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|a Handbook of polymer crystallization /
|c edited by Ewa Piorkowska, Gregory C. Rutledge.
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|a First edition.
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|a Hoboken, New Jersey :
|b Wiley,
|c ©2013.
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300 |
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|a 1 online resource (xvi, 481 pages) :
|b illustrations
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|a Print version record.
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|a Edition statement from first page of chapter PDFs.
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|a Includes bibliographical references and index.
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|a "The only comprehensive reference on polymer crystallization, Handbook of Polymer Crystallization provides readers with a broad, in-depth guide on the subject, covering the numerous problems encountered during crystallization as well as solutions to resolve those problems to achieve the desired result."--Provided by publisher
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|a Cover; Title page; Copyright page; Contents; Preface; Contributors; 1: Experimental Techniques; 1.1 Introduction; 1.2 Optical Microscopy; 1.2.1 Reflection and Transmission Microscopy; 1.2.2 Contrast Modes; 1.2.3 Selected Applications; 1.3 Electron Microscopy; 1.3.1 Imaging Principle; 1.3.2 Sample Preparation; 1.3.3 Relevant Experimental Techniques; 1.3.4 Selected Applications; 1.4 Atomic Force Microscopy; 1.4.1 Imaging Principle; 1.4.2 Scanning Modes; 1.4.3 Comparison between AFM and EM; 1.4.4 Recent Development: Video AFM; 1.4.5 Selected Applications; 1.5 Nuclear Magnetic Resonance.
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|a 1.5.1 Chemical Shift1.5.2 Relevant Techniques; 1.5.3 Recent Development: Multidimensional NMR; 1.5.4 Selected Applications; 1.6 Scattering Techniques: X-Ray, Light, and Neutron; 1.6.1 Wide-Angle X-Ray Diffraction; 1.6.2 Small-Angle X-Ray Scattering; 1.6.3 Small-Angle Light Scattering; 1.6.4 Small-Angle Neutron Scattering; 1.7 Differential Scanning Calorimetry; 1.7.1 Modes of Operation; 1.7.2 Determination of Degree of Crystallinity; 1.8 Summary; Acknowledgments; References; 2: Crystal Structures of Polymers; 2.1 Constitution and Configuration of Polymer Chains.
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|a 2.2 Conformation of Polymer Chains in Crystals and Conformational Polymorphism2.3 Packing of Macromolecules in Polymer Crystals; 2.4 Symmetry Breaking; 2.5 Packing Effects on the Conformation of Polymer Chains in the Crystals: The Case of Aliphatic Polyamides; 2.6 Defects and Disorder in Polymer Crystals; 2.6.1 Substitutional Isomorphism of Different Chains; 2.6.2 Substitutional Isomorphism of Different Monomeric Units; 2.6.3 Conformational Isomorphism; 2.6.4 Disorder in the Stacking of Ordered Layers (Stacking Fault Disorder); 2.7 Crystal Habits; 2.7.1 Rounded Lateral Habits; Acknowledgments.
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546 |
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|a English.
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590 |
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|a ProQuest Ebook Central
|b Ebook Central Academic Complete
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650 |
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|a Crystalline polymers.
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650 |
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6 |
|a Polymères cristallins.
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650 |
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7 |
|a SCIENCE
|x Chemistry
|x Organic.
|2 bisacsh
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650 |
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7 |
|a Crystalline polymers
|2 fast
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700 |
1 |
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|a Piorkowska, Ewa,
|e editor.
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1 |
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|a Rutledge, Gregory Charles,
|e editor.
|
758 |
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|i has work:
|a Handbook of Polymer Crystallization [electronic resource] (Text)
|1 https://id.oclc.org/worldcat/entity/E39PD3Py3wxxj3Gx8PXWJbCHfq
|4 https://id.oclc.org/worldcat/ontology/hasWork
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8 |
|i Print version:
|t Handbook of polymer crystallization.
|d Hoboken, New Jersey : John Wiley & Sons, Inc., [2013]
|z 9780470380239
|w (DLC) 2012037881
|w (OCoLC)813537794
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|u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=1209630
|z Texto completo
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880 |
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|6 505-00/(S
|a References -- 3: Structure of Polycrystalline Aggregates -- 3.1 Introduction -- 3.2 Crystals Grown from Solution -- 3.2.1 Facetted Monolayer Crystals from Dilute Solution -- 3.2.2 Dendritic Crystals from Dilute Solution -- 3.2.3 Growth Spirals in Dilute Solution -- 3.2.4 Concentrated Solutions -- 3.3 Crystals and Aggregates Grown from Molten Films -- 3.3.1 Structures in Thin Films -- 3.3.2 Structures in Ultrathin Films -- 3.3.3 Edge-On Lamellae in Molten Films -- 3.4 Spherulitic Aggregates -- 3.4.1 Optical Properties of Spherulites -- 3.4.2 Occurrence of Spherulites -- 3.4.3 Development of Spherulites -- 3.4.4 Banded Spherulites and Lamellar Twist -- Acknowledgments -- References -- 4: Polymer Nucleation -- 4.1 Introduction -- 4.2 Classical Nucleation Theory -- 4.2.1 Nucleation Rate (I) -- 4.2.2 Free Energy for Formation of a Nucleus ΔG(N) -- 4.2.3 Free Energy for Formation of a Critical Nucleus (ΔG*) -- 4.2.4 Shape of a Nucleus Is Related to Kinetic Parameters -- 4.2.5 Diffusion -- 4.3 Direct Observation of Nano-Nucleation by Synchrotron Radiation -- 4.3.1 Introduction and Experimental Procedure -- 4.3.2 Observation of Nano-Nucleation by SAXS -- 4.3.3 Extended Guinier Plot Method and Iteration Method -- 4.3.4 Kinetic Parameters and Size Distribution of the Nano-Nucleus -- 4.3.5 Real Image of Nano-Nucleation -- 4.3.6 Supercooling Dependence of Nano-nucleation -- 4.3.7 Relationship between Nano-Nucleation and Macro-Crystallization -- 4.4 Improvement of Nucleation Theory -- 4.4.1 Introduction -- 4.4.2 Nucleation Theory Based on Direct Observation of Nucleation -- 4.4.3 Confirmation of the Theory by Overall Crystallinity -- 4.5 Homogeneous Nucleation from the Bulk Melt under Elongational Flow -- 4.5.1 Introduction and Case Study -- 4.5.2 Formulation of Elongational Strain Rate e. -- 4.5.3 Nano-Oriented Crystals.
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|6 505-00/(S
|a 4.5.4 Evidence of Homogeneous Nucleation -- 4.5.5 Nano-Nucleation Results in Ultrahigh Performance -- 4.6 Heterogeneous Nucleation -- 4.6.1 Introduction -- 4.6.2 Experimental -- 4.6.3 Role of Epitaxy in Heterogeneous Nucleation -- 4.6.4 Acceleration Mechanism of Nucleation of Polymers by Nano-Sizing of Nucleating Agent -- 4.7 Effect of Entanglement Density on the Nucleation Rate -- 4.7.1 Introduction and Experimental -- 4.7.2 Increase of νe Leads to a Decrease of I -- 4.7.3 Change of νe with Δt -- 4.7.4 Two-Step Entangling Model -- 4.8 Conclusion -- Acknowledgments -- References -- 5: Growth of Polymer Crystals -- 5.1 Introduction -- 5.1.1 Complex Behavior of Polymers -- 5.2 Growth of Polymer Crystals from Solutions -- 5.2.1 Single Crystals -- 5.2.2 Crystallization from Solution under Shear -- 5.2.3 Solution Casting Method -- 5.3 Growth of Polymer Crystals from Melt -- 5.3.1 Positive and Negative Spherulites -- 5.3.2 Spherulite Morphology and Crystalline Modification -- 5.3.3 Spherulite Patterns of Blend Samples -- 5.4 Crystallization Mechanism of Polymer -- 5.4.1 Basic Theory of Crystallization of Polymer -- 5.4.2 Growth Rate of Spherulites -- 5.5 Microscopically Viewed Structural Evolution in the Growing Polymer Crystals -- 5.5.1 Experimental Techniques -- 5.5.2 Structural Evolution in Isothermal Crystallization -- 5.5.3 Shear-Induced Crystallization of the Melt -- 5.6 Crystallization upon Heating from the Glassy State -- 5.6.1 Cold Crystallization -- 5.6.2 Solvent-Induced Crystallization of Polymer Glass -- 5.7 Crystallization Phenomenon Induced by Tensile Force -- 5.8 Photoinduced Formation and Growth of Polymer Crystals -- 5.9 Conclusion -- References -- 6: Computer Modeling of Polymer Crystallization -- 6.1 Introduction -- 6.2 Methods -- 6.2.1 Molecular Dynamics -- 6.2.2 Langevin Dynamics -- 6.2.3 Monte Carlo -- 6.2.4 Kinetic Monte Carlo.
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