Introduction to Chemical Engineering Kinetics and Reactor Design.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Hill, Charles G.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Wiley, 2014.
Temas:
Chemical kinetics.
Chemical reactors > Design and construction.
Cinétique chimique.
Chemical kinetics
Chemical reactors > Design and construction
Electronic books.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Title Page
  • Contents
  • Preface
  • Preface to the First Edition
  • Chapter 1. Stoichiometric Coefficients and Reaction Progress Variables
  • 1.0 Introduction
  • 1.1 Basic Stoichiometric Concepts
  • 1.1.1 Stoichiometric Coefficients
  • 1.1.2 Reaction Progress Variables
  • Literature Citation
  • Chapter 2. Thermodynamics of Chemical Reactions
  • 2.0 Introduction
  • 2.1 Chemical Potentials and Standard States
  • 2.2 Energy Effects Associated with Chemical Reactions
  • 2.3 Sources of Thermochemical Data
  • 2.4 The Equilibrium Constant and its Relation to DeltaG0
  • 2.5 Effects of Temperature and Pressure Changes on the Equilibrium Constant
  • 2.6 Determination of Equilibrium Compositions
  • 2.7 Effects of Reaction Conditions on Equilibrium Yields
  • 2.7.1 Effects of Temperature Changes
  • 2.7.2 Effects of Total Pressure
  • 2.7.3 Effect of Addition of Inert Gases
  • 2.7.4 Effect of Addition of Catalysts
  • 2.7.5 Effect of Excess Reactants
  • 2.8 Heterogeneous Reactions
  • 2.9 Equilibrium Treatment of Simultaneous Reactions
  • 2.10 Supplementary Reading References
  • Literature Citations
  • Problems
  • Chapter 3. Basic Concepts in Chemical Kinetics: Determination of the Reaction Rate Expression
  • 3.0 Introduction
  • 3.0.1 Reaction Orders
  • 3.0.2 The Reaction Rate Constant
  • 3.1 Mathematical Characterization of Simple Reaction Systems
  • 3.1.1 Mathematical Characterization of Simple Constant Volume Reaction Systems
  • 3.1.2 Mathematical Characterization of Simple Variable Volume Reaction Systems
  • 3.2 Experimental Aspects of Kinetic Studies
  • 3.2.1 Preliminary Questions to Be Answered in Experimental Kinetics Studies
  • 3.2.2 Experimental Techniques and Apparatus
  • 3.3 Techniques for the Interpretation of Kinetic Data
  • 3.3.1 Differential Methods for the Treatment of Rate Data
  • 3.3.2 Integral Methods for the Treatment of Rate Data
  • 3.3.3 Techniques for the Analysis of Reaction Rate Data That Are Suitable for Use with Either Integral or Differential Methods
  • 3.3.4 Determination of the Activation Energy
  • 3.3.5 Precision of Rate Measurements for Simple Irreversible Reactions
  • Literature Citations
  • Problems
  • Chapter 4. Basic Concepts in Chemical Kinetics: Molecular Interpretations of Kinetic Phenomena
  • 4.0 Introduction
  • 4.1 Reaction Mechanisms
  • 4.1.1 The Nature of the Problem
  • 4.1.2 Basic Assumptions Involved in the Derivation of a Rate Expression from a Proposed Reaction Mechanism
  • 4.1.3 Preliminary Criteria for Testing a Proposed Reaction Mechanism: Stoichiometry and Derivation of a Rate Expression for the Mechanism
  • 4.1.4 From Stoichiometry and Rate Expression to Mechanism
  • 4.1.5 Additional Methods and Principles Used in Investigations of Reaction Mechanisms
  • 4.2 Chain Reactions
  • 4.2.1 The Reaction between Hydrogen and Bromine: H2 + Br2 \rightarrow 2HBr

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