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090408s2009 nyua ob 001 0 eng d |
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|a UAMI
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| 100 |
1 |
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|a Buchachenko, A. L.
|q (Anatoliĭ Leonidovich)
|1 https://id.oclc.org/worldcat/entity/E39PBJbWyCXRd8rtMcy3rPY9Dq
|
| 245 |
1 |
0 |
|a Magnetic isotope effect in chemistry and biochemistry /
|c Anatoly Buchachenko.
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| 260 |
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|a New York :
|b Nova Science Publishers,
|c ©2009.
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| 300 |
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|a 1 online resource (149 pages) :
|b illustrations
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| 336 |
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|a text
|b txt
|2 rdacontent
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| 337 |
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|a computer
|b c
|2 rdamedia
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| 338 |
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|a online resource
|b cr
|2 rdacarrier
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| 504 |
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|a Includes bibliographical references and index.
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0 |
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|a Magnetic Isotope Effect in Chemistry and Biochemistry; Contents; Preface; Introduction; Energy and Angular Momentum as the Reaction Controlling Factors; 1.1. Energy; 1.2. Angular Momentum; Spin Control of Chemical Reactions; 2.1. Spin States and Chemical Reactivity; 2.2. Magnetic Interactions and Magnetic Effects; Magnetic Isotope Effect (MIE); 3.1. How to Discriminate Classical and Magnetic Isotope Effects; 3.2. MIE: How It Functions; 3.3. MIE as a Test of Reaction Mechanism; 3.4. Nuclear Spin Polarization; 3.5. MIE and Isotope Technology; 3.6. MIE: The Road of Discoveries.
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| 505 |
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|a Kinetics of Isotope Fractionation4.1. Measurement of Isotope Composition; 4.2. Analysis of the Kinetic Schemes; 4.3. Absolute Measure of Isotope Separation; 4.4. Dynamic Characteristics of Spin Selective Nanoreactor; 4.5. Is There a Limit in MIE Induced Isotope Fractionation?; Physics of the MIE; 5.1. Spin-Selective Nanoreactor: How It Functions?; 5.2. Spin Dynamics; 5.3. Molecular Dynamics; 5.4. Chemical Dynamics; 5.5. Generalized Spin Dynamics; MIE for Deuterium-Hydrogen Dyad; 13C MIE: Controlling Factors; 7.1. Spin Prohibition: How It Is Rigorous.
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|a 7.2. Hyperfine Coupling and Chemical Reactivity7.3. MIE as a Function of the Magnetic Field; 7.4. Viscosity, Lifetime of Radicals and a Size of Microreactors; 7.5. Spin Multiplicity and Competition of Radical and Non-Radical Reaction Channels; 7.6. MIE as a Function of Molecular Energy; Oxygen MIE; 8.1. Fractionation of Isotopes in Chain Reactions of Molecular Oxygen; 8.2. Addition of Molecular Oxygen to Radicals; 8.3. Interaction of Peroxy Radicals (Chain Termination Reaction); 8.4. Temperature and Viscosity as Controlling Factors of Chemical Spin Selectivity.
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| 505 |
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|a 8.5. Nonchain Processes: Endoperoxides -- Synthesis and Decomposition8.6. Geochemical Anomalies of 17O; Silicon MIE; 9.1. Photolysis of Phenylsilylketone; 9.2. Photolysis of Benzylsilylketone; 9.3. Spin Multiplicity and The Sign of MIE; MIE for Sulfur, Germanium and Tin Nuclei; 10.1. Sulfur; 10.2. Germanium; 10.3. Tin; Uranium MIE; 11.1. Spin-Selective Reactions to Uranyl; 11.2. Uranium Nanoreactor; 11.3. Fractionation of Uranium Isotopes; Mercury MIE; 12.1. MIE in Photochemical Reactions; 12.2. Mercury MIE in Enzymatic Phosphorylation by Creatine Kinase; Magnesium Isotope Effects.
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| 505 |
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|a 13.1. Classical Isotope Effects13.2. Magnetic Isotope Effects in Enzymatic Phosphorylation; Microwave Effects; 14.1. Microwave MIE; Acknowledgements; References; Index.
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| 590 |
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|a ProQuest Ebook Central
|b Ebook Central Academic Complete
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| 650 |
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0 |
|a Free radical reactions.
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| 650 |
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0 |
|a Nuclear spin.
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| 650 |
|
0 |
|a Chemical kinetics.
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| 650 |
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0 |
|a Isotopes.
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| 650 |
|
6 |
|a Réactions radicalaires.
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| 650 |
|
6 |
|a Spin.
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| 650 |
|
6 |
|a Cinétique chimique.
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| 650 |
|
6 |
|a Isotopes.
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| 650 |
|
7 |
|a SCIENCE
|x Chemistry
|x Physical & Theoretical.
|2 bisacsh
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| 650 |
|
7 |
|a Chemical kinetics
|2 fast
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| 650 |
|
7 |
|a Free radical reactions
|2 fast
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| 650 |
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7 |
|a Isotopes
|2 fast
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| 650 |
|
7 |
|a Nuclear spin
|2 fast
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| 758 |
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|i has work:
|a Magnetic isotope effect in chemistry and biochemistry (Text)
|1 https://id.oclc.org/worldcat/entity/E39PCFHhj4Vh9k6KD467KxDC8K
|4 https://id.oclc.org/worldcat/ontology/hasWork
|
| 776 |
0 |
8 |
|i Print version:
|a Buchachenko, A.L. (Anatoliĭ Leonidovich).
|t Magnetic isotope effect in chemistry and biochemistry.
|d New York : Nova Science Publishers, ©2009
|w (DLC) 2009014711
|
| 856 |
4 |
0 |
|u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=3018546
|z Texto completo
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| 938 |
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