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Green Energetic Materials.
Since the end of the 20th century it has been increasingly realised that the use, or production, of many energetic materials leads to the release of substances which are harmful to both humans and the environment. To address this, the principles of green chemistry can be applied to the design of new...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2014.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Green Energetic Materials; Contents; List of Contributors; Preface; 1. Introduction to Green Energetic Materials; 1.1 Introduction; 1.2 Green Chemistry and Energetic Materials; 1.3 Green Propellants in Civil Space Travel; 1.3.1 Green Oxidizers to Replace Ammonium Perchlorate; 1.3.2 Green Liquid Propellants to Replace Hydrazine; 1.3.3 Electric Propulsion; 1.4 Conclusions; References; 2. Theoretical Design of Green Energetic Materials: Predicting Stability, Detection, Synthesis and Performance; 2.1 Introduction; 2.2 Computational Methods; 2.3 Green Propellant Components; 2.3.1 Trinitramide.
- 2.3.1.1 Synthesis and Detection2.3.1.2 Properties and Performance; 2.3.2 Energetic Anions Rich in Oxygen and Nitrogen; 2.3.2.1 Trinitrogen Dioxide Anion; 2.3.2.2 1-Nitro-2-oxo-3-Amino-Triazene Anion; 2.3.3 The Pentazolate Anion and its Oxy-Derivatives; 2.3.3.1 Kinetic Stability; 2.3.3.2 Spectroscopic Detection; 2.3.3.3 Synthesis; 2.3.3.4 Performance; 2.3.4 Tetrahedral N4; 2.3.4.1 Potential Energy Surface; 2.3.4.2 Spectroscopic Detection; 2.3.4.3 Synthesis; 2.3.4.4 Thermodynamic Stability and Performance; 2.4 Conclusions; References.
- 3. Some Perspectives on Sensitivity to Initiation of Detonation3.1 Energetic Materials and Green Chemistry; 3.2 Sensitivity: Some Background; 3.3 Sensitivity Relationships; 3.4 Sensitivity: Some Relevant Factors; 3.4.1 Amino Substituents; 3.4.2 Layered (Graphite-Like) Crystal Lattice; 3.4.3 Free Space in the Crystal Lattice; 3.4.4 Weak Trigger Bonds; 3.4.5 Molecular Electrostatic Potentials; 3.5 Summary; Acknowledgments; References; 4. Advances Toward the Development of "Green" Pyrotechnics; 4.1 Introduction; 4.2 The Foundation of "Green" Pyrotechnics.
- 4.3 Development of Perchlorate-Free Pyrotechnics4.3.1 Perchlorate-Free Illuminating Pyrotechnics; 4.3.2 Perchlorate-Free Simulators; 4.4 Removal of Heavy Metals from Pyrotechnic Formulations; 4.4.1 Barium-Free Green-Light Emitting Illuminants; 4.4.2 Barium-Free Incendiary Compositions; 4.4.3 Lead-Free Pyrotechnic Compositions; 4.4.4 Chromium-Free Pyrotechnic Compositions; 4.5 Removal of Chlorinated Organic Compounds from Pyrotechnic Formulations; 4.5.1 Chlorine-Free Illuminating Compositions; 4.6 Environmentally Friendly Smoke Compositions.
- 4.6.1 Environmentally Friendly Colored Smoke Compositions4.6.2 Environmentally Friendly White Smoke Compositions; 4.7 Conclusions; Acknowledgments; Abbreviations; References; 5. Green Primary Explosives; 5.1 Introduction; 5.1.1 What is a Primary Explosive?; 5.1.1.1 Common Initiating Devices: Detonators/Primers/Blasting Caps; 5.1.2 The Case for Green Primary Explosives; 5.1.3 Legacy Primary Explosives; 5.1.3.1 Lead Azide (LA); 5.1.3.2 Lead Styphnate (LS); 5.2 Green Primary Explosive Candidates; 5.2.1 Inorganic Compounds; 5.2.1.1 Silver Azide (SA); 5.2.1.2 Other Inorganic Azides.