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Physical and Chemical Equilibrium for Chemical Engineers.
This book concentrates on the topic of physical and chemical equilibrium. Using the simplest mathematics along with numerous numerical examples it accurately and rigorously covers physical and chemical equilibrium in depth and detail. It continues to cover the topics found in the first edition howev...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Chicester :
Wiley,
2012.
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| Edición: | 2nd ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- PHYSICAL AND CHEMICAL EQUILIBRIUM FOR CHEMICAL ENGINEERS; CONTENTS; Preface; About the Author; Nomenclature; 1 Introduction to Equilibrium; 1.1 Why Study Equilibrium?; 1.2 Stability and Equilibrium; 1.3 Time Scales and the Approach to Equilibrium; 1.4 Looking Ahead, Gibbs Energy; 1.5 Units, Conversion Factors, and Notation; 1.6 Reality and Equations; 1.7 Phases and Phase Diagrams; 1.8 The Plan of this Book; 1.9 Summary; References; 2 Basic Thermodynamics; 2.1 Conservation and Accounting; 2.2 Conservation of Mass; 2.3 Conservation of Energy; the First Law of Thermodynamics.
- 2.4 The Second Law of Thermodynamics2.4.1 Reversibility; 2.4.2 Entropy; 2.5 Convenience Properties; 2.6 Using the First and Second Laws; 2.7 Datums and Reference States; 2.8 Measurable and Immeasurable Properties; 2.9 Work and Heat; 2.10 The Property Equation; 2.11 Equations of State (EOS); 2.11.1 EOSs Based on Theory; 2.11.2 EOSs Based on Pure Data Fitting; 2.12 Corresponding States; 2.13 Departure Functions; 2.14 The Properties of Mixtures; 2.15 The Combined First and Second Law Statement; Reversible Work; 2.16 Summary; References.
- 3 The Simplest Phase Equilibrium Examples and Some Simple Estimating Rules3.1 Some General Statements About Equilibrium; 3.2 The Simplest Example of Phase Equilibrium; 3.2.1 A Digression, the Distinction between Vapor and Gas; 3.2.2 Back to the Simplest Equilibrium; 3.3 The Next Level of Complexity in Phase Equilibrium; 3.4 Some Simple Estimating Rules: Raoult's and Henry's "Laws"; 3.5 The General Two-Phase Equilibrium Calculation; 3.6 Some Simple Applications of Raoult's and Henry's Laws; 3.7 The Uses and Limits of Raoult's and Henry's Laws; 3.8 Summary; References.
- 4 Minimization of Gibbs Energy4.1 The Fundamental Thermodynamic Criterion of Phase and Chemical Equilibrium; 4.2 The Criterion of Equilibrium Applied to Two Nonreacting Equilibrium Phases; 4.3 The Criterion of Equilibrium Applied to Chemical Reactions; 4.4 Simple Gibbs Energy Diagrams; 4.4.1 Comparison with Enthalpy and Entropy; 4.4.2 Gibbs Energy Diagrams for Pressure-Driven Phase Changes; 4.4.3 Gibbs Energy Diagrams for Chemical Reactions; 4.5 Le Chatelier's Principle; 4.6 Summary; References; 5 Vapor Pressure, the Clapeyron Equation, and Single Pure Chemical Species Phase Equilibrium.
- 5.1 Measurement of Vapor Pressure5.2 Reporting Vapor-Pressure Data; 5.2.1 Normal Boiling Point (NBP); 5.3 The Clapeyron Equation; 5.4 The Clausius-Clapeyron Equation; 5.5 The Accentric Factor; 5.6 The Antoine Equation and Other Data-Fitting Equations; 5.6.1 Choosing a Vapor-Pressure Equation; 5.7 Applying the Clapeyron Equation to Other Kinds of Equilibrium; 5.8 Extrapolating Vapor-Pressure Curves; 5.9 Vapor Pressure of Solids; 5.10 Vapor Pressures of Mixtures; 5.11 Summary; References; 6 Partial Molar Properties; 6.1 Partial Molar Properties; 6.2 The Partial Molar Equation.