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Monitoring Polymerization Reactions : From Fundamentals to Applications.

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understandin...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Reed, Wayne F.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Wiley, 2013.
Temas:
Acceso en línea:Texto completo

MARC

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245 1 0 |a Monitoring Polymerization Reactions :  |b From Fundamentals to Applications. 
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505 0 |a TITLE PAGE; COPYRIGHT PAGE; PREFACE; INTRODUCTION; CONTRIBUTORS; SECTION 1: OVERVIEW OF POLYMERIZATION REACTIONS AND KINETICS; 1 FREE RADICAL AND CONDENSATION POLYMERIZATIONS; 1.1 INTRODUCTION; 1.2 FREE RADICAL POLYMERIZATION; 1.3 CONDENSATION POLYMERIZATION; 1.4 CONCLUSIONS; REFERENCES; 2 OVERVIEW OF CONTROLLED/LIVING POLYMERIZATION METHODS OF VINYL MONOMERS; 2.1 SCOPE; 2.2 DEFINITION OF LIVING POLYMERIZATIONS; 2.3 SIGNIFICANCE OF LIVING POLYMERIZATIONS; 2.4 ATTRIBUTES OF A CONTROLLED/LIVING POLYMERIZATIONS; 2.5 THERMODYNAMIC CONSIDERATIONS FOR CONTROLLED/LIVING POLYMERIZATIONS. 
505 8 |a 2.6 TYPES OF LIVING POLYMERIZATIONS2.7 CONTROLLED RADICAL POLYMERIZATIONS; 2.8 ARCHITECTURAL POSSIBILITIES WITH CONTROLLED/LIVING POLYMERIZATION METHODS; 2.9 CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; 3 STIMULI-RESPONSIVE POLYMERS VIA CONTROLLED RADICAL POLYMERIZATION; 3.1 INTRODUCTION; 3.2 SYNTHESIS OF STIMULI-RESPONSIVE POLYMERS; 3.3 BLOCK COPOLYMERS IN SOLUTION; 3.4 CROSS-LINKED MICELLES; 3.5 STIMULI-RESPONSIVE COPOLYMERS IN BIOCONJUGATES; 3.6 CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES. 
505 8 |a 4 REACTIONS IN HETEROGENEOUS MEDIA: EMULSION, MINIEMULSION, MICROEMULSION, SUSPENSION, AND DISPERSION POLYMERIZATION4.1 INTRODUCTION; 4.2 DESCRIPTION OF DIFFERENT POLYMERIZATION TECHNIQUES; 4.3 EMULSION POLYMERIZATION; 4.4 MINIEMULSION POLYMERIZATION; 4.5 MICROEMULSION POLYMERIZATION; 4.6 SUSPENSION POLYMERIZATION; 4.7 DISPERSION POLYMERIZATION; REFERENCES; SECTION 2: POLYMERIZATION CHARACTERIZATION AND MONITORING METHODS; 5 POLYMER CHARACTERISTICS; 5.1 INTRODUCTION; 5.2 POLYMER CONFORMATIONS AND DIMENSIONS; 5.3 MOLECULAR WEIGHT DISTRIBUTIONS (MWDs) AND AVERAGES. 
505 8 |a 5.4 POLYMER HYDRODYNAMIC CHARACTERISTICS5.5 ELECTRICALLY CHARGED POLYMERS AND COLLOIDS; 5.6 THERMODYNAMICS OF POLYMER SOLUTIONS; 5.7 RHEOLOGY; 5.8 CHARACTERISTICS OF POLYMERIZATION REACTIONS; 5.9 SUMMARY; REFERENCES; 6 INFRARED (MIR, NIR), RAMAN, AND OTHER SPECTROSCOPIC METHODS; 6.1 INTRODUCTION; 6.2 FUNDAMENTALS; 6.3 MODEL BUILDING AND CALIBRATION; 6.4 MONITORING AND CONTROL OF POLYMERIZATION REACTIONS; 6.5 CONCLUSIONS; REFERENCES; 7 CALORIMETRY, CONDUCTIVITY, DENSIMETRY, AND RHEOLOGICAL MEASUREMENTS; 7.1 INTRODUCTION; 7.2 REACTION CALORIMETRY; 7.3 CONDUCTIVITY; 7.4 DENSIMETRY. 
505 8 |a 7.5 RHEOLOGICAL SENSORS7.6 CONCLUSIONS; REFERENCES; 8 LIGHT SCATTERING; 8.1 INTRODUCTION; 8.2 DYNAMIC LIGHT SCATTERING; 8.3 STATIC LIGHT SCATTERING; ISOTROPIC SYSTEMS; 8.4 STATIC LIGHT SCATTERING: ANISOTROPIC SYSTEMS; 8.5 NOMENCLATURE; REFERENCES; 9 GPC/SEC AS A KEY TOOL FOR ASSESSMENT OF POLYMER QUALITY AND DETERMINATION OF MACROMOLECULAR PROPERTIES; 9.1 INTRODUCTION; 9.2 BASIC CONCEPTS OF SEC; 9.3 SEC ASPECTS OF SEPARATION; 9.4 SEC ASPECTS OF DETECTION; 9.5 COMPREHENSIVE 2D CHROMATOGRAPHY; REFERENCES. 
520 |a Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full. 
520 8 |a Advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant. 
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