SmI2)
  • References
  • Part IV Biological Application of iodine
  • Chapter 19 Iodinated X-Ray Contrast Agents
  • 19.1 Historical Aspects
  • 19.2 Extracellular (Unspecific) Contrast Agents
  • 19.3 Targeted Contrast Agents
  • 19.4 Summary and Conclusions
  • References
  • Chapter 20 Iodine as Disinfectant
  • 20.1 Historical Survey
  • 20.2 Chemistry
  • 20.3 Preparations Containing or Releasing Free Iodine
  • 20.4 Organic Iodine Compounds
  • 20.5 Toxicity
  • 20.6 Practical Applications
  • 20.7 Residual Effects of Iodine Preparations
  • 20.8 Range of Action
  • References
  • Chapter 21 Synthetic Thyroid Hormone
  • 21.1 Introduction
  • 21.2 Thyroid Hormone Biosynthesis
  • 21.3 Thyroid Hormone Metabolism
  • 21.4 Thyroid Disease
  • 21.5 Hormone Replacement Therapy
  • 21.6 Synthetic Preparation of T4
  • References
  • Chapter 22 Iodine Deficiency Disorders and Their Correction Using Iodized Salt and/or Iodine Supplements
  • Ecology and Dietary Sources, Absorption, Metabolism and Excretion
  • 22.1 Effects of Deficiency
  • 22.2 Requirements and Prevalence of Iodine Deficiency Worldwide
  • 22.3 Prophylaxis and Treatment
  • Summary
  • References
  • Chapter 23 Pharmaceuticals: Therapeutic Agents
  • 23.1 Introduction
  • 23.2 Antiarrhythmic Agent: Amiodarone
  • 23.3 Eye Drops: Idoxuridine
  • References
  • Chapter 24 Agrochemicals and Anthelmintics
  • 24.1 Introduction
  • 24.2 Herbicides
  • 24.3 Fungicides
  • 24.4 Insecticides
  • 24.5 Anthelmintics
  • 24.6 Summary
  • References
  • Part V Industrial Application of iodine
  • Chapter 25 Diaryliodonium Salt Photoacid Generators
  • 25.1 Introduction
  • 25.2 Photoinduced Acid Generation.
  • 25.3 Photoinitiated Cationic Polymerizations
  • 25.4 Photoinitiated Condensation Polymerizations
  • 25.5 Imaging Using Diaryliodonium Photoacid Generators
  • 25.6 Summary
  • References
  • Chapter 26 Polarizing Films
  • 26.1 Introduction
  • 26.2 Iodine and the Development of Polarized Film
  • 26.3 Modern Polarizing Films
  • References
  • Chapter 27 Iodine in Polymer Synthesis: An Important Element for Precision Polymerizations
  • 27.1 Introduction
  • 27.2 Living Polymerization and Precision Polymerization
  • 27.3 Iodine in Living Cationic Polymerization Cationic Polymerization: Problems in Control
  • 27.4 Living Cationic Polymerization
  • 27.5 Iodine in Living Radical Polymerization
  • References
  • Chapter 28 Iodine in Dye-Sensitized Solar Cells
  • 28.1 Background
  • 28.2 Iodine at the Photoelectrode
  • 28.3 Iodine at the Counterelectrode
  • 28.4 Iodine in the Electrolyte
  • 28.5 Challenges with the Iodine-Based Redox System
  • 28.6 Conclusions and Outlook
  • References
  • Chapter 29 Fluorinated Repellents
  • 29.1 Overview of Fluorinated Repellents
  • 29.2 PFOA Issues
  • 29.3 Alternative Technologies
  • References
  • Chapter 30 Etching Gas
  • 30.1 High-Performance Silicon Dioxide Etching
  • 30.2 Environmentally Harmonized CF3I Plasma for Low-Damage and Highly Selective Low-k Etching
  • 30.3 Experimental
  • 30.4 Results and Discussion
  • 30.5 Summary
  • References
  • Chapter 31 Other Industrial Applications
  • 31.1 Catalyst
  • 31.2 Stabilizer
  • 31.3 Colorant
  • References
  • Part VI Bioinorganic chemistry and Environmental Chemistry of iodine
  • Chapter 32 Iodine Bioinorganic Chemistry: Physiology, Structures, and Mechanisms
  • 32.1 Introduction
  • 32.2 Basic Chemistry Of Iodine and Its Compounds
  • 32.3 Iodine in Seaweeds and Microbes
  • 32.4 Vanadium Haloperoxidases
  • 32.5 Concluding Remarks and Future Directions
  • Acknowledgments.
  • Abbreviations
  • References
  • Chapter 33 Atmospheric Chemistry of Iodine
  • References
  • Part 7 Radioisotope of iodine
  • Chapter 34 Radioactive Iodine
  • 34.1 Introduction
  • 34.2 Nuclear Power Plant Accident and Radioactive Iodine
  • 34.3 Properties of Radioactive Iodine
  • 34.4 Pharmaceuticals and Medical Devices Containing Radioactive Iodine
  • 34.5 Labeling Reaction of Pharmaceuticals Labeled with Radioactive Iodine
  • 34.6 Sodium Iodide [123I, 131I]
  • 34.7 Iofetamine [123I]
  • 34.8 Ioflupane [123I]
  • 34.9 BMIPP [123I]
  • 34.10 Iobenguane [123I]
  • 34.11 Iomazenil [123I]
  • 34.12 Iodine [131I] Tositumomab
  • 34.13 Summary and Future Perspective
  • References
  • Index
  • Supplemental Images
  • End User License Agreement.

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