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Aggregation-Induced Emission : Fundamentals.
Aggregation-Induced Emission (AIE) is a novel photophysical phenomenon which offers a new platform FUNDAMENTALS for researchers to look into the light-emitting processes from luminogen aggregates, from which useful information on structure-property relationships may be collected and mechanistic insi...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2013.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Aggregation-Induced Emission: Fundamentals; Contents; List of Contributors; Preface; 1 Synthesis of Siloles (and Germoles) that Exhibit the AIE Effect; 1.1 Introduction; 1.2 Background; 1.3 Synthesis of Siloles; 1.3.1 Reductive dimerization of tolan; 1.3.2 Intramolecular cyclization of dialkynylsilanes; 1.3.3 Intramolecular cyclization of dialkynylsilanes utilizing borane reagents; 1.3.4 Synthesis of siloles using transition metal reagents; 1.4 Modification of Preformed Siloles; 1.4.1 Reactions at silicon centers; 1.4.2 Reactions of a ring carbon center; 1.5 Related Germole Methodology.
- 1.5.1 Germoles produced by metathesis and exchange reactions1.5.2 Germoles from other methods; 1.5.3 Photoluminescence and AIE of germoles; 1.6 Metallaindenes and Metallafluorenes of Si and Ge; 1.6.1 Methods for the formation of silaindenes and germaindenes; 1.6.2 Methods for the formation of metallafluorenes; 1.7 Oligomers and Polymers of Metalloles and Benzene-Annulated Metalloles; 1.7.1 Oligomers that contain silole units connected at the 1,1- and 2,5-positions; 1.7.2 Polysiloles and silole polymers connected through 2,5-positions.
- 1.7.3 Polymers with silole pendants and hyperbranched polymers1.7.4 Polybenzosiloles and ladder polymers; 1.7.5 Polymers that contain silafluorenes; 1.7.6 Germoles in oligomers and polymers; 1.8 Summary and Future Directions; References; 2 Aggregation-Induced Emission in Group 14 Metalloles (Siloles, Germoles, and Stannoles): Spectroscopic Considerations, Substituent Effects, and Applications; 2.1 Introduction; 2.1.1 The group 14 metalloles; 2.2 Characteristics of AIE in the Group 14 Metalloles; 2.2.1 Aryl-substituted siloles; 2.2.2 Aryl-substituted germoles and stannoles.
- 2.3 Origins of AIE in Group 14 Metalloles: Restricted Intramolecular Rotation2.3.1 Effect of solvent viscosity; 2.3.2 Effect of temperature; 2.3.3 Room-temperature glasses; 2.3.4 Effect of pressure; 2.3.5 Excited-state lifetimes; 2.3.6 Molecular geometry; 2.3.7 Aggregate nanoparticle morphology; 2.3.8 Internal structural control of intramolecular rotations; 2.4 Polymer Films and Polymerized Siloles; 2.5 Applications of AIE-Active Metalloles; 2.5.1 Electrooptical devices; 2.5.2 Chemical sensors; References.
- 3 Aggregation-Induced Emission of 9,10-Distyrylanthracene Derivatives and Their Applications3.1 Introduction; 3.2 AIE Molecules Based on 9,10-Distyrylanthracene; 3.2.1 Small molecules; 3.2.2 Macromolecules; 3.3 AIE Mechanism of 9,10-Distyrylanthracene Molecule Systems; 3.4 Application of AIE Luminogens Based on 9,10-Distyrylanthracene; 3.4.1 Solid-state emitters; 3.4.2 Piezochromism; 3.4.3 Fluorescent sensors and probes; 3.4.4 Bioimaging; 3.5 Conclusion; Acknowledgments; References; 4 Diaminobenzene-Cored Fluorophores Exhibiting Highly Efficient Solid-State Luminescence; 4.1 Introduction.