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Inorganic chemistry for dummies /

The easy way to get a grip on inorganic chemistry Inorganic chemistry can be an intimidating subject, but it doesn't have to be! Whether you're currently enrolled in an inorganic chemistry class or you have a background in chemistry and want to expand your knowledge, Inorganic Chemistry Fo...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Matson, Michael L.
Otros Autores: Orbaek, Alvin W.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken, NJ : John Wiley & Sons, Inc., 2013.
Colección:--For dummies.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Introduction:
  • About this book
  • Conventions used in this book
  • What you don't need to read
  • Foolish assumptions
  • How this book is organized:
  • Part 1: Reviewing some general chemistry
  • Part 2: Rules of attraction: chemical bonding
  • Part 3: It's elemental: dining at the periodic table
  • Part 4: Special topics
  • Part 5: Part of tens
  • Icons used in this book
  • Where to go from here
  • Part 1: Reviewing Some General Chemistry:
  • Introducing inorganic chemistry:
  • Building the foundation:
  • Losing your electrons
  • Splitting atoms: nuclear chemistry
  • Changing pH
  • Getting a grip on chemical bonding
  • Traveling across the periodic table:
  • Hyping up hydrogen
  • Moving through the main groups
  • Transitioning from one side to the table to another
  • Uncovering lanthanides and actinides
  • Diving deeper: special topics:
  • Bonding with carbon: organometallics
  • Speeding things up: catalysts
  • Inside and out: bio-inorganic and environmental chemistry
  • Solid-state chemistry
  • Nanotechnology
  • Listing 40 more
  • Following the leader: atomic structure and periodic trends:
  • Up an' atom: reviewing atomic terminology:
  • Sizing up subatomic particles
  • Knowing the nucleus
  • Going orbital
  • Distinguishing atomic number and mass number
  • Identifying isotopes
  • Grouping elements in the periodic table:
  • Keeping up with periodic trends
  • Measuring atomic size
  • Rating the atomic radius
  • Eyeing ionization energy
  • Examining electron affinities
  • Noting electronegativity
  • United States of oxidation:
  • Entering the oxidation-reduction zone:
  • Following oxidation state rules
  • Scouting reduction potentials
  • Walking through a redox reaction
  • Isolating elements:
  • Mechanically separating elements
  • Using thermal decomposition
  • Displacing one element with another
  • Heating things up: high-temperature chemical reactions
  • Relying on electrolytic reduction
  • Gone fission: nuclear chemistry:
  • Noting nuclear properties:
  • Using the force
  • Empirical strikes back
  • Documenting atomic decay: radioactivity:
  • Alpha radiation
  • Beta radiation
  • Gamma radiation
  • Half-life principle
  • Blind (radiocarbon) dating
  • Radioisotopes
  • Catalyzing a nuclear reaction:
  • Fission
  • Fusion
  • ABCs: acid-base chemistry:
  • Starting with the basics: acids and bases:
  • Developing the pH scale
  • Calculating pH
  • Calculating acid dissociation
  • Touring key theories: a historical perspective:
  • Early years
  • Bronsted-Lowry theory
  • Accepting or donating: Lewis's theory
  • Comparing Lewis and Bronsted theories
  • Pearson's hard and soft acids and bases (HSAB):
  • Characterization of the hard bodies
  • Who you callin' soft?
  • Strapping on a cape: superacids
  • Rules Of Attraction: Chemical Bonding:
  • No Mr Bond, I expect you to pi bond: covalent bonding:
  • Connecting the dots: Lewis structures:
  • Counting electrons
  • Placing electrons
  • Price tags in black ties? Formal charges
  • Returning to the drawing board: resonance structures
  • Keeping your distance: VSPR
  • Ante up one electron: valence-bond theory
  • Summing it all up: molecular orbital theory:
  • Types of MOs
  • Evens and odds: gerade and ungerade symmetry
  • Identical twins: homonuclear diatomic molecules
  • Fraternal twins: heteronuclear diatomic molecules
  • Molecular symmetry and group theory:
  • Identifying molecules: symmetry elements and operations:
  • Identity
  • n-fold rotational axis
  • Inversion center
  • Mirror planes
  • Improper rotation axis
  • It's not polite to point! Molecular point groups
  • Being such a character table:
  • Dissecting a character table
  • Degrees of freedom
  • Glitch in the matrix: matrix math
  • Reducible reps
  • Infrared and Raman active modes
  • Ionic and metallic bonding:
  • Blame it on electrostatic attraction: forming ionic bonds:
  • Marrying a cation and an anion
  • Measuring bond strength: lattice energy
  • Coexisting with covalent bonds
  • Conducting electricity in solution
  • Admiring ionic crystals:
  • Studying shapes: lattice types
  • Size matters (when it's ionic)
  • I'm melting! Dissolving ionic compounds with water: solubility:
  • Just add water: hydrated ions
  • Counting soluble compounds
  • What is a metal, anyway?:
  • Tracing the history of metallurgy
  • Admiring the properties of solid metals
  • Delocalizing electrons: conductivity
  • Analyzing alloys
  • Swimming in the electron sea: metallic bonding theories:
  • Free-electron theory
  • Valence bond theory
  • Band theory.
  • Clinging to complex ions: coordination complexes:
  • Counting bonds
  • Seeking stability
  • Grouping geometries
  • Identifying isomers:
  • Connecting differently: structural isomers
  • Arranged differently: stereoisomers
  • Naming coordination complexes
  • Sorting out the salts
  • Creating metal complexes throughout the periodic table:
  • Alkali metals
  • Alkali earth metals
  • Transition metals
  • Lanthanides and actinides
  • Metalloids
  • Applying coordination complexes in the real world
  • Part 3: It's Elemental: Dining At The Periodic Table:
  • What the H? hydrogen!:
  • Visiting hydrogen at home: its place in the periodic table
  • Appreciating the merits of hydrogen:
  • Available in abundance
  • Molecular properties
  • Nuclear spin
  • Introducing hydrogen isotopes
  • Investing in hydrogen bonds:
  • Forming a hydrogen ion
  • Creating hydrides
  • Applying itself: hydrogen's uses in chemistry and industry
  • Earning your salt: the alkali and alkaline earth metals:
  • Salting the earth: group 1 elements:
  • Lithium the outlier
  • Seafaring sodium
  • Maintaining your brain with potassium
  • Rubidium, cesium, francium, oh my
  • Reacting less violently: the group 2 alkaline earth metals:
  • Being beryllium
  • Magnificent magnesium
  • Commonly calcium
  • Strontium, barium, radium
  • Diagramming the diagonal relationship
  • Main groups:
  • Placing main group elements on the periodic table
  • Lucky 13: the boron group:
  • Not-so-boring boron
  • Abundance of aluminum
  • Mendeleev's missing link: gallium
  • Increasing indium use
  • Toxic thallium
  • Diamond club: the carbon group:
  • Captivating carbon
  • Coming in second: silicon
  • Germane germanium
  • Malleable tin cans
  • Plumbing lead
  • Noting pnictides of the nitrogen group:
  • Leading the pnictides: nitrogen
  • Finding phosphorus everywhere
  • Melding the metalloids: arsenic and antimony
  • Keeping up with the chalcogens:
  • Oxygen all around
  • Sulfur
  • From the earth to the moon
  • Marco-polonium!
  • (re)active singles: the group 17 halogens:
  • Cleaning up with chlorine
  • Briny bromine
  • Iodine
  • Rarely astatine
  • Lights of New York: the group 18 noble gases
  • Bridging two sides of the periodic table: the transition metals:
  • Getting to know transition metals:
  • Sorting t-metals into series
  • Separating T-metals from the main group
  • Partially filling d-orbitals:
  • Calculating an effective nuclear charge
  • Forming more than one oxidation state
  • Splitting the difference: crystal field theory and transition metal complexes:
  • Dividing d-orbitals
  • Absorbing light waves: color
  • Building attraction: magnetism
  • Electronic structure and bonding:
  • Reacting with other elements
  • Creating coordination complexes
  • Adsorbing gas: t-metals in catalysis
  • Finding what lies beneath: the lanthanides and actinides:
  • Spending quality time with the rare earth elements: lanthanides:
  • Electronic structure
  • Reactivity
  • Lanthanide contraction
  • Separating the lanthanide elements
  • Using lanthanides
  • Feelin' radioactive: the actinides:
  • Finding or making actinides
  • Examining electronic structure
  • Comparing reactivity: actinide versus lanthanide
  • Looking more closely at uranium
  • Part 4: Special Topics:
  • Not quite organic, not quite inorganic: organometallics:
  • Building organometallic complexes
  • Adhering to electron rules:
  • Counting to eight: the octet rule
  • Calculating with the 18-electron rule
  • Settling for 16 electrons
  • Effectively using the EAN rule
  • Bonding with metals: ligands
  • Including carbon: carbonyls
  • Providing the best examples:
  • e-precise carbon
  • e-rich nitrogen
  • e-deficient boron
  • Behaving oddly: organometallics of groups 1,2, and 12
  • Sandwiched together: metallocenes
  • Clustering together: metal-metal bonding
  • Creating vacancies: insertion and elimination
  • Synthesizing organometallics
  • Showing similarities with main group chemistry.
  • Accelerating change: catalysts:
  • Speeding things up-the job of a catalyst
  • Considering types of catalysts:
  • Homogenous catalysts
  • Heterogeneous
  • Organocatalysts
  • Bioinorganic chemistry: finding metals in living systems:
  • Focusing on photosynthesis
  • Climbing aboard the oxygen transport
  • Feeding a nitrogen fixation:
  • Fixing nitrogen for use by organisms
  • Re-absorbing nitrogen
  • Being human:
  • Making things happen: enzymes
  • Curing disease: medicines
  • Causing problems: toxicity
  • Answering when nature calls: environmental chemistry:
  • Eyeing key indicators
  • Rocking the heavy metals
  • Killing me softly: pesticides
  • Looking for and removing contaminants
  • Living in a materials world: solid-state chemistry:
  • Studying solid structures:
  • Building crystals with unit cells
  • Labeling lines and corners: Miller indices
  • Three types of crystal structure:
  • Simple crystal structures
  • Binary crystal structures
  • Complex crystals structures
  • Calculating crystal formation: the Born-Haber cycle
  • Bonding and other characteristics:
  • Characterizing size
  • Dissolving in liquids: solubility
  • Encountering zero resistance: superconductivity
  • Information technology: semiconductors
  • Synthesizing solid structures
  • Detecting crystal defects
  • Nanotechnology:
  • Defining nanotechnology:
  • History of nanotechnology
  • Science of nanotechnology
  • Top-down versus bottom-up
  • Nanomaterial's:
  • Size and shape control
  • Self-assembly and grapy goo
  • Applications for nanotechnology:
  • Cancer therapy
  • Catalysis
  • Education
  • Part 5: Parts Of Tens:
  • Ten nobels:
  • Locating ligands: Alfred Werner
  • Making ammonia: Fritz Haber
  • Creating transuranium elements: McMillan and Seaborg
  • Adding electronegativity: Pauling
  • Preparing plastics: Ziegler and Natta
  • Sandwiching compounds: Fischer and Wilkinson
  • Illuminating Boron Bonds: Lipscomb
  • Characterizing crystal structures: Hauptman and Karle
  • Creating cryptands: Jean-Marie Lehn
  • Making buckyballs
  • Tools of the trade: ten instrumental techniques:
  • Absorbing and transmitting light waves: Uv-vis and IR
  • Catching diffracted light: XRD
  • Rearranging excited atoms: XRF
  • Measuring atoms in solution: ICP/AA
  • Detecting secondary electrons: SEM
  • Reading the criss-crossed lines: TEM
  • Characterizing surface chemistry: XPS
  • Evaporating materials: TGA
  • Cyclic voltammetry
  • Tracking electron spin: EPR
  • Ten experiments:
  • Turning blue: the clock reaction
  • Forming carbon dioxide
  • Presence of carbon dioxide
  • Mimicking solubility
  • Separating water into gas
  • Testing conductivity of electrolyte solutions
  • Lemon batteries
  • Purifying hydrogen
  • Colorful flames
  • Making gunpowder
  • Ten inorganic household products:
  • Salting your food
  • Bubbling with hydrogen peroxide
  • Baking with bicarbonate
  • Whitening with bleach
  • Using ammonia in many ways
  • Killing pests with borax
  • Soothing babies with talc
  • Cleaning with lye
  • Scratching stainless steel
  • Wrapping it up with aluminum foil
  • Glossary
  • Index.