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The Noble Gases as Geochemical Tracers.

This complete guide to the use of noble gases in terrestrial geochemistry offers applications ranging from high temperature processes deep in the Earth, to tracing climatic variation using noble gases trapped in ice cores, groundwaters and modern sediments.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Burnard, Peter
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Dordrecht : Springer, 2012.
Colección:Advances in isotope geochemistry.
Temas:
Acceso en línea:Texto completo

MARC

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100 1 |a Burnard, Peter. 
245 1 4 |a The Noble Gases as Geochemical Tracers. 
260 |a Dordrecht :  |b Springer,  |c 2012. 
300 |a 1 online resource (390 pages) 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
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490 1 |a Advances in Isotope Geochemistry 
588 0 |a Print version record. 
505 0 |a The Noble Gases as Geochemical Tracers -- Preface -- Contents -- 1 The Noble Gases as Geochemical Tracers: History and Background -- Abstract -- 1 Introduction -- 1.1 History -- 1.2 Conventions -- 2 Noble Gas Mass Spectrometry -- 2.1 Principles -- 2.1.1 Electron Bombardment Sources -- 2.1.2 Pressure Dependent Effects -- 2.1.3 Isobaric interferences -- 2.2 Extraction and Purification -- 2.2.1 Extraction: Fluid Samples -- 2.2.2 Extraction: Solid Samples -- 2.2.3 Purification -- 2.2.4 Cryoseparation -- 2.3 Calibrating Noble Gas Mass Spectrometers -- References -- 2 Noble Gases in the Atmosphere -- Abstract -- 1 Determination of the Present-Day Atmospheric Noble Gas Compositions -- 1.1 Absolute Determinations of the Atmospheric 3He/4He -- 1.2 Absolute Measurements of Atmospheric Ar Isotope Ratios -- 1.3 Absolute Measurements of Ne, Kr and Xe Isotopic Compositions -- 2 Heterogeneity of the Modern Atmosphere -- 2.1 Possible Temporal Variation of Atmospheric Helium Isotopes -- 2.2 Anthropogenic Sources of Atmospheric Helium -- 2.3 Possible Spatial Variation of Atmospheric Helium Isotopes -- 2.4 Anthropogenic Kr and Xe -- 2.5 Temporal Variation of Atmospheric Argon Isotopes -- 3 Future Directions -- References -- 3 Noble Gases in Ice Cores: Indicators of the Earth's Climate History -- Abstract -- 1 Introduction -- 2 Background: Ice Cores in Greenland and Antarctica -- 3 Analytical Techniques -- 3.1 Preparation of Ice Samples for Noble Gas Analysis -- 3.1.1 Noble Gases in Trapped Air Bubbles -- 3.1.2 Noble Gases in Particles from Ice Cores -- 3.2 Mass Spectrometry -- 3.2.1 Noble Gas Mass Spectrometry of Trapped Air -- 3.2.2 Noble Gas Analysis of Particles -- 4 The Noble Gas Record from Trapped Air Bubbles in Ice Cores -- 4.1 Paleothermometry from Thermal Diffusion: Estimate of Abrupt Temperature Change Magnitude. 
505 8 |a 4.2 Paleothermometry from Solubility: A Time Series of Mean Ocean Temperature -- 4.3 Triple Argon Isotope Composition in Trapped Air: Constraining the Outgassing Rate of 40Ar from Earth's Interior -- 5 The Noble Gas Record from Particulate Matter in Ice Cores -- 5.1 Reconstructions of the Flux of Interplanetary Dust from Ice Cores -- 5.2 Reconstructions of Terrestrial Dust and Its Provenance -- 6 Summary and Future Work -- References -- 4 Noble Gases in Seawater as Tracers for Physical and Biogeochemical Ocean Processes -- Abstract -- 1 Introduction -- 2 Analytical Methods -- 2.1 Sample Collection -- 2.2 Sample Analysis -- 2.3 Solubilities in Water and Seawater -- 3 Air-Sea Gas Exchange -- 3.1 Separating Bubble Component from Diffusive Gas Exchange -- 3.2 High Latitude Ventilation -- Sec9 -- 5 Ocean-Cryospheric interaction -- 5.1 Sea Ice Formation and Destruction -- 5.2 Basal Melting of Glaciers -- 5.3 Underplating of Floating Ice Shelves -- 6 Ocean Circulation -- 7 Ocean-Lithosphere Interactions -- 8 Biogeochemical Processes -- 8.1 Oxygen and Argon for Net Community Production -- 8.2 The Helium Flux Gauge for New Production -- 8.3 Oxygen Utilization Rates for Export Production -- 8.4 Water Column Denitrification Rates -- 9 Summary -- References -- 5 Noble Gas Thermometry in Groundwater Hydrology -- Abstract -- 1 Introduction -- 1.1 Early History of the Noble Gas Thermometer -- 1.2 Recent Developments and Outline of this Chapter -- 2 Sampling and Analytical Methods -- 2.1 Sampling -- 2.1.1 Preventing Gas Exchange During Sampling -- 2.1.2 Selection of Suitable Wells and Springs -- 2.1.3 Standard Protocol for Copper Tube Samplers -- 2.1.4 Passive Diffusion Samplers -- 2.1.5 Additional Parameters to Measure in the Field -- 2.2 Analytical Techniques -- 2.2.1 Extraction of Noble Gases from Water -- 2.2.2 Gas Purification and Separation. 
505 8 |a 2.2.3 Analysis of Noble Gas Amounts -- 3 Data Reduction and Interpretation -- 3.1 From Raw Data to Noble Gas Concentrations -- 3.2 From Concentrations to Noble Gas Temperatures -- 3.3 Estimation of Non-Atmospheric Components -- 3.4 Excess Air Models: Historical Development -- 3.5 Excess Air Models: Equations -- 3.6 Excess Air Models: Discussion -- 3.7 From Noble Gas Temperatures to a Climate Record -- 3.7.1 Relationship of NGT with Soil and Air Temperature -- 3.7.2 Chronologies for NGT Records -- 4 Applications -- 4.1 Paleotemperature Reconstruction -- 4.1.1 Historical Overview -- 4.2 Excess Air as a Proxy for Paleohumidity -- 4.3 Recent Examples -- 4.4 Other Uses of Noble Gases in Groundwater -- 4.5 Mountain Block Recharge -- 5 Summary and Outlook -- Acknowledgments -- References -- 6 Noble Gases as Environmental Tracers in Sediment Porewaters and Stalagmite Fluid Inclusions -- Abstract -- 1 Introduction -- 2 Noble Gases in Aqueous Solution -- 2.1 Sources and Processes -- 2.1.1 Atmospheric Noble Gases -- Noble Gas Concentrations in Air-Saturated Water -- Excess Air -- 2.1.2 Non-atmospheric Noble Gases -- 2.1.3 Disentangling and Quantifying the Various Noble Gas Components -- 2.2 Experimental Methods -- 3 Lacustrine and Oceanic Sediments -- 3.1 Noble Gases in Sediment Porewater -- 3.2 Experimental Methods -- 3.2.1 Sampling -- 3.2.2 Extraction and Analysis of Dissolved Noble Gases -- 3.3 Applications in Environmental Studies -- 3.3.1 Palaeoenvironmental Conditions -- 3.3.2 Transport and Geochemical Origin of Pore Fluids -- 3.3.3 Diffusion and Trapping Mechanisms -- 4 Stalagmites -- 4.1 Noble Gases in Stalagmite Fluid Inclusions -- 4.2 Experimental Methods -- 4.2.1 Sample Selection -- 4.2.2 Crushing -- Crushing in Vacuo -- Crushing in a Gas Atmosphere -- 4.2.3 Heating -- 4.2.4 Quantification of the Water Mass. 
505 8 |a 4.3 First Applications of the Noble Gas Thermometer -- 4.3.1 Stalagmites from Bunker Cave (Germany) -- 4.3.2 Stalagmites from Central Europe and the Middle East -- He and Ne Trapped in the Calcite Lattice? -- Ar-Kr-Xe Signatures in Fluid Inclusions -- 5 Summary, Outlook and Future Research -- References -- 7 Extraterrestrial He in Sediments: From Recorder of Asteroid Collisions to Timekeeper of Global Environmental Changes -- Abstract -- 1 Introduction -- 2 Origin of Extraterrestrial He in IDPs -- 3 IDPs in Terrestrial Deposits -- 3.1 Determination of Extraterrestrial Noble Gases -- 3.2 Carrier Phase of 3HeET in Terrestrial Deposits -- 3.3 Atmospheric Entry Heating and Grain Size Distribution of 3HeET-Bearing IDPs in Terrestrial Deposits -- 4 Extraterrestrial He in the Geologic Record -- 4.1 Extraterrestrial He as a Tracer of Past Variations in IDP Flux -- 4.2 Use of Extraterrestrial 3He to Calculate Sedimentary Accumulation Rates -- 5 Summary and Future Work -- Acknowledgement -- References -- 8 Application of Noble Gases to the Viability of CO2 Storage -- Abstract -- Sec1 -- 1.1 The Need for CO2 Storage -- 1.2 What is Geological Carbon Storage? -- 1.2.1 Depleted Oil and Gas Reservoirs -- 1.2.2 Deep Saline Formations -- 1.2.3 Deep (Un-Minable) Coal Seams -- 1.2.4 Additional CO2 Storage Options -- 1.3 Mechanisms of Viable CO2 Storage -- 1.3.1 Physical Trapping: Stratigraphic and Structural Storage -- 1.3.2 Residual or Hydrodynamic Storage -- 1.3.3 Dissolution Storage or Solubility Trapping -- 1.3.4 Mineral Storage or Mineral Trapping -- 2 Sample Collection and Analytical Techniques -- 2.1 Well Head Collection Methods -- 2.2 Water and Low Pressure Gas Collection Methods -- 2.3 Issues of Long Term Sample Storage -- 2.4 Analytical Techniques Specific to CO2 Samples -- 3 Noble gases in Geological Reservoirs -- 3.1 Introduction. 
505 8 |a 3.2 Sources of Noble Gases in a Subsurface Reservoir -- 3.3 Noble Gas Production -- 3.3.1 Radiogenic Helium: 4He -- 3.3.2 Radiogenic Argon: 40Ar -- 3.3.3 Krypton and Xenon -- 3.3.4 Nucleogenic Helium and Neon -- 3.4 Atmospheric Noble Gases -- 3.5 Crustal Noble Gases -- 3.6 Mantle Noble Gases -- 4 Understanding the Sources and Processing of Crustal Fluids -- 4.1 Introduction -- 4.2 Two Component Mixing -- 4.3 Three Component Mixing -- 4.4 Role of Stable Isotopes -- 5 Use of Noble Gases in Natural CO2 Reservoirs: Colorado Plateau, USA -- 5.1 Determining the Source and Residence Time of CO2 -- 5.2 Determining the Long Term Fate of CO2 -- 5.2.1 Using Noble Gases and Carbon Isotopes to Identify Long Term Fate of CO2 -- 5.2.2 Using Noble Gases and Carbon Isotopes to Determine Reservoir pH Conditions -- 5.3 Physical Chemistry of Dissolved Noble Gases -- 5.4 Noble Gas Fractionation and Partitioning Between Phases -- 5.4.1 Solubility Controlled Phase Fractionation -- 5.4.2 Rayleigh Fractionation (Open System) -- 5.4.3 Quantifying the Extent of Water Interaction -- 5.4.4 Adsorptive Fractionation -- 5.4.5 Diffusive Fractionation -- 6 Use of Noble Gases in Hydrocarbon Fields Relevant to CO2 Storage -- 6.1 Tracing of CO2 Injected for EOR, Mabee Oil Field Texas -- 6.2 Noble Gas Tracing of Groundwater/Coalbed Methane Interaction, San Juan Basin, USA -- 7 Use of Noble Gases for Monitoring of Subsurface CO2 Migration and Leakage -- 7.1 Noble Gases as Tracers of CO2 Leakage at Green River Springs, Utah, USA -- 7.2 He and Rn in Soil Gases and CO2 Seeps from the Massif Central, France -- 7.3 He and Ne as Tracers of Natural CO2 Migration at St. Johns Dome, Arizona, USA -- 7.4 Noble Gas Investigation of Alleged CO2 Leakage at Weyburn -- 8 Summary and Future Work -- References -- 9 Noble Gas in Oil and Gas Accumulations -- Abstract. 
520 |a This complete guide to the use of noble gases in terrestrial geochemistry offers applications ranging from high temperature processes deep in the Earth, to tracing climatic variation using noble gases trapped in ice cores, groundwaters and modern sediments. 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
650 0 |a Environmental chemistry. 
650 0 |a Chemistry. 
650 0 |a Geography. 
650 0 |a Geochemistry. 
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650 6 |a Chimie de l'environnement. 
650 6 |a Chimie. 
650 6 |a Géographie. 
650 6 |a Géochimie. 
650 7 |a chemistry.  |2 aat 
650 7 |a geography.  |2 aat 
650 7 |a geochemistry.  |2 aat 
650 7 |a Chemistry  |2 fast 
650 7 |a Environmental chemistry  |2 fast 
650 7 |a Geochemistry  |2 fast 
650 7 |a Geography  |2 fast 
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830 0 |a Advances in isotope geochemistry. 
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