Keynotes in Organic Chemistry.

Detalles Bibliográficos
Autor principal: Parsons, Andrew F.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Wiley, 2013.
Temas:
Electronic books.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • 2 Functional groups, nomenclature and drawing organic compounds
  • 2.1 Functional groups
  • 2.2 Alkyl and aryl groups
  • 2.3 Alkyl substitution
  • 2.4 Naming carbon chains
  • 2.4.1 Special cases
  • 2.5 Drawing organic structures
  • Worked example
  • Problems
  • 3 Stereochemistry
  • 3.1 Isomerism
  • 3.2 Conformational isomers
  • 3.2.1 Conformations of ethane (CH3CH3)
  • 3.2.2 Conformations of butane (CH3CH2CH2CH3)
  • 3.2.3 Conformations of cycloalkanes
  • 3.2.4 Cyclohexane
  • 3.3 Configurational isomers
  • 3.3.1 Alkenes
  • 3.3.2 Isomers with chiral centres
  • Worked example
  • Problems
  • 4 Reactivity and mechanism
  • 4.1 Reactive intermediates: ions versus radicals
  • 4.2 Nucleophiles and electrophiles
  • 4.2.1 Relative strength
  • 4.3 Carbocations, carbanions and carbon radicals
  • 4.3.1 Order of stability
  • 4.4 Steric effects
  • 4.5 Oxidation levels
  • 4.6 General types of reaction
  • 4.6.1 Polar reactions (involving ionic intermediates)
  • 4.6.2 Radical reactions
  • 4.6.3 Pericyclic reactions
  • 4.7 Ions versus radicals
  • 4.8 Reaction selectivity
  • 4.9 Reaction thermodynamics and kinetics
  • 4.9.1 Thermodynamics
  • 4.9.2 Kinetics
  • 4.9.3 Kinetic versus thermodynamic control
  • 4.10 Orbital overlap and energy
  • 4.11 Guidelines for drawing reaction mechanisms
  • Worked example
  • Problems
  • 5 Halogenoalkanes
  • 5.1 Structure
  • 5.2 Preparation
  • 5.2.1 Halogenation of alkanes
  • 5.2.2 Halogenation of alcohols
  • 5.2.3 Halogenation of alkenes
  • 5.3 Reactions
  • 5.3.1 Nucleophilic substitution
  • 5.3.2 Elimination
  • 5.3.3 Substitution versus elimination
  • Worked example
  • Problems
  • 6 Alkenes and alkynes
  • 6.1 Structure
  • 6.2 Alkenes
  • 6.2.1 Preparation
  • 6.2.2 Reactions
  • 6.3 Alkynes
  • 6.3.1 Preparation
  • 6.3.2 Reactions
  • Worked example
  • Problems
  • 7 Benzenes
  • 7.1 Structure
  • 7.2 Reactions
  • 7.2.1 Halogenation
  • 7.2.2 Nitration
  • 7.2.3 Sulfonation
  • 7.2.4 Alkylation: The Friedel-Crafts alkylation
  • 7.2.5 Acylation: The Friedel-Crafts acylation
  • 7.3 Reactivity of substituted benzenes
  • 7.3.1 Reactivity of benzene rings: Activating and deactivating substituents
  • 7.3.2 Orientation of reactions
  • 7.4 Nucleophilic aromatic substitution (the SNAr mechanism)
  • 7.5 The formation of benzyne
  • 7.6 Transformation of side chains
  • 7.7 Reduction of the benzene ring

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