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Heterogeneous catalysts for clean technology : spectroscopy, design, and monitoring /
This ready reference and handbook is the first to combine the hot topics of heterogeneous catalysis and clean technology in a single volume. As such, it focuses on the development of heterogeneous catalysts for use in clean chemical synthesis, dealing with how modern spectroscopic techniques can aid...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Weinheim, Germany :
Wiley-VCH,
[2014]
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Heterogeneous Catalysts for Clean Technology; Title Page; Copyright; Contents; Preface; List of Contributors; Chapter 1 Introduction to Clean Technology and Catalysis; 1.1 Green Chemistry and Clean Technology; 1.1.1 Ideals of Green Chemistry; 1.2 Green Chemistry Metrics; 1.3 Alternative Solvents; 1.4 Heterogeneous or Homogeneous; 1.5 Alternative Energy Reactors for Green Chemistry; 1.5.1 Microchannel Reactors; 1.5.2 Microwave Reactors; 1.6 Concluding Remarks; References; Chapter 2 Mechanistic Studies of Alcohol Selective Oxidation; 2.1 Introduction; 2.1.1 Applications of Selective Oxidation.
- 2.1.2 Oxidant Considerations2.2 Metal-Catalyzed Alcohol Selox; 2.2.1 Monometallic Catalysts; 2.2.2 Bimetallic Selox Catalysts; 2.2.3 Support Effects; 2.3 Oxide, Sulfide, and Vanadate Catalysts; 2.4 Solvent Selection; 2.4.1 Supercritical Fluids; 2.4.2 Ionic Liquids and Water; 2.5 In Situ and Operando X-Ray Studies of Selox Catalysts; 2.5.1 X-Ray Absorption Spectroscopy; 2.5.2 X-Ray Photoelectron Spectroscopy; 2.6 Conclusions; References; Chapter 3 Reaction Monitoring in Multiphase Systems: Application of Coupled In Situ Spectroscopic Techniques in Organic Synthesis; 3.1 Introduction.
- 3.2 Method Coupling3.3 Spectroscopic Reactors and Practical Aspects; 3.4 Selected Examples of Use; 3.4.1 Heterogeneously Catalyzed Hydrogenation of Imines; 3.4.2 Three-Phase Hydrogenation of Nitrobenzene over Nanosized Au on TiO2; 3.4.3 Elucidating the Mechanism of Cu(II)-Catalyzed Arylation of Imidazole and Phenylboronic Acid by a Multitechnique Approach; 3.5 Conclusion and Outlook; References; Chapter 4 In Situ Studies on Photocatalytic Materials, Surface Intermediates, and Reaction Mechanisms; 4.1 Introduction; 4.2 In Situ Investigations; 4.2.1 FTIR; 4.2.1.1 NOx Depollution.
- 4.2.1.2 Hydrocarbon Oxidation4.2.1.3 Oxidation of Oxygen-Containing Compounds; 4.2.2 EPR; 4.2.2.1 Semiconductor Charge Separation and Transfer; 4.2.2.2 Reactive Oxygen Species; 4.2.2.3 Local Structure of Active Sites; 4.2.3 XPS; 4.2.4 XAFS and UV Vis; 4.2.5 NMR; 4.2.6 Other Methods; 4.3 Concluding Remarks; References; Chapter 5 Enantioselective Heterogeneous Catalysis; 5.1 Introduction; 5.2 Strategies for the Creation of Enantioselective Heterogeneous Catalysts; 5.2.1 Immobilization of Homogeneous or Enzyme Catalysts; 5.2.1.1 Covalent Tethering.
- 5.2.1.1.1 Covalent Immobilization on Inorganic Supports5.2.1.1.2 Covalent Immobilization on Polymeric Resins; 5.2.1.1.3 Covalent Immobilization by Copolymerization; 5.2.1.2 Immobilization by Encapsulation; 5.2.1.2.1 Construction of Catalyst within the Pores of a Support; 5.2.1.2.2 Construction of Support around the Catalyst; 5.2.1.3 Immobilization by Electrostatic Interactions; 5.2.1.4 Industrial Application of Immobilized Catalysts; 5.2.2 Use of Chiral Solids; 5.2.2.1 Metal or Metal Oxide on a Chiral Support; 5.2.2.2 Chiral Zeolites; 5.2.2.3 Chiral Metal-Organic Catalysts.