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Copper-catalyzed asymmetric synthesis /
This book reflects the increasing interest among the chemical synthetic community in the area of asymmetric copper-catalyzed reactions, and introduces readers to the latest, most significant developments in the field. The contents are organized according to reaction type and cover mechanistic and sp...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Weinheim :
Wiley-VCH,
2014.
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| Temas: | |
| Acceso en línea: | Texto completo |
| Sumario: | This book reflects the increasing interest among the chemical synthetic community in the area of asymmetric copper-catalyzed reactions, and introduces readers to the latest, most significant developments in the field. The contents are organized according to reaction type and cover mechanistic and spectroscopic aspects as well as applications in the synthesis of natural products. A whole chapter is devoted to understanding how primary organometallics interact with copper to provide selective catalysts for allylic substitution and conjugate addition, both of which are treated in separate chapters. Another is devoted to the variety of substrates and experimental protocols, while an entire chapter covers the use on non-carbon nucleophiles. Other chapters deal with less-known reactions, such as carbometallation or the additions to imines and related systems, while the more established reactions cyclopropanation and aziridination as well as the use of copper (II) Lewis acids are warranted their own special chapters. Two further chapters concern the processes involved, as determined by mechanistic studies. Finally, a whole chapter is devoted to the synthetic applications. This book is essential reading for researchers at academic institutions and professionals at pharmaceutical or agrochemical companies. |
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| Descripción Física: | 1 online resource (xvi, 454 pages) : illustrations |
| Bibliografía: | Includes bibliographical references at the end of each chapters and index. |
| ISBN: | 9783527664573 3527664572 9783527664603 3527664602 9783527664580 3527664580 9783527664597 3527664599 1306290996 9781306290999 |