Molecular Water Oxidation Catalysis.

Photocatalytic water splitting is a promising strategy for capturing energy from the sun by coupling light harvesting and the oxidation of water, in order to create clean hydrogen fuel. Thus a deep knowledge of the water oxidation catalysis field is essential to be able to come up with useful energy...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Llobet, Antoni
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken : Wiley, 2014.
Temas:
Electric power production from chemical action.
Energy harvesting.
Renewable energy sources.
Water > Purification > Oxidation > By-products.
Électricité > Production par réaction chimique.
Récupération d'énergie.
Énergies renouvelables.
Eau > Épuration > Oxydation > Sous-produits.
Electric power production from chemical action
Energy harvesting
Renewable energy sources
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Title Page
  • Copyright
  • Contents
  • List of Contributors
  • Preface
  • Chapter 1 Structural Studies of Oxomanganese Complexes for Water Oxidation Catalysis
  • 1.1 Introduction
  • 1.2 Structural Studies of the OEC
  • 1.3 The Dark-Stable State of the OEC
  • 1.4 Biomimetic Oxomanganese Complexes
  • 1.5 Base-Assisted O-O Bond Formation
  • 1.6 Biomimetic Mn Catalysts for Artificial Photosynthesis
  • 1.7 Conclusion
  • Acknowledgments
  • References
  • Chapter 2 O-O Bond Formation by a Heme Protein: The Unexpected Efficiency of Chlorite Dismutase
  • 2.1 Introduction
  • 2.2 Origins of O2-Evolving Chlorite Dismutases (Clds)
  • 2.3 Major Structural Features of the Proteins and their Active Sites
  • 2.4 Efficiency, Specificity, and Stability
  • 2.5 Mechanistic Insights from Surrogate Reactions with Peracids and Peroxide
  • 2.6 Possible Mechanisms
  • 2.7 Conclusion
  • Acknowledgements
  • References
  • Chapter 3 Ru-Based Water Oxidation Catalysts
  • 3.1 Introduction
  • 3.2 Proton-Coupled Electron Transfer (PCET) and Water Oxidation Thermodynamics
  • 3.3 O-O Bond Formation Mechanisms
  • 3.4 Polynuclear Ru Water Oxidation Catalysts
  • 3.5 Mononuclear Ru WOCs
  • 3.6 Anchored Molecular Ru WOCs
  • 3.7 Light-Induced Ru WOCs
  • 3.8 Conclusion
  • Acknowledgments
  • References
  • Chapter 4 Towards the Visible Light-Driven Water Splitting Device: Ruthenium Water Oxidation Catalysts with Carboxylate-Containing Ligands
  • 4.1 Introduction
  • 4.2 Binuclear Ru Complexes
  • 4.3 Mononuclear Ru Complexes
  • 4.3.1 Ru-O2N-N3 Analogs
  • 4.3.2 Ru-O2N2-N2 Analogs
  • 4.4 Homogeneous Light-Driven Water Oxidation
  • 4.4.1 The Three-Component System
  • 4.4.2 The Supramolecular Assembly Approach
  • 4.5 Water Oxidation Device
  • 4.5.1 Electrochemical Water Oxidation Anode
  • 4.5.2 Photo-Anode for Water Oxidation
  • 4.6 Conclusion
  • References.
  • 8.2 Fe-Tetrasulfophthalocyanine
  • 8.3 Fe-TAML
  • 8.4 Fe-mcp
  • 8.5 Fe2O3 as a Microheterogeneous Catalyst
  • 8.6 Conclusion
  • References
  • Chapter 9 Water Oxidation by Co-Based Oxides with Molecular Properties
  • 9.1 Introduction
  • 9.2 CoCat Formation
  • 9.3 Structure and Structure-Function Relations
  • 9.4 Functional Characterization
  • 9.5 Directly Light-Driven Water Oxidation
  • References
  • Chapter 10 Developing Molecular Copper Complexes for Water Oxidation
  • 10.1 Introduction
  • 10.2 A Biomimetic Approach
  • 10.2.1 Thermochemistry: Developing Oxidant/Base Combinations as PCET Reagents
  • 10.2.2 Copper Complexes with Alkylamine Ligands
  • 10.2.3 Copper Complexes with Anionic Ligands
  • 10.2.4 Lessons Learned: Thermochemical Insights and Oxidant/Base Compatibility
  • 10.3 An Aqueous System: Electrocatalysis with (bpy)Cu(II) Complexes
  • 10.3.1 System Selection: bpy + Cu
  • 10.3.2 Observing Electrocatalysis
  • 10.3.3 Catalyst Turnover Number and Turnover Frequency
  • 10.3.4 Catalyst Speciation: Monomer, Dimer, or Nanoparticles?
  • 10.4 Conclusion
  • Acknowledgement
  • References
  • Chapter 11 Polyoxometalate Water Oxidation Catalytic Systems
  • 11.1 Introduction
  • 11.2 Recent POM WOCs
  • 11.3 Assessing POM WOC Reactivity
  • 11.4 The Ru(oxbpy)32+/S2O82- System
  • 11.5 Ru(bpy)33+ as an Oxidant for POM WOCs
  • 11.6 Additional Aspects of WOC System Stability
  • 11.7 Techniques for Assessing POM WOC Stability
  • 11.8 Conclusion
  • Acknowledgments
  • References
  • Chapter 12 Quantum Chemical Characterization of Water Oxidation Catalysts
  • 12.1 Introduction
  • 12.2 Computational Details
  • 12.2.1 Density Functional Theory Calculations
  • 12.2.2 Multiconfigurational Calculations
  • 12.3 Methodology
  • 12.3.1 Solvation and Standard Reduction Potentials
  • 12.3.2 Multideterminantal State Energies.
  • 12.4 Water Oxidation Catalysts
  • 12.4.1 Ruthenium-Based Catalysts
  • 12.4.2 Cobalt-Based Catalysts
  • 12.4.3 Iron-Based Catalysts
  • 12.5 Conclusion
  • References
  • Index
  • Supplemental Images.

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