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Microwaves in Organic Synthesis 2 Volume Set.
The third edition of the bestselling two-volume reference covers everything you need to know about microwave technology for synthesis -- from the best equipment to nonthermal effects, from solid-support reactions to catalysis.Completely revised and updated with half of the authors completely new to...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Weinheim :
Wiley,
2013.
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| Edición: | 3rd ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Related Titles; Title Page; Copyright; Contents to Volume 1; Preface; List of Contributors; Part I: Fundamental Aspects of Microwave Irradiation in Organic Chemistry; Chapter 1: Microwave-Materials Interactions and Dielectric Properties: From Molecules and Macromolecules to Solids and Colloidal Suspensions; 1.1 Fundamentals of Microwave-Matter Interactions; 1.2 Dielectric Properties and Molecular Behavior; 1.3 Conclusion; References; Chapter 2: Development and Design of Reactors in Microwave-Assisted Chemistry; 2.1 Introduction.
- 2.2 Basic Concepts for Reactions and Reactors in Organic Synthesis2.3 Methods for Enhancing the Rates of Organic Reactions; 2.4 Microwave-Assisted Organic Syntheses; 2.5 Commercial Microwave Reactors; 2.6 Selected Equipment and Applications; 2.7 Qualification and Validation of Reactors and Results; 2.8 Conclusion and the Future; References; Chapter 3: Key Ingredients for Mastery of Chemical Microwave Processes; 3.1 The Systemic Approach; 3.2 Thermal Dependence of Dielectric Loss; 3.3 Electric Field Effects; 3.4 Loop Modes or Strange Solutions of Maxwell's Equations; 3.5 Hydrodynamic Aspects.
- 3.6 Thermodynamic and Other Effects of Electric Fields3.7 Athermal and Specific Effects of Electric Field; 3.8 The Thermal Path Effect: Anisothermal Conditions; 3.9 Hot Spots and Heterogeneous Kinetics; 3.10 Conclusion; References; Chapter 4: Nonthermal Effects of Microwaves in Organic Synthesis; 4.1 Introduction; 4.2 Origin of Microwave Effects; 4.3 Specific Nonthermal Microwave Effects; 4.4 Effects of the Medium; 4.5 Effects Depending on Reaction Mechanisms; 4.6 Effects Depending on the Position of the Transition State Along the Reaction coordinate; 4.7 Effects on Selectivity.
- 4.8 Some Illustrative Examples4.9 Concerning the Absence of Microwave Effects; 4.10 Conclusion: Suitable Conditions for Observation of Specific MW Effects; References; Chapter 5: Selectivity Modifications Under Microwave Irradiation; 5.1 Introduction; 5.2 Selective Heating; 5.3 Modification of Chemoselectivity and Regioselectivity; 5.4 Modification of Stereo- and Enantioselectivity; 5.5 Conclusion; References; Acknowledgments; Chapter 6: Elucidation of Microwave Effects: Methods, Theories, and Predictive Models; 6.1 Introduction; 6.2 Thermal Effects; 6.3 Non-Thermal Effects; 6.4 Conclusion.