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Keynotes in Organic Chemistry.

Detalles Bibliográficos
Autor principal: Parsons, Andrew F.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Wiley, 2013.
Temas:
Acceso en línea:Texto completo

MARC

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505 8 |a 2 Functional groups, nomenclature and drawing organic compounds -- 2.1 Functional groups -- 2.2 Alkyl and aryl groups -- 2.3 Alkyl substitution -- 2.4 Naming carbon chains -- 2.4.1 Special cases -- 2.5 Drawing organic structures -- Worked example -- Problems -- 3 Stereochemistry -- 3.1 Isomerism -- 3.2 Conformational isomers -- 3.2.1 Conformations of ethane (CH3CH3) -- 3.2.2 Conformations of butane (CH3CH2CH2CH3) -- 3.2.3 Conformations of cycloalkanes -- 3.2.4 Cyclohexane -- 3.3 Configurational isomers -- 3.3.1 Alkenes -- 3.3.2 Isomers with chiral centres -- Worked example -- Problems 
505 8 |a 4 Reactivity and mechanism -- 4.1 Reactive intermediates: ions versus radicals -- 4.2 Nucleophiles and electrophiles -- 4.2.1 Relative strength -- 4.3 Carbocations, carbanions and carbon radicals -- 4.3.1 Order of stability -- 4.4 Steric effects -- 4.5 Oxidation levels -- 4.6 General types of reaction -- 4.6.1 Polar reactions (involving ionic intermediates) -- 4.6.2 Radical reactions -- 4.6.3 Pericyclic reactions -- 4.7 Ions versus radicals -- 4.8 Reaction selectivity -- 4.9 Reaction thermodynamics and kinetics -- 4.9.1 Thermodynamics -- 4.9.2 Kinetics 
505 8 |a 4.9.3 Kinetic versus thermodynamic control -- 4.10 Orbital overlap and energy -- 4.11 Guidelines for drawing reaction mechanisms -- Worked example -- Problems -- 5 Halogenoalkanes -- 5.1 Structure -- 5.2 Preparation -- 5.2.1 Halogenation of alkanes -- 5.2.2 Halogenation of alcohols -- 5.2.3 Halogenation of alkenes -- 5.3 Reactions -- 5.3.1 Nucleophilic substitution -- 5.3.2 Elimination -- 5.3.3 Substitution versus elimination -- Worked example -- Problems -- 6 Alkenes and alkynes -- 6.1 Structure -- 6.2 Alkenes -- 6.2.1 Preparation -- 6.2.2 Reactions -- 6.3 Alkynes -- 6.3.1 Preparation 
505 8 |a 6.3.2 Reactions -- Worked example -- Problems -- 7 Benzenes -- 7.1 Structure -- 7.2 Reactions -- 7.2.1 Halogenation -- 7.2.2 Nitration -- 7.2.3 Sulfonation -- 7.2.4 Alkylation: The Friedel-Crafts alkylation -- 7.2.5 Acylation: The Friedel-Crafts acylation -- 7.3 Reactivity of substituted benzenes -- 7.3.1 Reactivity of benzene rings: Activating and deactivating substituents -- 7.3.2 Orientation of reactions -- 7.4 Nucleophilic aromatic substitution (the SNAr mechanism) -- 7.5 The formation of benzyne -- 7.6 Transformation of side chains -- 7.7 Reduction of the benzene ring 
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