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The organometallic chemistry of the transition metals /
Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, New Jersey :
Wiley,
[2014]
|
| Edición: | Sixth edition. |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 100 | 1 | |a Crabtree, Robert H., |d 1948- | |
| 245 | 1 | 4 | |a The organometallic chemistry of the transition metals / |c by Robert H. Crabtree. |
| 250 | |a Sixth edition. | ||
| 264 | 1 | |a Hoboken, New Jersey : |b Wiley, |c [2014] | |
| 264 | 4 | |c ©2014 | |
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 504 | |a Includes bibliographical references and index. | ||
| 588 | 0 | |a Print version record and CIP data provided by publisher. | |
| 520 | |a Fully updated and expanded to reflect recent advances, the sixth edition of this bestselling text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. Increased focus is given to organic synthesis applications, nanoparticle science, and green chemistry. This edition features: New sections on Multifunctional Ligands, Oxidation Catalysis, and Green ChemistryExpanded discussion on to. | ||
| 505 | 8 | |a 9.3 Hydrogenation -- Oxidative Addition Pathway -- Directing Effects -- Asymmetric Catalysis -- Reversibility -- Heterolytic H2 Activation -- Homolytic H2 Activation -- Outer Sphere Hydrogenation -- Transfer Hydrogenation -- Nanoparticles -- 9.4 Alkene Hydroformylation -- Chelating and Phosphite Ligands -- 9.5 Alkene Hydrocyanation -- 9.6 Alkene Hydrosilylation and Hydroboration -- Hydrosilylation -- Hydroboration -- 9.7 Coupling Reactions -- 9.8 Organometallic Oxidation Catalysis -- Oxidase Reactions -- Water Splitting and C-H Oxidation -- 9.9 Surface, Supported, and Cooperative Catalysis -- Surface Organometallic Chemistry -- Cooperative Catalysis -- Hidden Acid Catalysis -- References -- Problems -- 10: Physical Methods -- 10.1 Isolation -- 10.2 1H NMR Spectroscopy -- Virtual Coupling -- Diastereotopy -- Chemical Shifts -- Paramagnetic NMR -- 10.3 13C NMR Spectroscopy -- 10.4 31P NMR Spectroscopy -- Mechanistic Study of Wilkinson Hydrogenation -- 10.5 Dynamic NMR -- Rate of Fluxionality -- Ligand Fluxionality -- 10.6 Spin Saturation Transfer -- 10.7 T1 and the Nuclear Overhauser Effect -- T1 and H2 Complexes -- PHIP and SABRE -- Nuclear Overhauser Effect -- 10.8 IR Spectroscopy -- Carbonyls -- Other Ligands -- Band Identification by Isotope Substitution -- Raman Spectroscopy -- 10.9 Crystallography -- Limitations -- 10.10 Electrochemistry and EPR -- 10.11 Computation -- 10.12 Other Methods -- Mass Spectroscopy -- Single-Molecule Imaging -- Interpretation of Results -- References -- Problems -- 11: M-L Multiple Bonds -- 11.1 Carbenes -- Fischer versus Schrock Carbenes -- Fischer Carbenes -- Schrock Carbenes -- Intermediate Cases -- Boryls -- 11.2 Carbynes -- Synthesis -- Structure and Spectra -- Reactions -- 11.3 Bridging Carbenes and Carbynes -- Structure and Spectra -- Reactions -- 11.4 N-Heterocyclic Carbenes -- Synthesis of NHC Complexes. | |
| 505 | 8 | |a Polydentate NHCs -- Applications -- 11.5 Multiple Bonds to Heteroatoms -- Oxo Wall -- Synthesis -- Spectra and Structure -- References -- Problems -- 12: Applications -- 12.1 Alkene Metathesis -- Mechanism -- Selectivity in Cross Metathesis -- Commercial Applications -- 12.2 Dimerization, Oligomerization, and Polymerization of Alkenes -- Catalyst Activation -- Microstructure -- Mechanism -- SHOP Oligomerization -- 12.3 Activation of CO And CO2 -- Water-Gas Shift -- Monsanto Acetic Acid Process -- CO2 Activation -- 12.4 C-H Activation -- Shilov Chemistry -- Other Routes -- C-C Bond Formation and Cleavage -- 12.5 Green Chemistry -- Alcohol Activation and Hydrogen Borrowing -- 12.6 Energy Chemistry -- References -- Problems -- 13: Clusters, Nanoparticles, Materials, and Surfaces -- 13.1 Cluster Structures -- Effective Atomic Number (EAN) Rule -- Wade-Mingos Rules -- 13.2 The Isolobal Analogy -- 13.3 Nanoparticles -- 13.4 Organometallic Materials -- Bulk Materials -- Porous Materials -- Metal Organic Frameworks (MOFs) -- Porous Organic Polymers (POPs) -- Organometallic Polymers -- Molecular Wires -- Molecular Electronics -- Nonlinear Optical (NLO) Materials -- Organic Light-Emitting Diodes (OLEDs) -- Sensors -- References -- Problems -- 14: Organic Applications -- 14.1 Carbon-Carbon Coupling -- 14.2 Metathesis -- 14.3 Cyclopropanation And C-H Insertion -- 14.4 Hydrogenation -- Kinetic Resolution -- Asymmetric Hydrogenation -- 14.5 Carbonylation -- 14.6 Oxidation -- 14.7 C-H Activation -- 14.8 Click Chemistry -- References -- Problems -- 15: Paramagnetic and High Oxidation-State Complexes -- 15.1 Magnetism and Spin States -- Spin States -- Influence of Spin State Changes on Kinetics and Thermodynamics -- 3d versus 4d and 5d Metals -- NMR Spectroscopy -- 15.2 Polyalkyls and Polyhydrides -- Group 4 -- Group 5 -- Group 6 -- Group 7 -- Groups 8-l0 -- Group 11. | |
| 505 | 8 | |a ?7 Ligands --?8 Ligands -- 5.6 Isolobal Replacement and Metalacycles -- 5.7 Stability of Polyene and Polyenyl Complexes -- References -- Problems -- 6: Oxidative Addition and Reductive Elimination -- 6.1 Introduction -- 6.2 Concerted Additions -- 6.3 SN2 Pathways -- 6.4 Radical Mechanisms -- 6.5 Ionic Mechanisms -- 6.6 Reductive Elimination -- Octahedral Complexes -- Other Complexes -- Binuclear Reductive Elimination -- Reductive Elimination of C-F, -O, and -N -- 6.7?-Bond Metathesis -- 6.8 Oxidative Coupling and Reductive Fragmentation -- References -- Problems -- 7: Insertion and Elimination -- 7.1 Introduction -- 7.2 CO Insertion -- Enhancing Insertion Rates -- Apparent Insertions -- Double Insertion -- 7.3 Alkene Insertion -- Regiochemistry of Insertion -- Syn versus Apparent Anti Insertion -- Insertion into M-H versus M-R -- Radical Pathways -- Alternating CO/Alkene Insertion -- 7.4 Outer Sphere Insertions -- 7.5?,?,?, And? Elimination --? Elimination --? Elimination -- Other Eliminations -- References -- Problems -- 8: Addition and Abstraction -- 8.1 Introduction -- 8.2 Nucleophilic Addition to CO -- 8.3 Nucleophilic Addition to Polyenes and Polyenyls -- Davies-Green-Mingos Rules -- Wacker Process -- Alkyne Hydration -- 8.4 Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls -- Hydrides -- Alkyls and Acyls -- 8.5 Electrophilic Addition and Abstraction -- Addition to the Metal -- Addition to a Metal-Ligand Bond -- Addition to Ligand -- Abstraction of Alkyl Groups -- 8.6 Single-Electron Transfer and Radical Reactions -- References -- Problems -- 9: Homogeneous Catalysis -- 9.1 Catalytic Cycles -- Homogeneity -- Thermodynamics -- Kinetics -- Mechanism, Intermediates, and Kinetic Competence -- Cooperative Catalysis -- Deactivation -- Choice of Metal and Ligands -- 9.2 Alkene Isomerization -- Alkyl Mechanism -- Allyl Mechanism. | |
| 505 | 8 | |a Reductive Elimination -- Kinetic Stability from Bulky Substituents -- Preparation of Metal Alkyls -- Cyclometalation -- Oxidative Addition -- Insertion -- Bridging Alkyls -- Metalacycles --?1 and?2-Acyl and Vinyls -- 3.2 Other?-Bonded Ligands -- Group 14 Elements -- Groups 15-17 -- Oxophilicity and Functional Group Tolerance -- 3.3 Metal Hydrides -- Characterization -- Synthesis -- Reactions -- Hydricity -- Bridging Hydrides -- 3.4 Sigma Complexes -- Dihydrogen Complexes20 -- Characterization -- Reactions -- Agostic Species -- 3.5 Bond Strengths -- Supramolecular Interactions -- References -- Problems -- 4: Carbonyls, Phosphines, and Substitution -- 4.1 Metal Carbonyls -- Preparation of Carbonyls -- Reactions of Carbonyls -- Bridging Carbonyls -- Isonitriles -- Thiocarbonyls -- Nitrosyls -- Cyanide -- Other CO Analogs -- 4.2 Phosphines -- Structure and Bonding -- Tolman Electronic Parameter and Cone Angle -- Bite Angle -- 4.3 N-Heterocyclic Carbenes (NHCs) -- 4.4 Dissociative Substitution -- Kinetics -- Stereochemistry and Trans Effect -- Electronic and Steric Factors -- 4.5 Associative Substitution -- Kinetics -- Trans Effect -- Solvent Participation -- Ligand Rearrangements -- 4.6 Redox Effects and Interchange Substitution -- 17e and 19e Species -- The Interchange Mechanism -- 4.7 Photochemical Substitution -- Carbonyls -- Other Photochemical Processes -- 4.8 Counterions and Solvents in Substitution -- "Noncoordinating" Anions -- References -- Problems -- 5: Pi-Complexes -- 5.1 Alkene and Alkyne Complexes -- Synthesis -- Reactions -- Alkyne Complexes -- 5.2 Allyls -- Synthesis -- Reactions -- Related Ligands -- 5.3 Diene Complexes -- Cyclobutadiene Complexes -- Trimethylenemethane -- 5.4 Cyclopentadienyl Complexes -- Bent Metallocenes -- Synthesis -- Cp Analogs -- 5.5 Arenes and Other Alicyclic Ligands -- Synthesis -- Other Arene Ligands. | |
| 505 | 0 | |a Cover -- Title page -- Copyright page -- Contents -- Preface -- List of Abbreviations -- 1: Introduction -- 1.1 Why Study Organometallic Chemistry -- 1.2 Coordination Chemistry -- 1.3 Werner Complexes -- Stereochemistry -- Chelate Effect -- Werner's Coordination Theory -- 1.4 The Trans Effect -- 1.5 Soft versus Hard Ligands -- 1.6 The Crystal Field -- High Spin versus Low Spin -- Inert versus Labile Coordination -- Jahn-Teller Distortion -- Low- versus High-Field Ligands -- Magnetism and Nuclearity -- Other Geometries -- Isoconfigurational Ions -- 1.7 The Ligand Field -- 1.8 The sdn Model and Hypervalency -- 1.9 Back Bonding -- Frontier Orbitals -- ?-Donor Ligands -- 1.10 Electroneutrality -- Oxidation State Trends -- Periodic Trends -- 1.11 Types of Ligand -- Ambidentate Ligands -- Actor and Spectator Ligands -- Multifunctional Ligands29 -- Organometallic versus Coordination Compounds -- References -- Problems -- 2: Making Sense of Organometallic Complexes -- 2.1 The 18-Electron Rule -- Covalent Electron Counting Model -- Ionic Electron Counting Model -- Electron Counts for Common Ligands and Hapticity -- Bridging Ligands -- Zero-Electron Ligands -- 2.2 Limitations of The 18-Electron Rule -- Steric Stabilization of Reactive Species -- 2.3 Electron Counting in Reactions -- 2.4 Oxidation State -- Oxidation State versus Real Charge -- Ambiguous Oxidation States and Noninnocent Ligands -- Maximum and Minimum Oxidation States -- Net Ionic Charge -- 2.5 Coordination Number and Geometry -- 2.6 Effects of Complexation -- Ligand Polarization -- Free ≠ Bound -- Symbiotic and Antisymbiotic Effects -- 2.7 Differences between Metals -- Real Charge -- References -- Problems -- 3: Alkyls and Hydrides -- 3.1 Alkyls and Aryls -- Metal Alkyls as Stabilized Carbanions -- ? Elimination -- Stable Alkyls -- Agostic Alkyls -- ? Elimination of Other Groups. | |
| 590 | |a ProQuest Ebook Central |b Ebook Central Academic Complete | ||
| 650 | 0 | |a Organometallic chemistry. | |
| 650 | 0 | |a Organotransition metal compounds. | |
| 650 | 6 | |a Chimie organométallique. | |
| 650 | 6 | |a Métaux de transition |x Composés organiques. | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Organometallic chemistry |2 fast | |
| 650 | 7 | |a Organotransition metal compounds |2 fast | |
| 650 | 7 | |a Compostos organometàl·lics de transició. |2 thub | |
| 655 | 7 | |a Llibres electrònics. |2 thub | |
| 758 | |i has work: |a The organometallic chemistry of the transition metals (Text) |1 https://id.oclc.org/worldcat/entity/E39PCGCdPRq4bGJJYdfWcJFD7b |4 https://id.oclc.org/worldcat/ontology/hasWork | ||
| 776 | 0 | 8 | |i Print version: |a Crabtree, Robert H., 1948- |t Organometallic chemistry of the transition metals. |b Sixth edition. |d Hoboken, New Jersey : Wiley, [2014] |z 9781118138076 |w (DLC) 2013046043 |
| 856 | 4 | 0 | |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=1662194 |z Texto completo |
| 880 | 8 | |6 505-00/(S |a Reductive Elimination -- Kinetic Stability from Bulky Substituents -- Preparation of Metal Alkyls -- Cyclometalation -- Oxidative Addition -- Insertion -- Bridging Alkyls -- Metalacycles -- η1 and η2-Acyl and Vinyls -- 3.2 Other σ-Bonded Ligands -- Group 14 Elements -- Groups 15-17 -- Oxophilicity and Functional Group Tolerance -- 3.3 Metal Hydrides -- Characterization -- Synthesis -- Reactions -- Hydricity -- Bridging Hydrides -- 3.4 Sigma Complexes -- Dihydrogen Complexes20 -- Characterization -- Reactions -- Agostic Species -- 3.5 Bond Strengths -- Supramolecular Interactions -- References -- Problems -- 4: Carbonyls, Phosphines, and Substitution -- 4.1 Metal Carbonyls -- Preparation of Carbonyls -- Reactions of Carbonyls -- Bridging Carbonyls -- Isonitriles -- Thiocarbonyls -- Nitrosyls -- Cyanide -- Other CO Analogs -- 4.2 Phosphines -- Structure and Bonding -- Tolman Electronic Parameter and Cone Angle -- Bite Angle -- 4.3 N-Heterocyclic Carbenes (NHCs) -- 4.4 Dissociative Substitution -- Kinetics -- Stereochemistry and Trans Effect -- Electronic and Steric Factors -- 4.5 Associative Substitution -- Kinetics -- Trans Effect -- Solvent Participation -- Ligand Rearrangements -- 4.6 Redox Effects and Interchange Substitution -- 17e and 19e Species -- The Interchange Mechanism -- 4.7 Photochemical Substitution -- Carbonyls -- Other Photochemical Processes -- 4.8 Counterions and Solvents in Substitution -- "Noncoordinating" Anions -- References -- Problems -- 5: Pi-Complexes -- 5.1 Alkene and Alkyne Complexes -- Synthesis -- Reactions -- Alkyne Complexes -- 5.2 Allyls -- Synthesis -- Reactions -- Related Ligands -- 5.3 Diene Complexes -- Cyclobutadiene Complexes -- Trimethylenemethane -- 5.4 Cyclopentadienyl Complexes -- Bent Metallocenes -- Synthesis -- Cp Analogs -- 5.5 Arenes and Other Alicyclic Ligands -- Synthesis -- Other Arene Ligands. | |
| 880 | 8 | |6 505-00/(S |a η7 Ligands -- η8 Ligands -- 5.6 Isolobal Replacement and Metalacycles -- 5.7 Stability of Polyene and Polyenyl Complexes -- References -- Problems -- 6: Oxidative Addition and Reductive Elimination -- 6.1 Introduction -- 6.2 Concerted Additions -- 6.3 SN2 Pathways -- 6.4 Radical Mechanisms -- 6.5 Ionic Mechanisms -- 6.6 Reductive Elimination -- Octahedral Complexes -- Other Complexes -- Binuclear Reductive Elimination -- Reductive Elimination of C-F, -O, and -N -- 6.7 σ-Bond Metathesis -- 6.8 Oxidative Coupling and Reductive Fragmentation -- References -- Problems -- 7: Insertion and Elimination -- 7.1 Introduction -- 7.2 CO Insertion -- Enhancing Insertion Rates -- Apparent Insertions -- Double Insertion -- 7.3 Alkene Insertion -- Regiochemistry of Insertion -- Syn versus Apparent Anti Insertion -- Insertion into M-H versus M-R -- Radical Pathways -- Alternating CO/Alkene Insertion -- 7.4 Outer Sphere Insertions -- 7.5 α, β, γ, And δ Elimination -- β Elimination -- α Elimination -- Other Eliminations -- References -- Problems -- 8: Addition and Abstraction -- 8.1 Introduction -- 8.2 Nucleophilic Addition to CO -- 8.3 Nucleophilic Addition to Polyenes and Polyenyls -- Davies-Green-Mingos Rules -- Wacker Process -- Alkyne Hydration -- 8.4 Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls -- Hydrides -- Alkyls and Acyls -- 8.5 Electrophilic Addition and Abstraction -- Addition to the Metal -- Addition to a Metal-Ligand Bond -- Addition to Ligand -- Abstraction of Alkyl Groups -- 8.6 Single-Electron Transfer and Radical Reactions -- References -- Problems -- 9: Homogeneous Catalysis -- 9.1 Catalytic Cycles -- Homogeneity -- Thermodynamics -- Kinetics -- Mechanism, Intermediates, and Kinetic Competence -- Cooperative Catalysis -- Deactivation -- Choice of Metal and Ligands -- 9.2 Alkene Isomerization -- Alkyl Mechanism -- Allyl Mechanism. | |
| 880 | 0 | |6 505-00/(S |a Cover -- Title page -- Copyright page -- Contents -- Preface -- List of Abbreviations -- 1: Introduction -- 1.1 Why Study Organometallic Chemistry-- 1.2 Coordination Chemistry -- 1.3 Werner Complexes -- Stereochemistry -- Chelate Effect -- Werner's Coordination Theory -- 1.4 The Trans Effect -- 1.5 Soft versus Hard Ligands -- 1.6 The Crystal Field -- High Spin versus Low Spin -- Inert versus Labile Coordination -- Jahn-Teller Distortion -- Low- versus High-Field Ligands -- Magnetism and Nuclearity -- Other Geometries -- Isoconfigurational Ions -- 1.7 The Ligand Field -- 1.8 The sdn Model and Hypervalency -- 1.9 Back Bonding -- Frontier Orbitals -- π-Donor Ligands -- 1.10 Electroneutrality -- Oxidation State Trends -- Periodic Trends -- 1.11 Types of Ligand -- Ambidentate Ligands -- Actor and Spectator Ligands -- Multifunctional Ligands29 -- Organometallic versus Coordination Compounds -- References -- Problems -- 2: Making Sense of Organometallic Complexes -- 2.1 The 18-Electron Rule -- Covalent Electron Counting Model -- Ionic Electron Counting Model -- Electron Counts for Common Ligands and Hapticity -- Bridging Ligands -- Zero-Electron Ligands -- 2.2 Limitations of The 18-Electron Rule -- Steric Stabilization of Reactive Species -- 2.3 Electron Counting in Reactions -- 2.4 Oxidation State -- Oxidation State versus Real Charge -- Ambiguous Oxidation States and Noninnocent Ligands -- Maximum and Minimum Oxidation States -- Net Ionic Charge -- 2.5 Coordination Number and Geometry -- 2.6 Effects of Complexation -- Ligand Polarization -- Free ≠ Bound -- Symbiotic and Antisymbiotic Effects -- 2.7 Differences between Metals -- Real Charge -- References -- Problems -- 3: Alkyls and Hydrides -- 3.1 Alkyls and Aryls -- Metal Alkyls as Stabilized Carbanions -- β Elimination -- Stable Alkyls -- Agostic Alkyls -- β Elimination of Other Groups. | |
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