New developments in aldehydes research /

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Torrioni, Luca (Editor ), Pescasseroli, Emilia (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York : Nova Publishers, [2013]
Colección:Chemical engineering methods and technology.
Temas:
Aldehydes.
Aldéhydes.
SCIENCE > Chemistry > Organic.
Aldehydes
Acceso en línea:Texto completo
Tabla de Contenidos:
  • NEW DEVELOPMENTS IN ALDEHYDES RESEARCH ; NEW DEVELOPMENTS IN ALDEHYDES RESEARCH ; CONTENTS ; PREFACE ; SYNTHESIS AND PROPERTIES OF INTERMEDIATES IN REACTIONS OF ALDEHYDES WITH P (III) CHLORIDES ; ABSTRACT ; INTRODUCTION ; 1. THE BRIEF HISTORICAL SURVEY OF REACTIONS OF ALDEHYDES WITH P(III) CHLORIDES ; 2. SYNTHETIC METHODS AND STRUCTURE OF PRIMARY INTERMEDIATES ; 3. CHEMICAL PROPERTIES OF THEPRIMARY INTERMEDIATES ; 3.1. Interaction of Intermediates 12with Ethylene Oxide, Acetal, Trialkyl Orthoformates and Trialkyl Phosphites.
  • 3.2. Reactions of Intermediates10b-C with Acetals and Trialkyl Orthoformates 3.3. Oxidation of Primary Intermediates (R; 3.4. Interaction of Intermediates 12f-Iwith Phosphorus Pentachloide and Chlorine ; 4. REACTIONS OF THE PRIMARY INTERMEDIATESWITH ALDEHYDES AND DETECTION OF THE SECONDARY INTERMEDIATES ; Conclusion; 5. DESCRIPTION OF THE EXPERIMENTS ; 5.1. Removing of HCl Contaminant from P(III) Chlorides; 5.1.1. By Treatment with Tertiary Amines ; 5.1.2. By Treatment with AVE Ethy; 5.2. Reactions of P(III) Chlorides with Aldehydes.
  • 5.2.1. Interaction of P(III) Chlorides with Acetaldehyde in the Absence of Catalyst 5.2.2. Reaction of P(III) Chloride with Aldehydes in the Presence of Tertiary Amines ; General Procedure The ; 1-Chloro-2-Methylpropyl Phosphorodichloridite 10c ; 1-Chlorobutyl Phosphorodichloridite 10b ; 1-Chloroethyl Phosphorodichloridite 10a ; Di(1-chloroethyl) phosphorochloridite 11a The rea; Tri(1-chloroethyl) Phosphite 12a 3; 5.2.3. Reaction of P(III) Chlorides with Aldehydes in Presence of EVE ; General Procedure Ethy; Catechol 1-chloro-2,2-dimethylpropyl Phosphite 12i.
  • Catechol 1-chloro-2-methylpropyl Phosphite 12f. The reac1-Chloro-2-methylpropyl bis(2,2,2-trichloroethyl) Phosphite 12b ; Di(1-chloroethyl) 2,2,2-trichloroethyl Phosphite 12e ; 5.3. Reactions of Primary Intermediates with Nucleophiles ; 5.3.1. With Ethylene Oxide ; 5.3.2. With Trialkylphosphite ; 5.3.3. With the Acetals ; 5.3.4. With Trialkyl Orthoformate ; 5.3.5. With Ü-Chlorodiethyl Ether ; 5.4. Oxidation of the Primary Intermediates ; 5.4.1. With Dimethylsulfoxide (DMSO) ; 1-Chloroethyl Dichlorophosphate 65a Benz; 1-Chlorobutyl Dichlorophosphate 65b On anal.
  • 1-Chloro-2-methylpropyl Dichlorophosphate65c Catechol 1-chloroethyl Phosphate 65f O; Catechol 1-chlorobutyl Phosphate 65g ; 1,2,2,2-Tetrachloroethyl Dichlorophosphate 65l; Di(1-chloroethyl) Chlorophosphate 65d O; Di(1-Chloro-2-Methylpropyl) 2,2,2-Trichloroethyl Phosphate 65n ; 1-Chloro-2-Methylpropyl Bis (2,2,2-Trichloroethyl) Phosphate 65h. ; Di(1-Chloroethyl) 2,2,2-Trichloroethyl Phosphate 65o.; 5.4.2. With t-BuOCl ; 1-Chloroethyl Dichlorophosphate 65a BuO; 1-Chlorobutyl Dichlorophosphate 65b O; 1-Chloro-2-Methylpropyl Dimethyl Phosphate 65i ; 1-Chloro-2-Methylprophyl Diethyl Phosphate 65j.

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