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Supported Ionic Liquids : Fundamentals and Applications.
This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coup...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2013.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Supported Ionic Liquids; Contents; Preface; List of Contributors; Chapter 1 Introduction; 1.1 A Century of Supported Liquids; 1.2 Supported Ionic Liquids; 1.3 Applications in Catalysis; 1.4 Applications in Separation; 1.5 Coating of Heterogeneous Catalysts; 1.6 Monolayers of IL on Surfaces; 1.7 Conclusion; References; Part I Concept and Building Blocks; Chapter 2 Introducing Ionic Liquids; 2.1 Introduction; 2.2 Preparation; 2.3 Liquid Range; 2.4 Structures; 2.4.1 The Liquid/Solid Interface; 2.4.2 The Liquid/Gas Interface; 2.5 Physical Properties; 2.5.1 The Liquid/Solid Interface.
- 2.5.2 The Liquid/Gas Interface2.5.3 Polarity; 2.5.4 Chromatographic Measurements and the Abraham Model of Polarity; 2.5.5 Infinite Dilution Activity Coefficients; 2.6 Effects of Ionic Liquids on Chemical Reactions; 2.7 Ionic Liquids as Process Solvents in Industry; 2.8 Summary; References; Chapter 3 Porous Inorganic Materials as Potential Supports for Ionic Liquids; 3.1 Introduction; 3.2 Porous Materials
- an Overview; 3.2.1 History; 3.2.2 Pore Size; 3.2.3 Structural Aspects; 3.2.4 Chemistry; 3.2.5 Synthesis; 3.3 Silica-Based Materials
- Amorphous; 3.3.1 Silica Gels.
- 3.3.2 Precipitated Silicas3.3.3 Porous Glass; 3.4 Layered Materials; 3.5 Microporous Materials; 3.5.1 Zeolites; 3.5.2 AlPOs/SAPOs; 3.5.3 Hierarchical Porosity in Zeolite Crystals; 3.6 Ordered Mesoporous Materials; 3.6.1 Silica-Based Classical Compounds; 3.6.2 PMOs; 3.6.3 Mesoporous Carbons; 3.6.4 Other Mesoporous Oxides; 3.6.5 Anodic Oxidized Materials; 3.7 Structured Supports and Monolithic Materials; 3.7.1 Monoliths with Hierarchical Porosity; 3.7.2 Hierarchically Structured Reactors; 3.8 Conclusions; References; Chapter 4 Synthetic Methodologies for Supported Ionic Liquid Materials.
- 4.1 Introduction4.2 Support Materials; 4.3 Preparation Methods for Supported Ionic Liquids; 4.3.1 Incipient Wetness Impregnation; 4.3.2 Freeze-Drying; 4.3.3 Spray Coating; 4.3.4 Chemically Bound Ionic Liquids; 4.3.5 IL-Silica Hybrid Materials; 4.4 Summary; References; Part II Synthesis and Properties; Chapter 5 Pore Volume and Surface Area of Supported Ionic Liquids Systems; 5.1 Example I: [EMIM][NTf2] on Porous Silica; 5.2 Example II: SCILL Catalyst (Commercial Ni catalyst) Coated with [BMIM][OcSO4]; Acknowledgments; Symbols; Abbreviations; References.
- Chapter 6 Transport Phenomena, Evaporation, and Thermal Stability of Supported Ionic Liquids6.1 Introduction; 6.2 Diffusion of Gases and Liquids in ILs and Diffusivity of ILs in Gases; 6.2.1 Diffusivity of Gases and Liquids in ILs; 6.2.2 Diffusion Coefficient of Evaporated ILs in Gases; 6.3 Thermal Stability and Vapor Pressure of Pure ILs; 6.3.1 Drawbacks and Opportunities Regarding Stability and Vapor Pressure Measurements of ILs; 6.3.2 Experimental Methods to Determine the Stability and Vapor Pressure of ILs; 6.3.3 Data Evaluation and Modeling Methodology.