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Advances in Chemical Physics, Liquid Polymorphism.
Advances in Chemical Physics is the only series of volumes available that explores the cutting edge of research in chemical physics. This new guest-edited volume focuses on liquid polymorphism, containing a representative cross-section of research that questions established thinking by scrutinizing...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken :
Wiley,
2013.
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| Colección: | Advances in chemical physics.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Liquid Polymorphism: Advances In Chemical Physics; CONTRIBUTORS TO VOLUME 152; FOREWORD; PREFACE; PREFACE TO THE SERIES; CONTENTS; Electron Spin Resonance Studies of Supercooled Water; I. Introduction; II. Outline of ESR Spectroscopy; A. Spin Probes; B. Rigid-Limit and Motional Narrowing of the Lineshape; C. Accessible Range of the Rotational Dynamics; III. ESR Spectroscopy of Spin Probes: Basic Theoretical Introduction; A. Spin Hamiltonian; B. Lineshape Analysis; 1. No Tumbling: Powder Lineshape; 2. Tumbling: Motional Narrowing of the ESR Lineshape.
- IV. ESR Studies of Liquid Water and Aqueous Solutions: A ReviewV. ESR Studies of Confined Water in Polycrystalline Ice; A. Water Confinement in Polycrystalline Ice; B. Location of Paramagnetic Solutes in Water-Ice Mixtures; C. Rotational Dynamics of TEMPOL in Interstitial Water of Polycrystalline Ice; 1. Spin Probe Mobility Above 130K; 2. Dynamical Heterogeneities; 3. Temperature Dependence of the Spin Probe Reorientation; 4. Breakdown of the Debye-Stokes-Einstein Law; 5. Spin Probe Sensing of the Water Static Heterogeneities; 6. Missing Evidence of Additional Impurities in Interstitial Water.
- VI. SummaryReferences; Pressure-Driven Liquid-Liquid Transformations and Corresponding Bizarre Viscosity Behavior; I. Introduction; II. Methods; III. Results and Discussions; A. Se; B. AsS; C. As2S3; D. B2O3; IV. Conclusions; References; The Stability Limit and Other Open Questions on Water at Negative Pressure; I. Introduction; II. What is Negative Pressure?; III. The Phase Diagram of Water; IV. Experimental Methods to Generate Tension; A. Acoustic Cavitation; B. Metastable Vapor-Liquid Equilibrium; C. Berthelot Tube; D. Centrifuge Method; V. Limit(s) of Metastability.
- IV. Rosenfeld ScalingV. Conclusions; References; High-Frequency Dynamics of Liquids Through a Liquid-Liquid Transition: The Case of CS; I. Introduction; II. The Case of Liquid Cesium; III. The Experiment; IV. Results; V. Discussion; VI. Conclusions; References; The Liquid-Liquid Phase Transition, Anomalous Properties, and Glass Behavior of Polymorphic Liquids; I. Introduction; II. Polymorphic Liquids: Phase Diagram, Anomalous Properties, and Glass Behavior; A. Liquid-Liquid Phase Transition; B. Supercritical Region: Anomalous Properties; C. Glass Polymorphism.