Cargando…
Advances in Multi-Photon Processes and Spectroscopy, Vol 17.
Among others, chemistry, physics, biology, and material sciences have seen a rapid growth in both experimental and theoretical studies of multi-photon processes and spectroscopy of atoms, ions and molecules. This book is an important addition to an advanced series that contains review papers readabl...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Singapore :
World Scientific Publishing Company,
2006.
|
| Colección: | Advances in Multi-Photon Processes and Spectroscopy.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Preface; 1 Probing Orbital Symmetries and Ionization Dynamics of Simple Molecules With Femtosecond Laser Pulses C.D. Lin and X.M. Tong; 1.1. Introduction; 1.2. Probing Molecular Orbital Symmetry with Sub-10 fs Laser Pulses; 1.2.1. Molecular tunneling ionization theory; 1.2.2. Alignment dependence of tunneling ionization rates and the symmetry of molecular orbitals; 1.3. Attosecond Molecular Clocks: Time-Resolved Double Ionization Dynamics of H2 and D2 Molecules; 1.3.1. Dynamics of double ionization of H2 by femtosecond lasers.
- 1.3.2. Theory of double ionization of H2 by femtosecond lasers: rescattering region1.3.3. Control the time sequence of double ionization by tuning laser parameters; 1.4. Probing Nonclassical VibrationalWave Packets on Two Potential Surfaces; 1.5. Summary and Discussion; Acknowledgments; References; 2 Generalization and Application to Molecular Systems of Keldysh's Atomic Photoionization Theory K. Mishima, K. Nagaya, M. Hayashi, S.H. Lin and E.W. Schlag; 2.1. General Introduction; 2.2. Original Atomic Keldysh Theory; 2.3. Generalization of the Original Atomic Keldysh Theory.
- 2.3.1. Introduction2.3.2. Theory-atomic case; 2.3.3. Theory-diatomic molecule case; 2.3.4. Results and discussion; 2.4. Coulomb Correction of the Atomic Keldysh Theory; 2.4.1. Introduction; 2.4.2. Theory; 2.4.3. Results and discussion; 2.5. Application to Large Polyatomic Molecules; 2.5.1. Introduction; 2.5.2. Theory; 2.5.2.1. Molecular Coulomb-corrected Volkov function of electron; 2.5.2.2. Photoionization rate of spatially aligned molecules in the linearly polarized electric field; 2.5.3. Computational method
- ab initio calculation; 2.5.4. Numerical results and discussion.
- 2.5.4.1. Ab initio calculation2.5.4.2. Photoionization rates of all-trans polyacetylene radicals (CnHn+2, n = 3, 5, 7, 9, 13, 27); 2.6. Extension of the Atomic Keldysh Theory to Molecular Photoionization Processes; 2.6.1. Introduction; 2.6.2. Theory; 2.6.3. Computational methods; 2.6.3.1. Ab initio calculation; 2.6.3.2. Calculation of Franck-Condon factors; 2.6.4. Numerical results and discussion; 2.6.5. Introduction; 2.6.6. Theory; 2.6.7. Computational methods; 2.6.7.1. Ab initio calculation; 2.6.7.2. Calculation of potential energy curves and Franck-Condon factors.
- 2.6.8. Numerical results and discussion2.7. Towards the Realization of the Quantum Chemistry Approach to Tunneling Photoionization Processes in Strong Laser Fields; 2.8. Ab Initio/RRKM Approach to the Elucidation of the Mechanism of Photoionization and Photodissociation of Molecules in Intense Laser Fields; 2.9. Conclusion; Acknowledgments; Appendix; Appendix A. Saddle-Point Method for Integrals with a Singularity; Appendix B. Compact Forms of L(p) Defined by Eq. (64); Appendix C. Definition of N(r, w, I0, I0, B, C) in Eqs. (66) and (79).