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Introduction to Infrared and Raman Spectroscopy.
Introduction to Infrared and Raman Spectroscopy.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford :
Elsevier Science,
1975.
|
| Edición: | 2nd ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Introduction To Infrared and Raman Spectroscopy; Copyright Page; Table of Contents; Preface; CHAPTER 1. VIBRATIONAL AND ROTATIONAL SPECTRA; 1.1 Introduction; 1.2 Photon Energy; 1.3 Degrees of Freedom of Molecular Motion; 1.4 Normal Modes of Vibration; 1.5 Mechanical Molecular Models; 1.6 Coordinates Used to Describe Molecular Vibrations; 1.7 Classical Vibrational Frequency Formula for a Diatomic Molecule; 1.8 Infrared Absorption and the Change in Dipole Moment; 1.9 Anharmonicity and Overtones; 1.10 Vibrational Potential Function; 1.11 Introduction to the Quantum Effect.
- 1.12 The Quantum Mechanical Harmonic Oscillator1.13 The Boltzmann Distribution Function; 1.14 Vibrational Transitions and Infrared Absorption; 1.15 The Anharmonic Oscillator; 1.16 Combination and Difference Bands; 1.17 Fermi Resonance; 1.18 Rotation of Linear Molecules; 1.19 Rotational Transitions and Infrared Absorption; 1.20 The Nonrigid Rotator; 1.21 Rotational Line Intensities; 1.22 Types of Rotators; 1.23 Rotation of Symmetric Top Molecules; 1.24 Vibrational-Rotational Spectrum, Classical Picture; 1.25 Vibrational-Rotational Spectrum, Quantum Mechanical Treatment.
- 1.26 Vibrational-Rotational Spectrum Nonrigid Rotator1.27 Spherical Top Molecules; 1.28 Symmetrical Top Molecules; 1.29 Asymmetrical Top Molecules; 1.30 The Raman Effect; 1.31 Polarizability; 1.32 The Tensor Character of the Polarizability; 1.33 Depolarization Ratio; 1.34 Pure Rotational Raman Spectra; CHAPTER 2. EXPERIMENTAL CONSIDERATIONS; 2.1 Source of Infrared Radiation; 2.2 Infrared Monochromators and Filters; 2.3 Infrared Detectors; 2.4 Commercial Instruments; 2.5 Instrument Calibration; 2.6 Sample Handling Techniques; 2.6 Sample Handling Techniques; 2.8 Polarized Infrared Radiation.
- 2.9 Infrared Fourier Transform Spectroscopy2.10 Raman Sources; 2.11 Raman Spectrographs; 2.12 Raman Measurements; CHAPTER 3. MOLECULAR SYMMETRY; 3.1 Symmetry Properties; 3.2 Point Groups; 3.3 Group Theory; 3.4 Group Theory Applied to Point Groups; 3.5 Representations of Groups; 3.6 Irreducible Representations; 3.7 The Character Table; 3.8 Irreducible Representation Components in a Representation; 3.9 Transformation Properties of a Vector; 3.10 The Number of Fundamentals of Each Type; 3.11 Selection Rules; 3.12 Infrared Activity of Fundamentals; 3.13 Raman Activity of Fundamentals.
- 3.14 Overtone and Combination Bands3.15 Symmetry Coordinates; 3.16 Isotope Effects and the Product Rule; 3.17 Character Tables and Selection Rules; CHAPTER 4. THE VIBRATIONAL ORIGIN OF GROUP FREQUENCIES; 4.1 Introduction; 4.2 Diatomic Oscillators; 4.3 Coupled Oscillators; 4.4 Unsymmetrical Coupled Oscillators; 4.5 X-H Stretching Frequencies; 4.6 Triple Bond Vibrations; 4.7 Cumulated Double Bonds; 4.8 The Linear M 1
- M 2
- M 3 Model; 4.9 X-Ca" Compounds; 4.10 Carbonyl and C=C Compounds; 4.11 Cyclic Compound Stretching Vibrations; 4.12 The Bent M1-M2-M1 Stretching Frequencies.